ISHIFUNE Manabu

    Department of Applied Chemistry Associate Professor
Last Updated :2024/03/24

Researcher Information

Degree

  • Engineering(Kyoto University)

URL

J-Global ID

Research Interests

  • 高分子合成   有機合成化学   有機電子移動化学   Polymer Synthesis   Organic Synthesis   Organic Electron Transfer Chemistry   

Research Areas

  • Nanotechnology/Materials / Functional solid-state chemistry
  • Nanotechnology/Materials / Polymer chemistry
  • Nanotechnology/Materials / Synthetic organic chemistry

Academic & Professional Experience

  • 2003 - 2008  Lecturer, Kinki University,
  • 2002 - 2008  Kindai UniversityFaculty of Science and Engineering
  • 2008  - 近畿大学理工学部 准教授
  • 2008  - Associate Professor, Kinki University,
  • 1995 - 2002  Kindai UniversityFaculty of Science and Engineering
  • 1995 - 2002  Research Assistant, Kinki University,
  • 2000 - 2001  ドイツ・ミュンスター大学有機化学研究所 客員研究員
  • 2000 - 2001  Guest Researcher, Institute of Organic Chemistry,
  • 1994 - 1995  日本学術振興会特別研究員(PD)
  • 1994 - 1995  Reserch Fellow,
  • University of Muenster (Germany)
  • School of Science and Engineering
  • Research Fellowships for Young Scientists
  • JSPS (Japan Society for the Promotion of Science)

Education

  •        - 1993  Kyoto University  工学研究科  合成化学
  •        - 1993  Kyoto University  Graduate School, Division of Engineering
  •        - 1988  Kyoto University  Faculty of Engineering  合成化学
  •        - 1988  Kyoto University  Faculty of Engineering

Association Memberships

  • The Electrochemical Society (America)   高分子学会   電気化学会   有機合成化学協会   日本化学会   The Electrochemical Society   The Society of Organic Synthetic Chemisty, Japan   The Society of Polymer Science, Japan   The Electrochemical Society of Japan   The Chemical Society of Japan   

Published Papers

  • Toru Uemukai; Masashi Torisaki; Takahiro Hamanaka; Manabu Ishifune
    Journal of Applied Polymer Science Wiley 130 (5) 3458 - 3464 0021-8995 2013/12 
    Partitioning of organic substrates by thermoresponsive polymer having N-acryloylaminoalcohol moieties in aqueous phase has been studied. Thermoresponsive polymers, such as poly(N-isopropylacrylamide) (PNIPAAm) and poly(NIPAAm-co-N-acryloyl-(±)-alaninol) (poly(NIPAAm-co-HIPAAm)), were found to concentrate several organic substrates into the hydrophobic field generated during their phase transition. The amount of the substrates recoverd from the polymer phase mainly depended on the hydrophobicity of the substrates. Aqueous solutions of PNIPAAm (lower critical solution temperature, LCST = 33°C) and poly(NIPAAm-co-HIPAAm) (LSCT = 41°C) containing 1-phenylethanol showed LCSTs at 22°C and 33°C, respectively. The changes of LCSTs indicate that specific interactions such as hydrogen bonding between the side chain functionalities of the polymers and the substrates influence the phase transition behavior. Moreover, new optically active polymers having chiral aminoalcohol moieties have been synthesized by copolymerizations of NIPAAm with N-acryloylaminoalcohols such as N-acryloyl-(S)-alaninol and N-acryloyl-(S)-prolinol. The (R)/(S) ratio of 1-phenylethanol recovered from poly(NIPAAm-co-N-acryloyl-(S)-alaninol) and poly(NIPAAm-co-N-acryloyl-(S)- prolinol) were determined to be 75/25 and 68/32, respectively. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3458-3464, 2013 Copyright © 2013 Wiley Periodicals, Inc.
  • Toru Uemukai; Manabu Ishifune
    JOURNAL OF APPLIED POLYMER SCIENCE WILEY-BLACKWELL 129 (5) 2554 - 2560 0021-8995 2013/09 
    Optically active polymers having chiral 2-aminomethylpyrrolidine side chains have been newly synthesized by a radical homopolymerization of the corresponding protected acrylamide monomer and copolymerization with N-isopropylacrylamide followed by deprotection. The resulting polymers were found to be thermoresponsive showing lower critical solution temperatures (LCSTs) at 27-65 degrees C in their aqueous solutions. The pyrrolidine side chains of the resulting thermoresponsive polymer promoted aldol reaction between cyclohexanone and p-nitrobenzaldehyde in water, and the reaction proceeded most smoothly at its LCST. Moreover, the diastereomeric ratio (syn : anti) of the aldol adducts obtained at the reaction at 40 degrees C was 22 : 78, whereas the diastereomeric ratio (syn : anti) was 55 : 45 at 20 degrees C. These results indicate that the pyrrolidine side chains catalyze the aldol reactions in the relatively hydrophobic field generated by the thermoresponsive polymer at its LCST. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
  • Toru Uemukai; Tomoya Hioki; Manabu Ishifune
    Electrochemistry 81 (5) 383 - 387 1344-3542 2013/05 
    Thermoresponsive polymers having 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) moieties were fixed on the graphite surface by using the reversible addition-fragmentation chain transfer (RAFT) graft polymerization technique. The surface of graphite has been anodically oxidized by using our original electrochemical method, and then modified with 4-cyano-4- [(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoyloxy groups (RAFT reagents) by esterification with the corresponding acid chlorides. From the resulting RAFT reagent-modified graphite, 2,2,6,6- tetramethyl-4-piperidyl methacrylate (TEMPMA) and N-isopropylacrylamide (NIPAAm) monomers were copolymerized stepwise under RAFT polymerization conditions to afford the thermoresponsive block-copolymer-grafted graphite, poly(TEMPMA)-block-PNIPAAm-grafted graphite. N-Oxylation of tetramethylpiperidyl groups on the resulting graphite successfully afforded the corresponding TEMPO-containing thermoresponsive polymer-grafted graphite. Redox behavior of the resulting graphites was observed by cyclic voltammetry. The potential and intensity of the cathodic current peaks were discontinuously changed below and above the lower critical solution temperature (LCST) of the grafted thermoresponsive polymers. These results indicate that the phase transition of the thermoresponsive polymer on the graphite influences the electron transfer between the TEMPO moieties and the graphite surface.
  • Toru Uemukai; Tomoya Hioki; Manabu Ishifune
    INTERNATIONAL JOURNAL OF POLYMER SCIENCE HINDAWI PUBLISHING CORPORATION 2013 1687-9422 2013 
    Thermoresponsive and redox-active block copolymers having 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) moieties have been synthesized by using the reversible addition-fragmentation chain transfer (RAFT) polymerization technique. N-Isopropylacrylamide (NIPAAm) and 2,2,6,6-tetramethylpiperidyl methacrylate (TEMPMA) monomers were copolymerized step-wise under RAFT polymerization conditions to afford the thermoresponsive block copolymers, PNIPAAm-block-PTEMPMA and PNIPAAm-block-PTEMPMA-block-PNIPAAm. Oxidation of tetramethylpiperidine groups in the copolymers successfully afforded the corresponding TEMPO-containing block copolymers. The resulting triblock copolymer was found to be thermoresponsive showing lower critical solution temperature (LCST) at 34 degrees C in its aqueous solution. Redox behavior of the resulting copolymer was observed by cyclic voltammetry. The potential of anodic current peak changed below and above the LCST of the block copolymer. These results indicate that the phase transition of thermoresponsive polymer influences the redox potential of TEMPO moieties.
  • Manabu Ishifune; Chika Sana; Misako Ando; Yohei Tsuyama
    POLYMER INTERNATIONAL WILEY-BLACKWELL 60 (8) 1208 - 1214 0959-8103 2011/08 
    The electroreductive polymerization of dichloromethylphenylsilane in the presence of triphenylsilyl group-containing disilanes such as hexaphenyldisilane followed by the electroreductive termination with chlorotriphenylsilane afforded triphenylsilyl group-terminated polymethylphenylsilane in 15-32% yield. The isolated polymethylphenylsilane (M(n) = 3350 g mol(-1), M(w)/M(n) = 1.4) was found to react as a macroinitiator to copolymerize with dibutyldichlorosilane under electroreductive conditions producing the corresponding block copolymer (M(n) = 4730 g mol(-1), M(w)/M(n) = 1.2) in 38% yield. The ratio of monomer units (-MeSiPh-to-BuSiBu-) of the copolymer was determined to be 75 : 25 using (1)H NMR analysis, which was in good agreement with the calculated ratio (74 : 26) on the assumption that molecular weight of the macroinitiator was not changed. The block structure of the resulting copolymer, poly(methylphenylsilane)-block-poly(dibutylsilane), was also confirmed by comparing its (1)H NMR and UV absorption spectra with those of polymethylphenylsilane, polydibutylsilane and a statistical copolymer prepared by electroreductive polymerization of dichloromethylphenylsilane with dibutyldichlorosilane. This method is applicable to the preparation of other types of macroinitiator such as triphenylsilyl group-terminated polydibutylsilane, and polydibutylsilane-block-polymethylphenylsilane was also obtained using this macroinitiator. (C) 2011 Society of Chemical Industry
  • Manabu Ishifune; Ryuhei Suzuki; Mikio Yamane; Hiroyuki Tanabe; Yuki Nakagawa; Kumao Uchida
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY TAYLOR & FRANCIS INC 45 (7) 523 - 528 1060-1325 2008 
    Acrylamide (AAm) was found to polymerize in a solution of poly(N-isopropylacrylamide) (PNIPAAm) in water at around its lower critical solution temperature (LCST) (32 degrees C) without any initiators. This phenomenon was specifically observed in aqueous solutions of the polymers having LCST such as PNIPAAm and poly(methylvinylether) (PMVE). AAm polymerized only when PNIPAAm and AAm were dissolved in water below LCST of PNIPAAm and then the solution was warmed up to the polymerization temperature (40 degrees C). On the other hand, the polymerization of AAm did not proceed when AAm was added into aqueous PNIPAAm solution during and after the phase separation above 32 degrees C. Furthermore the polymerizability of AAm was remarkably affected by the concentration and molecular weight of the PNIPAAm additives. Under the condition of lower PNIPAAm concentration (0.30 mol/L), the increase in the molecular weight of PNIPAAm considerably increased the molecular weight of the resulting PAAm but decreased the yield of PAAm. Under the condition of higher PNIPAAm concentration (0.60 mol/L) the polymerizability was not so affected by the molecular weight of PNIPAAm, while the molecular weight of PAAm formed by using higher molecular weight PNIPAAm was higher than those of PAAm formed by using lower molecular weight PNIPAAm. Moreover, the molecular weight of PAAm formed by the PNIPAAm induced polymerization of AAm was much higher than that of the polymer obtained by the radical polymerization using AIBN in THF or VA- 061 in water.
  • Shigenori Kashimura; Yoshiyuki Tane; Manabu Ishifune; Yoshihiro Murai; Sho Hashimoto; Tomohiro Nakai; Ryuich Hirose; Hiroaki Murase
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 49 (2) 269 - 271 0040-4039 2008/01 
    Reduction of dichlorosilanes with Mg metal in the presence of Lewis acid and LiCl was found to be the highly practical method for the synthesis of polysilanes. (c) 2007 Elsevier Ltd. All rights reserved.
  • Shigenori Kashimura; Yoshiyuki Tane; Manabu Ishifune; Yoshihiro Murai; Yasuki Kataoka; Hiroaki Murase; Ryoichi Nishida
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 74 (8) 603 - 605 1344-3542 2006/08 
    Electroreduction of methylphenylpolysilane (MPPS) with Mg electrode led to the formation of silyl anion. The reactions of this silyl anion with electrophiles such as dichlorosilanes and dichlorogermanes were found to form new Si-Si and Si-Ge bond, respectively. Namely, the reaction of this silyl anion with methylphenyldichlorosilanes resulted in the increase of the molecular weight of MPPS and that with dichlorogermanes led to the formation of Si-Ge copolymers.
  • Manabu Ishifune; Hajime Yamashita; Daisuke Hashimoto; Hiroshi Kanesei; Yoshimi Kakutani
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 74 (8) 659 - 667 1344-3542 2006/08 
    The modified platinum electrodes having complexes of sodium with crown ether type ligands were prepared and utilized in the electroreduction of methyl decanoate (1) in the presence of t-BuOH as a proton donor and Bu4NClO4 as a supporting electrolyte. The product yield by using the modified platinum electrode having the complex of lithium or sodium ion with the monomeric ligand LA (MPt(A)-Na) was 46%. The use of the modified platinum electrodes having the complex of sodium ion with the polymeric ligands LB (MPt(B)-Na) or LC (MPt(C)-Na) gave the reduced product in 52% or 47% yield respectively. Durability of the electrodes, MPt(A)-Na and MPt(B)-Na, under the electroreduction conditions was not so high, however, the activity of the electrodes was found to be recovered by the re-complexation of sodium ion with the ligand on the surface of the used modified electrodes. The durability of the electrode MPt(C)-Na was satisfactory to use repeatedly, and the use of MPt(C)-Na as a cathode and NaClO4 instead of Bu4NClO4 as a supporting electrolyte gave the reduced product in 69% yield. Moreover, using the modified electrodes in the presence of anodically dissolved magnesium ion the reduced product was obtained in > 90 % yield.
  • R Suzuki; M Ishifune; Y Mima; K Uchida
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 74 (3) 226 - 232 1344-3542 2006/03 
    A new method for the surface modification of carbon fiber by using electro-oxidation and -reduction sequential procedure has been exploited. The introduction of hydroxyl groups on carbon fiber was attained by the electrooxidation of the NO3 anion containing electrolyte using the carbon fiber as an anode, and the anodically introduced hydroxyl groups were successively transferred to the alkoxy groups by the electroreduction in the presence of alkyl halides using the oxidized carbon fiber as a cathode. The functional groups introduced on the carbon fiber were estimated by the X-ray photoelectron spectroscopy, the observation of the hydrophilicity of the carbon fibers, and also by using the carbon fibers as cathodes for the electroreduction of acetophenone (1). The diastereoselectivity of the reduced product, 2,3-diphenyl-2,3-butanediol (2), in the electroreduction of 1 indicated the interaction between the electrogenerated radical anion species of 1 with the hydroxyl groups on the carbon fiber surface, and the dllmeso ratio was found to increase with an increase in the content of the hydroxyl groups on the carbon fibers. The sequential modification method for carbon fibers in one-pot was successfully performed by using the MeCN-H2O (3 : 1) mixed solvent containing the mixed supporting electrolytes Bu4NNO3-Bu4NClO4 (1 : 1) and alternating the polarity of the electrodes to give the carbon fibers having high content of hydroxyl or alkoxy groups.
  • R Suzuki; M Ishifune; S Fujitani; K Uchida
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 74 (3) 216 - 220 1344-3542 2006/03 
    Carbon fiber (CF) was anodically oxidized and the resulting oxidized CF was modified with several organic compounds such as butyl bromide, benzoic anhydride, and beta-cyclodextrin (CD) under electroreductive conditions. By using the resulting modified CFs as cathodes, the electroreduction of methyl cinnamate (1) was carried out in MeCN affording methyl 3,4-diphenylcyclopentanone-2-carboxylate (3), methyl 3-phenylpropionate (4), and trace amount of dimethyl 3,4-diphenyladipate (2), and the electrode effects on the reduction efficiency and the products selectivity were investigated. The use of the oxidized CF gave relatively high products selectivity (the products ratio 3/4 = 29.0) and slight increase of the reduction efficiency (62%) in comparison with the use of the untreated CF or the alkylated CF (the products ratio 3/4 = 9.4-9.6, the reduction efficiency = 57-58%). In the electroreduction by using the modified CF having benzoate groups (Ph-modified CF) the yield of 3 and the reduction efficiency also increased (3/4 = 11.2, the reduction efficiency = 67%). The use of the CD-modified CF afforded the highest yield of the hydromonomer 4 (15%) in MeCN-H2O mixed solvent. These electrode effects were explained by the interaction between the functional groups on the modified CFs and the substrate 1.
  • M Ishifune; R Suzuki; Y Mima; K Uchida; N Yamashita; S Kashimura
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 51 (1) 14 - 22 0013-4686 2005/10 
    The electrooxidative and -reductive methods for the surface modification of carbon fiber were developed. The carbon fiber surface was first oxidized under anodic conditions to introduce phenolic hydroxyl groups on the carbon fiber, and then the resulting oxidized carbon fiber was treated under cathodic conditions in the presence of various kinds of electrophiles such as alkyl halides and alkyl tosylates introducing the alkyl groups on the carbon fiber. The changes of the functional groups on the carbon fibers were confirmed by the X-ray photoelectron spectroscopy (XPS) study and the observation of the hydrophilicity. The functional carbon fiber electrode introduced beta-cyclodextrin (beta-CD) was then prepared by this electrochemical method. The electroreduction of acetophenone (1) was carried out using the resulting carbon fibers as cathodes. The use of the carbon fiber modified with beta-CD gave relatively high dl selectivity of the reductive coupling products 2 (the dl/meso ratio: 5.2), while the dl/meso ratio using the untreated carbon fiber was 3.0, and the formation of 1-phenyl ethanol (3) was observed only by using the beta-CD-modified carbon fiber. The observed products selectivity is discussed from the viewpoints of the interaction between the electrogenerated species and the functional groups on the carbon fibers. (C) 2005 Elsevier Ltd. All rights reserved.
  • M Ishifune; Y Kogai; K Uchida
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY TAYLOR & FRANCIS INC A42 (7) 921 - 929 1060-1325 2005/07 
    The electroreduction of dichloromethylphenylsilane was carried out in the presence of the disilane additives such as 1,1,1-trimethyl-2,2,2-triphenyldisilane under constant current conditions by using Mg electrodes to give the corresponding polysilanes in 24-88% yield. The disilane additives were found to promote the electroreductive polymerization of dichloromethylphenylsilane and control the molecular weight distribution of the resulting polysilanes. The number average molecular weights of the resulting polysilanes were determined by GPC to be 2100-3800, and the molecular weight distributions, 1.05-1.25. The resulting polymers synthesized in the presence of the disilanes showed narrower molecular weight distributions than that synthesized without the additives. In particular, the resulting polymer prepared using an equal amount of the disilane additive to the dichlorosilane monomer, the number average molecular weight was 3200, the molecular weight distribution was 1.25, and the yield was found to be remarkably increased (88%). The mechanism of the electroreductive polymerization of dichloromethylphenylsilane in the presence of 1, 1, 1 -trimethyl-2,2,2-triphenyldisilane was discussed.
  • Y Kogai; M Ishifune; K Uchida; S Kashimura
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 73 (6) 419 - 423 1344-3542 2005/06 
    The reduction of chlorodimethylphenylsilane was carried out in the presence of anodically dissolved magnesium ion. After 1.0 F/mol of electricity was passed based on the chlorosilane (pre-electrolysis), the chlorosilane was added to the resulting electrolyte, and the solution was just stirred over night to give the corresponding disilane in 13% yield. Moreover, the electroreduction of the chlorosilane using platinum electrodes was carried out in the presence of the anodically dissolved magnesium ion, and the disilane was found to be obtained in 20% yield, while the disilane was not obtained by electroreduction using Pt electrodes without pre-electrolysis. The flow-system equipped with carbon electrodes was applied to the electroreduction of chlorodimethylphenylsilane in the presence of the anodically dissolved magnesium ion to give the disilane in 97% current yield. The electroreductive polymerization of dichloromethylphenylsilane was also carried out by using the flow-system and the pre-electrolysis technique to give the corresponding polymer in 17-24% yield. The number averagemolecular weights of the resulting polysilanes determined by GPC were 10900-17500. The active reductant in the present electroreduction system is probably electrogenerated during the electrolysis using magnesium electrodes, and it is able to promote the reductive synthesis of polysilanes.
  • Hiroya Kakegawa; Tomoya Satoh; Kenjin Higaki; Kazuya Nishimura; Hirokazu Itoh; You Sasaki; Yoshihiro Murai; Mananbu Ishifune; Shigenori Kashimura
    TANSO THE CARBON SOCIETY OF JAPAN 2005 (219) 243 - 245 0371-5345 2005 
    The anodic oxidation durability of several PAN based carbon fibers heat-treated at 2000°C, 2400°C and 2800°C was measured.The improvement in anodic oxidation durability was observed for all the tested heat-treated carbon fibers. In two kinds of carbon fibers, the maximum durability was observed for the samples heat-treated at 2400°C. The reason of the appearance of the maximum value is estimated that dry and wet type of oxidation occurred simultaneously in this anodic oxidation.
  • Hiroya Kakegawa; Shigonori Kashimura; Manabu Ishifune; Yoshihiro Murai; Yoshihiro Tamai; Tadasuke Isoko; You Sasaki; Ryuichi Hirose
    TANSO THE CARBON SOCIETY OF JAPAN 2005 (219) 246 - 248 0371-5345 2005 
    Indirect surface oxidation of highly graphitized milled carbon fiber (CF) with NO3. generated by an anodic oxidation of NO3- gives hydrophilic CF (CF-OH). Carbon fiber reinforced plastics (CFRP) prepared by using this milled CF-OH resulted in the remarkable increase of bending strength, elasticity, and thermal conductivity.
  • M Ishifune; Y Kogai; H Iijima; Y Kera; N Yamashita; S Kashimura
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 72 (3) 159 - 164 1344-3542 2004/03 
    The silylene-germylene copolymer with the SiSiGe ordered sequences was successufully synthesized in 49% yield by the electroreductive polymerization of bis(chlorodimethylsilyl)dibutylgermane, which was prepared by the electroreductive cross-coupling reaction of chlorodimethylsilane with dichlorodibutylgermane followed by the chlorination of the Si-H bonds. The resulting copolymer having 3900 of the number average molecular weight showed a characteristic strong UV absorption bands (lambda(max)) at 300 nm, and the extinction coefficients (epsilon(max)) per dibutylgermylene and dimethylsilylene units were calculated to be 14000. On the other hand, the electroreductive homo- and co-polymerization of dibutyldichlorosilane or dibutyldichlorogermane with dichlorodimethylsilane were also carried out using Mg electrodes to give the corresponding copolymers in 6-44% yield. The number average molecular weights were 3000-4600. The copolymers showed lambda(max) at 308 and 286 nm. The epsilon(max) per dibutylsilylene, dibutylgermylene or dimethylsilylene units were calculated to be 6300 and 1600. The epsilon(max) value of copolymer with SiSiGe sequences was found to be much higher than those of copolymers having random sequences. A large difference of the epsilon(max) values between the silylene-germylene copolymers is probably due to the conformational difference of the polymer main chain.
  • M Ishifune; Y Kogai; H Iijima; Y Kera; N Yamashita; S Kashimura
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY MARCEL DEKKER INC A41 (4) 373 - 386 1060-1325 2004 
    Electroreductive copolymerization of 1,4-bis(chloromethylphenylsilyl)benzene with dichlorodimethylsilane, was carried out under constant current conditions, using Mg electrodes, to give the corresponding copolymers having (disilanylene)phenylenes and dimethylsilylene units in 40-71% yield. The resulting copolymers having dimethylsilylene units showed solubility in common organic solvents. The (disilanylene) phenylene units were predominantly included in the resulting copolymers. The molecular weight determined by gel permeation chromatography (GPC) was 17402900 depending on the units composition, and all elution profiles showed broad monomodal molecular weight distributions. The copolymers showed characteristic strong UV absorption bands (lambda(max) at 250nm. Extinction coefficients (epsilon(max)) per (disilanylene)phenylene or silylene units were calculated to be 12,340-13,750, and their extinction coefficients increased with an increase of (disilanylene)phenylene units. The temperatures of 10% wt loss of the copolymers were observed at 3 80 - 395degreesC and the weight loss at 500degreesC was 33.0-34.3%. The thermal properties of the copolymers were found to depend on their molecular weights and the content of (disilanylene)phenylene units.
  • M Ishifune; H Yamashita; Y Kera; N Yamashita; K Hirata; H Murase; S Kashimura
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 48 (17) 2405 - 2409 0013-4686 2003/07 
    Regioselective electroreduction of the aromatics, including methoxybenzenes, by using LiClO4 as a supporting electrolyte in an aprotic solvent (THF) containing alcoholic proton donors such as t-BuOH was successfully achieved to afford the corresponding 1,4-cyclohexadienes regioselectively in high yield. The electrolysis can, be performed under constant current conditions at ambient temperature. The effect of electrode materials was remarkable, that is, the use of Mg electrodes gave the best result. Moreover in the presence of t-BuOD instead of t-BuOH, the deutrated 1,4-cyclohexadienes were obtained in high deuterium incorporation at 1- and 4-positions. A direct electron transfer to the aromatics is unlikely, and it is reasonable that the solvated Li(0), which is generated by the cathodic reduction of LiClO4, is intermediately involved in the electron transfer with being assisted by the anodically generated Mg2+ as an electron transfer catalyst. (C) 2003 Elsevier Science Ltd. All rights reserved.
  • M Ishifune; H Yamashita; M Matsuda; Y Kera; N Yamashita; S Kashimura
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 48 (13) 1879 - 1884 0013-4686 2003/06 
    The electroreduction of methyl decanoate (1) by using alkali metal ion-free BU4NClO4 as a supporting electrolyte and platinum as anode and cathode was carried out in the presence of several kinds of alkali metal ion sources. The use of BU4NClO4 as a supporting electrolyte without alkali metal ions gave only a trace amount of the reduced product. The addition of 0.05 equiv. of LiClO4 or NaClO4 into this electroreduction system gave the reduction product, 2-alkoxytetrahydrofurans 5 in ca. 20% yield. In this electrolysis, the ligand effect of the alkali metal ion sources was remarkably noted, that is, the electroreduction using sodium ion-crown ether complexes, especially, sodium ion-the polymeric crown ether ligands such as poly(vinylbenzo-15-crown-5-co -styrene) complex, greatly increased the efficiency of the electroreduction. It is plausible that alkali metal (0) species are electrogenerated from alkali metal ions and react as active reductants to reduce the aliphatic esters and the mediatory system is established in this electrolysis system. (C) 2003 Elsevier Science Ltd. All rights reserved.
  • S Kashimura; H Yamashita; Y Murai; Y Kera; N Yamashita; H Murase; M Ishifune
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 48 (1) 7 - 10 0013-4686 2002/11 
    Electroreduction of aliphatic esters in THF was found to be promoted by the catalytic amount of porphine-magnesium(II) complexes and afforded 2-alkoxytetrahydrofuran derivatives, the coupling products between alkoxide anions formed by the electroreduction of aliphatic esters and THF cation generated by the anodic oxidation of the solvent (THF). In this reaction, chlorophyll a extracted from Trifolium repens L was remarkably effective. In addition, lanthanide metal(III) ions such as samarium trichloride were also found to be effective for the electroreduction of aliphatic esters. (C) 2002 Elsevier Science Ltd. All rights reserved.
  • Shigenori Kashimura; Yoshihiro Murai; Yoshihiro Tamai; Ryuich Hirose; Manabu Ishifune; Hirokazu Iwase; Hajime Yamashita; Natsuki Yamashita; Hiroya Kakegawa
    Electrochimica Acta 46 (20-21) 3301 - 3307 0013-4686 2001/07 [Refereed]
     
    A comparative cyclic voltabsorptometric study was carried out for polyaniline (PAn) films prepared by electrochemical polymerization and vacuum thermal evaporation. The absorption values were measured at different characteristic wavelengths (895, 755, 665, 435, and 325 nm) corresponding to the individual absorption bands separated by us earlier from the spectra using the Alentsev-Fock method. Differential voltabsorptometric curves (dA/dt vs. potential (DCVA)) measured in aqueous HCl were compared with ordinary cyclic voltammetry (CVA). The experiments for different sweep rates were also compared. It was found that the DCVA peak at 895 nm corresponds perfectly to the CVA peak both in the electrosynthesized and the vacuum deposited PAn. The DCVA peak at 435 nm (cation-radicals) precedes the CVA peak (similar to the maximum of the EPR signal), while that at 755 nm (polarons or cation-radical dimers) lags behind the CVA peak. For the vacuum deposited films an intense intermediate DCVA and current peaks (at a bout 0.6 V vs. Ag/AgCl) are observed. The results are discussed in terms of the heterogeneous structure of PAn particularly, its specific features in the films prepared using different methods. © 2001 Elsevier Science Ltd. All rights reserved.
  • M Ishifune; H Yamashita; M Matsuda; H Ishida; N Yamashita; Y Kera; S Kashimura; H Masuda; H Murase
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 46 (20-21) 3259 - 3264 0013-4686 2001/07 
    Electroreduction of aliphatic esters to form 2-alkoxytetrahydrofurans was achieved by using a new paired electrolysis system, that consists of the cathodic reduction of aliphatic esters and the anodic oxidation of the solvent (THF). It was also found that the presence of magnesium ion in the electrolyte promoted the electroreduction of aliphatic esters remarkably. In fact, the electroreduction of aliphatic esters was found to proceed toward 2-alkoxytetrahydrofurans by using a platinum cathode and anode in the presence of anodically dissolved magnesium ions. (C) 2001 Elsevier Science Ltd. All rights reserved.
  • S Kashimura; Y Murai; Y Tamai; R Hirose; M Ishifune; H Iwase; H Yamashita; N Yamashita; H Kakegawa
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 46 (20-21) 3265 - 3268 0013-4686 2001/07 
    Modification of the surface of carbon fiber (CF) with hydroxyl groups was attained by the indirect oxidation of CF with radical NO3. generated by the anodic oxidation of NO3-. This modified CF electrode showed quite interesting selectivity in the electroreduction of acetophenone. (C) 2001 Elsevier Science Ltd. All rights reserved.
  • S Kashimura; M Ishifune
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN SOC SYNTHETIC ORGANIC CHEM JPN 58 (10) 966 - 974 0037-9980 2000/10 
    The electroreduction of organochlorosilanes was carried out by using magnesium cathode and anode in a single compartment cell affording oligosilanes, polysilanes, and polycarbosilanes, The electroreductive coupling of organochlorosilanes gave the corresponding disilanes in high yield, The cross-coupling of chloroorganosilanes with dichloroorganosilanes under the same reaction conditions produced various types of oligosilanes such as trisilanes, tetrasilanes, and pentasilanes. This procedure was successfully applied to the stepwise elongation of silicon-silicon chains. The high efficiency of this electroreductive silicon-silicon bond formation reaction enabled the electroreductive synthesis of poly (alkylarylsilane)s having high molecular weight ((M) over barn=5200-31000, (M) over barw/(M) over barn=1.4-1.8). The electroreductive polymerization of the dichlorosilanes bearing various types of functional groups was also carried out to afford the functionalized polysilanes. Moreover, the electroreductive polymerization of dichlorooligosilanes was successfully applied to the synthesis of sequence-ordered polysilanes. This electroreductive method was also applicable to the synthesis of poly-p-(disilanylene)phenylenes and silane-germane copolymers. The effects of electrode material, monomer concentration, amount of supplied electricity, and ultrasound were investigated in these reactions.
  • M Ishifune; S Kashimura; Y Kogai; Y Fukuhara; T Kato; HB Bu; N Yamashita; Y Murai; H Murase; R Nishida
    JOURNAL OF ORGANOMETALLIC CHEMISTRY ELSEVIER SCIENCE SA 611 (1-2) 26 - 31 0022-328X 2000/10 
    The stepwise elongation of Si-Si or Si-Ge chain was achieved by the electroreductive cross-coupling reaction of chlorohydrosilanes with dichlorooligosilanes using magnesium electrodes. The electroreductive cross-coupling reaction of chlorodimethylsilane (1) with dichlorodiphenylsilane (2) or dichlorodiphenylgermane (4), for instance, gave 1,2-dihydro-1,1,3,3-tetramethyl-2,2-diphenyltrisilane (3) or bis(hydrodimethylsilyl)germane (5) in good yield. Compounds 3 and 5 were readily transformed to the corresponding 1,3-dichlorotrisilane (6) and bis(chlorosilyl)germane (7), respectively. The electroreductive polymerization of the resulting dichlorooligosilanes using magnesium electrodes in tetrahydrofuran was successfully applied to the synthesis of sequence-ordered polysilanes. (C) 2000 Elsevier Science S.A. All rights reserved.
  • XD Zhong; M Ishifune; N Yamashita
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY TAYLOR & FRANCIS INC 37 (1-2) 49 - 63 1060-1325 2000 
    Copolymerization of acrylamide (AAm) with styrene (St) was carried out in the presence of methyl ethyl ketone (MEK), methyl isopropyl ketone (MIK) and t-butyl methyl ketone (tBMK) without any conventional initiator in tetrahydrofuran (THF) at 60 degrees C. The copolymerization of AAm with St proceeded readily in the presence of the MEK, MIK, and tBMK, while no copolymerization of AAm with St proceeded in the absence of these ketones under the same conditions and no homo-polymerization of St proceeded even in the presence of the ketones. The reactivity ratio of monomer AAm (r(1)) is smaller than that of St (r(2)) in all of the copolymerization systems, and increases as the order: MEK < MIK < tBMK. The conversion of the copolymerizations increases as the same order described above. The interaction between AAm and the ketones with hydrogen bonding was estimated by the shifts of the absorption bands of the amide carbonyl and N-H groups in the infrared spectra. From the results of the copolymerization between AAm and St, the greater the shift in the N-H absorption, the higher the amount of AAm found in the copolymer.
  • S Kashimura; M Ishifune; H Kakegawa; Y Murai; H Iwase; Y Tamai; N Yamashita; T Shono
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 67 (12) 1117 - 1119 1344-3542 1999/12 
    Introduction of hydroxyl group on the surface of carbon fiber was attained by the indirect anodic oxidation of carbon fiber with NO3. generated by anodic oxidation of NO3-. This hydroxyl group was found to have enough chemical reactivity with electrophiles and the modification of carbon fiber surface was attained by using the reactivity of the hydroxyl group.
  • S Kashimura; Y Murai; M Ishifune; H Masuda; M Shimomura; H Murase; T Shono
    ACTA CHEMICA SCANDINAVICA MUNKSGAARD INT PUBL LTD 53 (10) 949 - 951 0904-213X 1999/10
  • S Kashimura; M Ishifune; N Yamashita; HB Bu; M Takebayashi; S Kitajima; D Yoshiwara; Y Kataoka; R Nishida; S Kawasaki; H Murase; T Shono
    JOURNAL OF ORGANIC CHEMISTRY AMER CHEMICAL SOC 64 (18) 6615 - 6621 0022-3263 1999/09 
    The electroreduction of alkylaryldichlorosilane carried out with Mg cathode and anode in a single compartment cell gave high molecular weight poly(alkylarylsilane) (M-n = 5200-31000, M-w/M-n = 1.4-1.8) in 5-79% yield. The effects of electrode material, monomer concentration, amount of supplied electricity, and ultrasound were investigated. This electroreductive method was also successfully applied to the synthesis of polygermanes, silane-geramane copolymers, and also poly[p- (disilanylene)phenylenes].
  • M Ishifune; S Kashimura
    ELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 67 (8) 870 - 874 1344-3542 1999/08
  • XD Zhong; M Ishifune; N Nakao; N Yamashita
    JOURNAL OF MATERIALS SCIENCE KLUWER ACADEMIC PUBL 34 (8) 1761 - 1765 0022-2461 1999/04 
    Polymerizations of acrylamide (AAm) were carried out in the presence of methyl ethyl ketone (MEK), methyl isopropyl ketone (MIK) and t-butyl methyl ketone (tBMK) in tetrahydrofuran at 30 degrees C. It was found that the rate of polymerization (R-p) increased according to this order: MEK< MIK<tBMK in the case of AAm, but in the methyl methacrylate (MMA) system the order was as followed: MEK>MIK>tBMK. The maximum value of R-p for AAm reached the point of equimolar ratio of AAm to ketone in any of the three systems. The polymerization was confirmed to proceed through radical mechanism. Effects of temperature on the R-p were discussed in a temperature range of 30-60 degrees C. The overall activation energy (E-a) was estimated to be 52.6, 35.7, and 22.7 KJ/mol for MEK, MIK, and tBMK, respectively. No acceleration of the polymerization of N,N-dimethylacrylamide system was observed even in the presence of these ketones. The participation of -NH2 in the complexation of monomer with the ketones is proposed in the initiation of this radical polymerization. (C) 1999 Kluwer Academic Publishers.
  • XD Zhong; M Ishifune; N Yamashita
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY MARCEL DEKKER INC A36 (2) 275 - 286 1060-1325 1999 
    Homopolymerization of acrylamiide (AAm) initiated with cyclohexanone (CHn) was carried out in TT-IF at 75 degrees C under argon atmosphere. It was found that the rate of polymerization (Rp) can be expressed by Rp = k[AAm](1.6)[CHn](0.6). The polymerization was confirmed to proceed through a radical-initiated mechanism from the resulting polymerization equation. The effects of temperature of the Rp were discussed in the temperature range of 70-80 degrees C. The overall activation energy (Ea) was estimated to be 138.9 kJ/mol. 2,6-Dimethylcyclohexnone (DMCHn) was also applied instead of CHn. The acceleration effect of DMCHn on the polymerization was higher than that of CHn in the case of AAm, but was lower in the case of methyl methacrylate under the same conditions. No effect of CHn on the polymerization of N,N-dimethylacrylamide was found under these conditions. The participation of-NH2 in the complexation of a monomer with CHn is proposed to induce this radical polymerization.
  • XD Zhong; M Ishifune; N Nakao; N Yamashita
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY TAYLOR & FRANCIS INC A36 (2) 287 - 303 1060-1325 1999 
    Template polymerization of acrylamide (AAm) in the presence of several homo- and copolymers such as poly(methyl vinyl ketone) (poly-MVK), poly(methyl methacrylate) (poly-MMA), copoly(MVK-styrene) and copoly(MMA-styrene) was carried out in THF at 30 or 40 degrees C. The rate of polymerization (Rp) of AAm was greatly enhanced by the presence of a template polymer. However, a small amount of styrene (St) units in the template polymer markedly decreased the Rp of AAm. It was assumed that the contamination of the St units in the chain of the template polymer impeded the continuous absorption of AAm monomers onto the active sites of the template polymer. Also, the effect of stereo-regularity of poly-MMA on the Rp and the number-average molecular weight (Mn) of the resulting poly-AAm was investigated. The syndiotactic poly-MMA had pronounced influence on the Rp of AAm and Mn of poly-AAm comparing with the isotactic poly-MMA. This effect can be explained in the terms of the different conformational features of the two tacticity forms of templates.
  • 石船 学; 柏村成史
    Electrochemistry 電気化学会 67 (8) 870 - 874 1344-3542 1999
  • S Kashimura; M Ishifune; Y Murai; H Murase; M Shimomura; T Shono
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 39 (34) 6199 - 6202 0040-4039 1998/08 
    Electroreduction of aliphatic amides (RCONMe2) with Mg electrode in the presence of chlorotrimethylsilane (TMSCl) has been found to give the coupling products [R(TMSO)C=C(NMe2)R] and hydrolysis of the products affords the corresponding alpha-amino ketones [RCOCH(NMe2)R] in excellent yields. (C) 1998 Elsevier Science Ltd. All rights reserved.
  • Xu-Dong Zhong; Manabu Ishifune; Nobuaki Nakao; Natsuki Yamashita
    Journal of Japan Oil Chemical Society Japan Oil Chemists' Society 47 (9) 845 - 859 1341-8327 1998 
    Reactions of acrylamide (AAm) were carried out in the presence of cyclohexanone, methyl ethyl ketone and its derivatives in tetrahydorafuran at various reaction temperatures. Interactions between the carbonyl oxygen of ketones and the amide group were found to enhance the reactivity of AAm. No reactions of AAm occurred in the absence of the ketones under the same condition. Interactions of carbonyl group in the ketone with AAm could be examined directly using the 13C NMR spectra of a mixture of AAm and t-butyl methyl ketone or poly (methyl vinyl ketone).
  • S Kashimura; M Ishifune; H Maekawa; Y Yamaguchi; Y Murai; S Kitajima; T Shono
    DENKI KAGAKU ELECTROCHEMICAL SOC JAPAN 65 (6) 479 - 482 0366-9297 1997/06
  • S Kashimura; M Ishifune; HB Bu; M Takebayashi; S Kitajima; D Yoshihara; R Nishida; S Kawasaki; H Murase; T Shono
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 38 (26) 4607 - 4610 0040-4039 1997/06 
    Polysilanes having hydroxyl and related functional groups have been synthesized by the electroreduction of appropriate dichlorosilanes with Mg electrode, and a vinyl polymer which has oligosilane unit in the side chain has also been synthesized. (C) 1997 Elsevier Science Ltd.
  • S Kashimura; Y Murai; M Ishifune; A Takatani; M Fujita; K Nakajima; E Sato; K Fujimoto; N Yamashita; T Shono
    ELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 42 (13-14) 2241 - 2245 0013-4686 1997 
    The electroreduction of polyacrylamide derivatives in DMF using tetraalkylammonium salts (R4NX) as supporting electrolytes has been found to yield the corresponding anionic species possessing interesting reactivities as electrogenerated bases (EGBs). The homopolymer of n-methylacrylamide (MAAm) and its copolymers with N,N-dimethylacrylamide (DMAAm) and styrene (St) were used as polymeric probases and the reactivity of the resulting polymer EGBs was investigated. The polymer EGB prepared from the copolymer of MAAm with DMAAm [copoly(MAAm-DMAAm)] containing 65% of MAAm unit gave the best result in the trichloromethylation of alpha,beta-unsaturated esters (89%). It was also found that polymeric probases were easily recovered by reprecipitation and they were repeatedly useable as probases. (C) 1997 Published by Elsevier Science Ltd.
  • S Kashimura; M Ishifune; Y Murai; T Shono
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 37 (37) 6737 - 6740 0040-4039 1996/09 
    Cathodic coupling of ketones with 3-(trimethylsiiyl)allyl alcohols has been found to give trimethylsilyl substituted 1,3-diols with high diastereoselectivity, whereas that with 2-(trimethylsilyl)allyl alcohols afforded homoallylic alcohols through the Peterson elimination of intermediately formed trimethylsilyl substituted 1,4-diols. Copyright (C) 1996 Elsevier Science Ltd
  • Organic Synthesis Using Chemically Reactive Magnesium Electrodes
    Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai
    Kagaku To Kogyo (Osaka) 70 (7) 285 - 292 1996
  • Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai
    Journal of Synthetic Organic Chemistry, Japan 54 (8) 675 - 685 1996
  • 柏村成史; 石船 学; 村井義洋
    科学と工業 大阪工研協会 70 (7) 285 - 292 0368-5918 1996
  • Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai
    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry Society of Synthetic Organic Chemistry 54 (8) 675 - 685 0037-9980 1996 
    Some synthetic electroorganic reactions promoted by chemically reactive electrodes (CRE) have recently been exploited and CRE is one of the most attractive new techniques in electroorganic chemistry (EOC). Altohugh the definition of CRE is not always clear at present, the role of electrode in CRE method is quite different from that in the conventional EOC. Namely, the role of electrode in the conventional EOC is generally just a donor or acceptor of an electron and it is not involved in the organic reaction as a reagent. On the other hand, in CRE method, some electrode mterials made of chemically reactive materials such as Mg, Al, and Zn are involved in the reaction as reagents and promote unique reactions which are not attained under the usual conditions of EOC. In this article, some synthetic reactions using CRE are described, and the main contents of the article are as follows : 1) Electroreuction of aliphatic ester and amide and related C-C bond forming reactions, 2) Si-Si and Ge Ge bonds formation reactions and their application to the synthesis of ploysilane and polygermane high polymers, 3) Coupling of dienes and styrenes with aliphatic esters, 4) Reduction of aromatic compounds, 5) Generation of highly reactive metals (Electrogenerated metals).
  • S Kashimura; M Ishifune; Y Murai; T Shono
    CHEMISTRY LETTERS CHEMICAL SOC JAPAN (4) 309 - 310 0366-7022 1996 
    Cathodic coupling of ketones with ethoxydimethylvinylsilanes takes place regioselectively at the position beta to ethoxydimethylsilyl group and affords 1-oxa-2-silacyclopentane derivatives as products which are easily transformed to 1,3-diols by oxidative desilylation.
  • S KASHIMURA; Y MURAI; M ISHIFUNE; H MASUDA; H MURASE; T SHONO
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 36 (27) 4805 - 4808 0040-4039 1995/07 
    It has been found in this study that electroreduction of aliphatic ester (1) with Mg electrode leads to the formation of the corresponding 1,2-diketone under aprotic conditions, whereas bis(trimethylsilyloxy)alkene is afforded through acyloin condensation when the reduction is carried out in the presence of chlorotrimethylsilane.
  • S KASHIMURA; M ISHIFUNE; Y MURAI; N MORIYOSHI; T SHONO
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 36 (28) 5041 - 5044 0040-4039 1995/07 
    The electroreduction of 6-trimethylsilyl-6-hepten-2-one afforded cis-1-methyl-3-trimethylsilyl cyclohexanol, and gamma-trimethylsilyl alcohols were yielded as the intermolecular coupling products when the cathodic reduction of ketones was carried out in the presence of unsaturated silanes.
  • T SHONO; M CHUANKAMNERDKARN; H MAEKAWA; M ISHIFUNE; S KASHIMURA
    SYNTHESIS-STUTTGART GEORG THIEME VERLAG (9) 895 - 897 0039-7881 1994/09 
    When NO3- is electrochemically oxidized in the presence of a variety of terminal and 1,2-disubstituted olefins 1 in a mixed solvent system (MeCN:H2O:Et(2)O = 10:2: 1), a radical NO3. is generated from NO; and nitrate esters 3 are formed by a new coupling reaction of the olefin with the radical. The products 3 can be further transformed into the corresponding alcohols 4 and alkyl iodides 5. Under the same reaction conditions, 1,1-di- and 1,1,2-trisubstituted olefins 6 do not give nitrate esters but afford oxazolne derivatives 7. (1S,5S)-(-)-beta-Pinene (13) is diastereoselectively transformed into (1S,2R,5S)-( -)-myrtanol (14) by this technique.
  • T SHONO; Y YAMAMOTO; K TAKIGAWA; H MAEKAWA; M ISHIFUNE; S KASHIMURA
    CHEMISTRY LETTERS CHEMICAL SOC JAPAN (6) 1045 - 1048 0366-7022 1994/06 
    A radical NO3. generated by anodic oxidation of NO3- was found to be an effective species to the oxidation of ethers to the corresponding carboxylic acids and ketones, and this reaction was successfully applied to the synthesis of dihydrojasmone.
  • Natsuki Yamashita; Manabu Ishifune; Tatsuo Tsuneka; Lun-Shin Wei
    Journal of the Faculty of Science and Technology Kinki University Kinki University 30 (30) 69 - 75 0386-4928 1994
  • Manabu Ishifune; Jun-ya Watanabe; Kazuhiko Shimomiya; Natsuki Yamashita; Shigenori Kashimura
    Journal of the Faculty of Science and Technology Kinki University Kinki University 30 (30) 74 - 84 0386-4928 1994
  • T SHONO; Y MORISHIMA; N MORIYOSHI; M ISHIFUNE; S KASHIMURA
    JOURNAL OF ORGANIC CHEMISTRY AMER CHEMICAL SOC 59 (2) 273 - 275 0022-3263 1994/01 
    Cathodic coupling of ketones with allylic alcohols has been found to take place with high regio- and stereoselectivities at the position gamma to the hydroxyl group to afford the corresponding 1,4-diols.
  • T TSUNEKA; M ISHIFUNE; N YAMASHITA; S KASHIMURA; LS WEI
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY MARCEL DEKKER INC A31 (9) 1169 - 1176 1060-1325 1994 
    Polymerizations of acrylamide (AAm) in the presence of several homo- and copolymers such as poly(methyl vinyl ketone) (poly-MVK) and poly(N-vinylpyrrolidone) (poly-VPr), copoly(MVK-St), and copoly(VPr-St) were carried out in tetrahydrofuran (THF) at 30-degrees-C without catalyst. Similarly, the polymerizations of AAm in the presence of poly(methyl methacrylate) were also carried out in THF at 40-degrees-C. The increasing concentration of these matrix polymers increased the polymerizability of AAm. Number-average molecular weight (MBAR(n)) of the resulting poly-AAm were close to the molecular weight (MBAR(n)) of the matrix polymers. The polymerizability of N-methylacrylamide was lower than that of AAm, and N,N-dimethylacrylamide did not polymerize at all. From these results it appeared that these matrix polymerizations proceeded by the interaction between the carbonyl group in the matrix polymer and the amide group of the AAm monomer.
  • T SHONO; M ISHIFUNE; H KINUGASA; S KASHIMURA
    JOURNAL OF ORGANIC CHEMISTRY AMER CHEMICAL SOC 57 (21) 5561 - 5563 0022-3263 1992/10 
    The cathodic cyclocoupling of 1,3-dienes 1 with aliphatic esters 2 is promoted by a magnesium electrode and yields homologs of 3-cyclopentenol. Under similar reaction conditions, the coupling of styrenes with 2 affords 2-phenylcyclopropanol derivatives, and this coupling reaction has been successfully applied to the synthesis of ar-dihydroturmerone and curcumone.
  • T SHONO; T NOZOE; Y YAMAGUCHI; M ISHIFUNE; M SAKAGUCHI; H MASUDA; S KASHIMURA
    TETRAHEDRON LETTERS PERGAMON-ELSEVIER SCIENCE LTD 32 (8) 1051 - 1054 0040-4039 1991/02 
    Electroreduction of cycloheptatriene or substituted cycloheptatrienes in the presence of an alkyl halide was found to be a unique and effective method for introducing regioselectively an alkyl group into seven-membered ring system and it was applied to a new synthesis of beta-thujaplicin (hinokitiol).
  • T SHONO; M ISHIFUNE; T OKADA; S KASHIMURA
    JOURNAL OF ORGANIC CHEMISTRY AMER CHEMICAL SOC 56 (1) 2 - 4 0022-3263 1991/01 
    A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent. In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.
  • T SHONO; S KASHIMURA; M ISHIFUNE; R NISHIDA
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS ROYAL SOC CHEMISTRY (17) 1160 - 1161 0022-4936 1990/09
  • T SHONO; M ISHIFUNE; S KASHIMURA
    CHEMISTRY LETTERS CHEMICAL SOC JAPAN (3) 449 - 452 0366-7022 1990/03

Books etc

  • New Trends in Electoorganic Synthesis
    (監 修)淵上寿雄,跡部真人,稲木信介 (著 者)石船 学 (Joint work第17章 高分子修飾電極による電解反応)シーエムシー出版 2021/11
  • New Polymers for Special Applications, Chapter 11 "Electroreductive synthesis of polysilanes with ordered sequences"
    石船 学 (Joint work)ISBN 978-953-51-0744-6 2012/08
  • はじめてみようスペクトル解析-MS・FTIR・500MHz NMR-
    三共出版 2007 9784782705339
  • Encyclopedia of Electrochemistry, Volume 8 Organic Electrochemistry "Reduction of Oxygen-containing Compounds"
    WILEY-VCH (Edited by H.J.Schaefer) 2004 3527304002
  • 有機電解合成の新展開 「ポリシラン類の電解合成」
    シーエムシー出版(監修:淵上寿雄) 2004 4882314452
  • Encyclopedia of Electrochemistry, Volume 8 Organic Electrochemistry "Reduction of Oxygen-containing Compounds"
    WILEY-VCH (Edited by H.J.Schaefer) 2004 3527304002
  • New Developments in Organic Electrosynthesis "Electroreductive Synthesis of Polysilanes"
    CMC (Supervisor: Toshio Fuchigami) 2004 4882314452
  • マイクロリアクター-新時代の合成技術- 「熱化学工業に用いられる微細構造装置」(翻訳)
    シーエムシー出版(監修:吉田潤一) 2003 4882313855
  • Microreactors, Epoch-making Technology for Synthesis
    CMC (Supervisor: Jun-ichi Yoshida) 2003 4882313855
  • Novel Trends in Electroorganic Synthesis "Electroreductive Synthesis of Sequence-Ordered Polysilanes Using Mg Electrodes"
    Springer-Verlag Tokyo (Edited by Sigeru Torii) 1998 4431702210
  • Novel Trends in Electroorganic Synthesis "Electroreductive Synthesis of Sequence-Ordered Polysilanes Using Mg Electrodes"
    Springer-Verlag Tokyo (Edited by Sigeru Torii) 1998 4431702210
  • Novel Trends in Electroorganic Synthesis "Electroreduction of Aliphatic Esters Using Mg and Sm as Mediators" "Electroreduction of Organic Compounds Using Chemically Reactive Mg Electrode"
    KODANSHA Tokyo (Edited by Sigeru Torii) 1995 4062075032
  • Novel Trends in Electroorganic Synthesis "Electroreduction of Aliphatic Esters Using Mg and Sm as Mediators" "Electroreduction of Organic Compounds Using Chemically Reactive Mg Electrode"
    KODANSHA Tokyo (Edited by Sigeru Torii) 1995 4062075032

Conference Activities & Talks

  • TEMPO 構造を側鎖に有する光学活性熱応答性高分子修飾炭素電極の調製  [Not invited]
    吉田皓一; 石船学
    第45回有機電子移動化学討論会  2021/06
  • パラジウム錯体および熱応答性高分子を同時に固定化した炭素繊維の調製  [Not invited]
    吉田瞬也; 石船学
    第45回有機電子移動化学討論会  2021/06
  • TEMPO構造を有する熱応答性高分子修飾炭素電極を用いた酸化反応  [Not invited]
    吉田皓一; 石船学
    日本化学会第101春季年会  2021/03
  • 炭素繊維表面へのパラジウム錯体および熱応答性高分子の固定化  [Not invited]
    吉田 瞬也; 石船 学
    日本化学会第101春季年会  2021/03
  • 電子ドナー部位を有する光学活性熱応答性高分子による電荷移動相互作用  [Not invited]
    米田 尚輝; 石船 学
    日本化学会第101春季年会  2021/03
  • 包接化合物を側鎖に含む温度応答性高分子の合成およびその包接能  [Not invited]
    西島 悠起; 石船 学
    日本化学会第101春季年会  2021/03
  • Synthesis and phase transition behavior of thermoresponsive block polymers bearing the porphyrin side chains.  [Not invited]
    白井 晶子; 石船 学
    高分子学会・高分子学会関西支部  2013/07  神戸市  高分子学会・高分子学会関西支部
  • Synthesis of Thermoresponsive Polymers Having Crown Ether Structures as Its Side Chains and Their Phase Transition Behavior in the Presence of Metal Ions.  [Not invited]
    中村 郁文; 小山 祐佳; 西田 潤平; 石船 学
    高分子学会・高分子学会関西支部  2013/07  神戸市  高分子学会・高分子学会関西支部
  • ジメチルアミノフェニル基を有するジクロロシランの電解挙動  [Not invited]
    石船 学; 櫻本 尚己
    第37回有機電気化学討論会/講演要旨集pp.78-79.  2013/06  電気化学会有機電気化学研究会・有機電子移動化学研究会(岡山市)  第37回有機電気化学討論会/講演要旨集pp.78-79.
  • 電解法を用いたアントラセン部位を含むポリカルボシランの合成  [Not invited]
    石船 学; 杉本 美由紀
    第37回有機電子移動化学討論会/講演要旨集pp.76-77.  2013/06  電気化学会有機電気化学研究会・有機電子移動化学研究会(岡山市)  第37回有機電子移動化学討論会/講演要旨集pp.76-77.
  • リビングラジカル重合および電解重合を利用した熱応答性高分子固定化ポリピロール薄膜の調製  [Not invited]
    漣 大輔; 西尾 彰浩; 石船 学
    第37回有機電子移動化学討論会/講演要旨集pp.42-43.  2013/06  電気化学会有機電気化学研究会・有機電子移動化学研究会(岡山市)  第37回有機電子移動化学討論会/講演要旨集pp.42-43.
  • 花野 恵典; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • 西尾 彰浩; 河村 崇; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • 森 脩二; 秋山 健造; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • 杉本 美由紀; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • 橋本 紗矢香; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • 靍谷 一真; 石船 学
    日本化学会第93春季年会  2013/03  日本化学会(草津市)  日本化学会第93春季年会
  • Synthesis and UV absorption behavior of thermoresponsive polymers bearing the porphyrin side chains  [Not invited]
    石船 学; 白井晶子
    第58回高分子研究発表会  2012/07  神戸  第58回高分子研究発表会
  • Synthesis of thermoresponsive polycarbosilanes by using functionalized polysilanes as macroinitiators  [Not invited]
    石船 学; 秋山健造; 森 脩二
    第58回高分子研究発表会  2012/07  神戸  第58回高分子研究発表会
  • Synthesis of the block copolymer cosisting of thermoresponsive polymer chains and water-soluble polymer chains and its dissolving behavior in the presence of organic substrates  [Not invited]
    石船 学; 花野恵典
    第58回高分子研究発表会  2012/07  神戸  第58回高分子研究発表会
  • Anodic oxidation of the graphite surface and grafting of thermoresponsive polymers by using ATRP method  [Not invited]
    石船 学; 西尾彰浩; 工藤智也
    第36回有機電子移動化学討論会  2012/06  府中  第36回有機電子移動化学討論会
  • Preparation of the platinum electrode modified with azacrown ether ligands  [Not invited]
    石船 学; 中村郁文; 山下 創
    第36回有機電子移動化学討論会  2012/06  府中  第36回有機電子移動化学討論会
  • Preparation of the thermoresponsive polymer grafted electrode bearing TEMP units  [Not invited]
    石船 学; 日置友哉; 漣 大輔; 柏村 成史
    第36回有機電子移動化学討論会  2012/06  府中  第36回有機電子移動化学討論会
  • Synthesis and sequence control of the polymer complexes having more than two different metalloporphyrin side chains  [Not invited]
    石船 学; 野原一樹; 森川 愛
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Synthesis of new optically active thermoresponsive polymers and their thermoresponsive behavior in aqueous solutions of amino acid derivatives  [Not invited]
    石船 学; 松島綾香
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Synthesis and catalytic activity of the thermoresponsive polymer having pyrrolidine side chains as chiral and base functionalities  [Not invited]
    石船 学; 上向井 徹
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Functionalization of the end groups of the electrochemically synthesized polysilanes and their utilization as macroinitiators  [Not invited]
    石船 学; 森 脩二; 秋山健造
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Electroreductive synthesis of the polysilanes having highly functionalized side chains  [Not invited]
    石船 学; 米山聡一郎
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Preparation of the thermoresponsive polyacrylamides - grafted electrodes  [Not invited]
    石船 学; 漣 大輔; 日置友哉
    日本化学会第92春季年会  2012/03  横浜  日本化学会第92春季年会
  • Introduction of fullerene units into the electrochemically synthesized polysilanes  [Not invited]
    石船 学; 米山聡一郎
    第35回有機電子移動化学討論会  2011/06  福岡市  第35回有機電子移動化学討論会
  • Preparation of metalloporphyrin complexes having azobenzene moieties and their fixation on the electrodes  [Not invited]
    石船 学; 野原一樹
    第35回有機電子移動化学討論会  2011/06  福岡市  第35回有機電子移動化学討論会
  • Preparation of novel thermoresponsive polymer-grafted polymers by using polymer reactions with electroreductively synthesized polysilanes  [Not invited]
    石船 学; 秋山健造; 都築優介
    第35回有機電子移動化学討論会  2011/06  福岡市  第35回有機電子移動化学討論会
  • Preparation of optically active thermoresponsive polymer-grafted polypyrroles  [Not invited]
    石船 学; 漣 大輔; 工藤智也; 柏村 成史
    第35回有機電子移動化学討論会  2011/06  福岡市  第35回有機電子移動化学討論会
  • Substituent Effect and End Group Controll in the Electroreductive Polymerization of Dichlorosilanes  [Not invited]
    石船 学; 山下恭平; 都築優介
    第60回高分子学会年次大会  2011/05  高分子学会(大阪市)  第60回高分子学会年次大会
  • Synthesis and Swelling Behavior of Thermoresponsive Cross-linked Polymers Having Crown-ether Structures as Their Side Chains  [Not invited]
    石船 学; 西田潤平
    第60回高分子学会年次大会  2011/05  高分子学会(大阪市)  第60回高分子学会年次大会
  • Synthesis of the polymer having calixarene structures on its side chains and fixation to platinum electrodes  [Not invited]
    石船 学; 杉原啓之
    第60回高分子学会年次大会  2011/05  高分子学会(大阪市)  第60回高分子学会年次大会
  • Synthesis and phase transition behavior of new thermoresponsive polymers containing azobenzene moieties  [Not invited]
    石船 学; 村辻朋幸
    第60回高分子学会年次大会  2011/05  高分子学会(大阪市)  第60回高分子学会年次大会
  • Synthesis of new optically active thermoresponsive polymers and stereoselective trapping of organic substrates into their polymer field generated at LCST  [Not invited]
    石船 学; 濵中 貴大; 鳥﨑 賢史
    第56回高分子研究発表会  2010/07  神戸  第56回高分子研究発表会
  • Concentraton effect of hydroxyl ions by the thermoresponsive polymers having crown ether-alkali metal ions complexes as their side chains  [Not invited]
    石船 学; 西田 潤平
    第56回高分子研究発表会  2010/07  神戸  第56回高分子研究発表会
  • Utilization of thermoresponsive polymers having imidazolyl groups as their side chains as polymer catalysts  [Not invited]
    石船 学; 辻 純弥
    第56回高分子研究発表会  2010/07  神戸  第56回高分子研究発表会
  • 電解修飾法を利用したパラジウム錯体固定化とHeck反応における触媒活性評価  [Not invited]
    石船 学; 渡邊 真希; 柏村 成史
    第34回有機電子移動化学討論会  2010/06  堺市  第34回有機電子移動化学討論会
  • 高配位ケイ素中心を有するジクロロシランの電解重合  [Not invited]
    石船 学; 山下 恭平; 真 千加
    第34回有機電子移動化学討論会  2010/06  堺市  第34回有機電子移動化学討論会
  • 電解調製ポリシランをマクロイニシエーターとするジクロロシランのブロック共重合  [Not invited]
    石船 学; 真 千加; 柏村 成史
    第34回有機電子移動化学討論会  2010/06  堺市  第34回有機電子移動化学討論会
  • Preparation of Metallo-porphyrin Complex Modified Electrode and Its Utilization to the Electroreductio of Aliphatic Esters  [Not invited]
    石船 学; 岩井 由実; 角谷 善美; 柏村 成史
    213th Meeting of the Electrochemical Society  2010/05  Phenix, USA  213th Meeting of the Electrochemical Society
  • Electroreductive Block Copolymerization of Dichlorosilanes in the Presence of Disilane Additives  [Not invited]
    石船 学; 真 千加; 柏村 成史
    217th Meeting of the Electrochemical Society  2010/04  Vancouver, Canada  217th Meeting of the Electrochemical Society
  • 複数種類の金属イオンを導入したメタロポルフィリン高分子錯体固定化修飾電極の調製  [Not invited]
    石船 学; 森川 愛; 岩井 由実
    第34回有機電子移動化学討論会  2010/03  堺市  第34回有機電子移動化学討論会
  • Synthesis of Thermoresponsive Polymers Having Imidazolyl Groups as a Side Chain and Their Utilization as Polymer Catalysis  [Not invited]
    石船 学; 辻 純弥
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Preparation of New Carbon-based Material Modified with TEMPO and Thermoresponsive Polymer  [Not invited]
    石船 学; 日置 友哉
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Preparation of Calixarene-modified Platinum Electrode  [Not invited]
    石船 学; 杉原 啓之
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Synthesis and Alkali Metal Ions Inclusion Behavior of Thermoresponsive Polymers Having Crown-ether Structure as Its Side Chain  [Not invited]
    石船 学; 西田 潤平
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Stereoselective Incorporation of Chiral Substrates by Thermoresponsive Polymers Having Chiral Amino-alcohol Structures as Their Side Chains  [Not invited]
    石船 学; 濵中 貴大; 中田 真利子; 鳥﨑 賢史
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Synthesis of the Dichlorosilane Having Pentacoodinated Silicon Center and Its Polymerizability under Electroreductive Conditions  [Not invited]
    石船 学; 山下 恭平; 真 千加
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Preparation of the Polymeric Metalloporphyrin Complexes Containing Different Metal Ions and their Fixation onto a Platinum Electrode  [Not invited]
    石船 学; 森川 愛; 岩井 由実
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Preparation of the Graphite Modified with the Palladium Pincer Complexes and Estimation of Their Catalytic Activity  [Not invited]
    石船 学; 渡邊 真希
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Preparation of the Thermoresponsive Polymer Grafted Graphite Electrodes by Using Living Radical Polymerization Method  [Not invited]
    石船 学; 工藤 智也; 前田 智美; 上向井 徹
    日本化学会第90春季年会  2010/03  東大阪市  日本化学会第90春季年会
  • Synthesis of thermoresponsive polymers having chiral amino alcohol structures as their side chains and stereoselective concentration of organic substrates into the polymer field generated at LCST  [Not invited]
    石船 学; 濵中 貴大; 鳥﨑 賢史
    第55回高分子研究発表会  2009/07  神戸  第55回高分子研究発表会
  • Organic reactions within the reaction field generated by the optically active thermoresponsive polymers in water  [Not invited]
    石船 学; 鳥﨑 賢史; 濵中 貴大
    第55回高分子研究発表会  2009/07  神戸  第55回高分子研究発表会
  • ジクロロシラン類の電解還元重縮合におけるポリシランの配列ならびに立体制御  [Not invited]
    石船 学; 真 千加; 柏村 成史
    第33回有機電子移動化学討論会  2009/06  横浜市  第33回有機電子移動化学討論会
  • Incorporation behavior and reactions of organic substrates in aqueous solution of chiral themoresponsive polymers  [Not invited]
    石船 学; 鳥﨑 賢史; 津稱鹿 勝博; 米澤 康
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Preparation of the thermoresponsive polymer grafted milled carbon fiber by using reversible addition fragmentation chain transfer (RAFT) polymerization technique  [Not invited]
    石船 学; 上向井 徹; 工藤 智也
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Synthesis of thermoresponsive polymers having chiral amino alcohol stractures as their side chains  [Not invited]
    石船 学; 濵中 貴大; 鳥﨑 賢史
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Preparation of the carbon fiber modified with the palladium SCS pincer complex by using electrochemical modification methods  [Not invited]
    石船 学; 渡邊 真希; 上向井 徹
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Fixation of the mediatory system using metalloporphyrin complexes on platinum electrodes  [Not invited]
    石船 学; 岩井 由実
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Electroreductive block copolymerization of organodichlorosilanes in the presence of disilane additives  [Not invited]
    石船 学; 真 千加; 上窪 一博
    日本化学会第89春季年会  2009/03  船橋市  日本化学会第89春季年会
  • Preparation of the Thermoresponsive Polymer Grafted Graphite Electrodes  [Not invited]
    石船 学; 上向井 徹; 工藤 智也
    日本化学会第89春季年会  2009  船橋市  日本化学会第89春季年会
  • Electrochemical Modification of Carbon Fibers with Redox Centers  [Not invited]
    石船 学; 上向井 徹; 中川 侑己
    The 9th International Symposium on Organic Reactions  2008/11  Chiayi, Taiwan  The 9th International Symposium on Organic Reactions
  • 熱応答性高分子固定化炭素繊維粉末の調製および評価  [Not invited]
    石船 学; 上向井 徹
    第32回有機電子移動化学討論会  2008/06  東大阪市  第32回有機電子移動化学討論会
  • メタロポルフィリン高分子錯体固定化修飾電極の調製とその評価  [Not invited]
    石船 学; 岩井 由実
    第32回有機電子移動化学討論会  2008/06  東大阪市  第32回有機電子移動化学討論会
  • ジシラン存在下ジクロロシラン類の電解ブロック共重合  [Not invited]
    石船 学; 真 千加
    第32回有機電子移動化学討論会  2008  東大阪市  第32回有機電子移動化学討論会
  • 反応性Mg電極を用いた芳香族エステル類の電極還元  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • PhMeSiCl2とビニルモノマーを用いた含ケイ素ポリマーの合成  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • ジシラン存在下ジクロロシラン類の還元重縮合およびブロック共重合  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • 熱応答性高分子固定化炭素繊維粉末の調製  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • メタロポルフィリン高分子錯体の調製および白金電極への固定化  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • 水溶媒中LCSTを有するポリマーによる有機化合物の取り込み挙動およびその反応  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • プロリノール側鎖を有する熱応答性高分子の合成  [Not invited]
    日本化学会第88春季年会(東京)  2008
  • メタロポルフィリン高分子錯体修飾電極の調製およびその評価  [Not invited]
    電気化学会第75回大会(甲府)  2008
  • Electroreduction of Aromatic Esters by Using Mg Electrodes  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Reductive Copolymerization of PhMeSiCl2 and Vinyl Monomers  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Electroreductive Polymerization and Block Copolymerization of Organodichlorosilanes in the Presence of Disilane Additives  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Preparation of the Thermoresponsive Polymer Grafted Milled Spherical Carbon Fibers  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Preparation of a Polymeric Metalloporphyrin Complex and Its Modification onto a Platinum Electrode  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Incorporation Behavior and Reactions of Organic Substrates in Aqueous Solution of the Polymer Having Lower Critical Solution Temperature  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Synthesis of Thermoresponsive Polymer Having Prolinol Structure as a Side Chain  [Not invited]
    The 88th Annual Meeting of the Chemical Society of Japan (Tokyo)  2008
  • Preparation and Characterization of the Electrodes Modified with Metalloporphyrin Polymer Complexes  [Not invited]
    The 75th Annual Meeting of the Electrochemical Society of Japan (Kofu)  2008
  • Preparation of Magnesium - Porphyrin Complexes Modified Electrode and Its Utilization to the Electroreduction of Aliphatic Esters  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis(ISOETC-2007)(Yokohama)  2007
  • Electrochemical Surface Modification of the Spherical Carbon Fiber with the Redox Centers  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis(ISOETC-2007)(Yokohama)  2007
  • Structural Control of the Si-Si Main Chain in the Electroreductive Polymerization of Organochlorosilanes in the Presence of Disilane and Magnesium Ion Additives  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2007) (Yokohama)  2007
  • グリーンケミストリーを指向した有機電解合成における反応性電極ならびにメディエーター固定化修飾電極の可能性  [Not invited]
    電気化学会第74回大会(野田)  2007
  • 電子移動反応を用いたジクロロシランとスチレンとの共重合反応  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • Mg電極を用いたナフタレンとケトン及びエステルとの電極還元カップリング反応  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • 反応性Mg電極を用いたアントラセンと脂肪族ケトンおよびエステルとの電極還元カップリング反応  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • 新規金属-ポルフィリン錯体固定化修飾電極の調製及びそれを利用した電極還元反応  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • 電解修飾法によるカーボンファイバー固定化酸化還元酵素の調製  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • 下部臨界共溶温度を有するポリマー水溶液中での環境調和型有機合成  [Not invited]
    日本化学会第87春季年会(吹田)  2007
  • ジシラン存在下ジクロロシランの電解還元重合におけるポリシランの構造制御  [Not invited]
    第31回有機電子移動化学討論会(エレクトロオーガニックケミストリー討論会) (鳥取)  2007
  • 金属ポルフィリン錯体固定化修飾電極の調製及び評価  [Not invited]
    第31回有機電子移動化学討論会(エレクトロオーガニックケミストリー討論会) (鳥取)  2007
  • 電解修飾法を用いたカーボンファイバーへの酸化還元酵素の固定化及び評価  [Not invited]
    第31回有機電子移動化学討論会(エレクトロオーガニックケミストリー討論会) (鳥取)  2007
  • 下部臨界共溶温度を有する高分子水溶液中での極性ビニルモノマーの重合および有機合成反応  [Not invited]
    第53回高分子研究発表会(神戸)  2007
  • Preparation of Magnesium - Porphyrin Complexes Modified Electrode and Its Utilization to the Electroreduction of Aliphatic Esters  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2007)(Yokohama)  2007
  • Electrochemical Surface Modification of the Spherical Carbon Fiber with the Redox Centers  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2007)(Yokohama)  2007
  • Structural Control of the Si-Si Main Chain in the Electroreductive Polymerization of Organochlorosilanes in the Presence of Disilane and Magnesium Ion Additives  [Not invited]
    2nd International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2007) (Yokohama)  2007
  • Fixation of Redox Centers and Polymer Reaction Field on Electrodes, and Application of the Resulting Electrodes to Electroorganic Synthesis  [Not invited]
    The 74th Annual Meeting of the Electrochemical Society of Japan (Noda)  2007
  • Copolymerization of Dichlorosilane with Styrene by Electron Transfer Reactions  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Electroreductive Coupling of Ketones or Esters with Naphthalene by Using Mg Electrodes  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Electroreductive Coupling of Ketones or Aliphatic Esters with Anthracene by Using Mg Electrodes  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Preparation of Metalloporphyrin Complexes Modified Electrode and Its Utilization of Electroreduction  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Electrochemical Preparation of the Carbon Fiber Immobilized Redox Enzyme  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Environmentally Beningn Organic Synthesis in Aqueous Solution of the Polymer Having Lower Critical Solution Temperature  [Not invited]
    The 87th Annual Meeting of the Chemical Society of Japan (Suita)  2007
  • Structure Control of Polysilanes in the Electroreductive Polymerization of Dichlorosilanes in the Presence of Disilanes  [Not invited]
    The 31st Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Tottori)  2007
  • Preparation and Characterization of Metalloporphyrin Complex Modified Electrodes  [Not invited]
    The 31st Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Tottori)  2007
  • Fixation and Evaluation of Redox Enzyme on Carbon Fiber by Using Electrochemical Modification Methods  [Not invited]
    The 31st Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Tottori)  2007
  • Polymerization of Polar Vinyl Monomers and Organic Synthesis in Aqueous Solution of the Polymer Having Lower Critical Solution Temperature  [Not invited]
    The 53rd Annual Kobe Polymer Research Symposium (Kobe)  2007
  • ジシラン存在下ポリシランの電解合成におけるケイ素主鎖の立体化学に関する検討  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • 脂肪族エステルの電極還元反応におけるマグネシウム-フタロシアニン錯体添加効果および錯体修飾電極の調製  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • 電解修飾法によるパラジウム錯体固定化カーボンファイバーの調製  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • 金属Mgからの電子移動によるシリン系ポリマーの合成  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • 電極還元法と金属Mgを用いたポリシランの合成  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • PhMeSiCl2とビニルモノマーを用いた含ケイ素ポリマーの合成  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • 反応性Mg電極を用いた芳香族化合物の還元重水素化  [Not invited]
    日本化学会第86春季年会(船橋)  2006
  • Effects of Disilane Additives and Magnesium Ion on the Electroreductive Polymerization of Organodichlorosilanes  [Not invited]
    209th Meeting of the Electrochemical Society (Denver)  2006
  • 電解修飾法をキーステップとする金属錯体固定化炭素粉末の調製  [Not invited]
    第30回有機電子移動化学討論会(エレクトロオーガニックケミストリー討論会) (横浜)  2006
  • Naイオン固定化修飾電極を用いた難還元性化合物の電解還元とMgイオン共存効果  [Not invited]
    2006年 電気化学会秋季大会(京田辺)  2006
  • Mgからの電子移動による活性種の生成  [Not invited]
    2006年 電気化学会秋季大会(京田辺)  2006
  • Study on the Stereochemistry of Si-Si Main Chain in the Electroreductive Synthesis of Polysilanes in the Presence of Disilane Additives  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Effect of Magnesium-Phthalocyanine Complexes on the Electroreduction of Aliphatic Esters and Preparation of a Magnesium-Phthalocyannine Complex Modified Electrode  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Electrochemical Preparation of the Carbon Fiber Modified with Palladium Complexes  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Synthesis of Silicone Containing Polymers by Electron Transfer from Mg Metal  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Synthesis of Polysilane by Using Electroreduction and Mg Metal Induced Reduction  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Reductive Copolymerization of PhMeSiCl2 and Vinyl Monomers  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Electroreductive Deuteration of Aromatic Compounds by Using Mg Electrodes  [Not invited]
    The 86th Annual Meeting of the Chemical Society of Japan (Funabashi)  2006
  • Effects of Disilane Additives and Magnesium Ion on the Electroreductive Polymerization of Organodichlorosilanes  [Not invited]
    209th Meeting of the Electrochemical Society (Denver)  2006
  • Preparation of Metal Complexes Fixed Carbon Powder by Using Electrochemical Modification Methods  [Not invited]
    The 30th Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Yokohama)  2006
  • Effects of Mg Ion on the Electroreduction of Hardly Reducible Compounds by Using Na Ion Fixed Electrodes  [Not invited]
    2006 Fall Meeting of the Electrochemical Society of Japan (Kyotanabe)  2006
  • Generation of Reactive Oxidative Species Using Mg Metal  [Not invited]
    2006 Fall Meeting of the Electrochemical Society of Japan (Kyotanabe)  2006
  • Electro-oxidation and -reduction Surface Modification of Carbon Fiber and Its Utilization to the Preparation of Functional Electrodes  [Not invited]
    1st International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis(ISOETC-2005)(Higashi-Osaka)  2005
  • Preparation and Utilization of the Modified Electrodes Having the Polymer Complexes of Alkali Metal Ions as Mediatory Centers  [Not invited]
    1st International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2005) (Higashi-Osaka)  2005
  • 極性溶媒中高分子反応場におけるアクリルアミド類の重合反応性  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 電気化学的表面改質法を利用した機能分子固定化炭素繊維の調製  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 水溶媒中不飽和エステルの電極還元反応における表面改質炭素繊維電極の電極効果  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 電子移動反応によるトリクロロシランとスチレンの共重合反応  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 高還元能を有するアルカリ金属イオン-ベンゾ-18-クラウン-6錯体修飾電極の調製  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • ジクロロシラン類の電解重合におけるケイ素主鎖の立体化学に関する検討  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • Mg電極を用いた芳香族化合物の電極還元  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 電極還元法および金属Mgを用いたジクロロシランとスチレンの共重合反応  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 電極還元法と金属Mgを用いたポリシランの合成  [Not invited]
    日本化学会第85春季年会(横浜)  2005
  • 高還元能を有するメディエーター固定化電極の調製  [Not invited]
    第29回エレクトロオーガニックケミストリー討論会(仙台)  2005
  • 電解表面改質法を利用した機能分子固定化炭素繊維の調製  [Not invited]
    第29回エレクトロオーガニックケミストリー討論会(仙台)  2005
  • 反応性電極ならびに高分子錯体修飾電極を用いた新規電解還元系の開発  [Not invited]
    第29回エレクトロオーガニックケミストリー討論会(仙台)  2005
  • Electro-oxidation and -reduction Surface Modification of Carbon Fiber and Its Utilization to the Preparation of Functional Electrodes  [Not invited]
    1st International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2005) (Higashi-Osaka)  2005
  • Preparation and Utilization of the Modified Electrodes Having the Polymer Complexes of Alkali Metal Ions as Mediatory Centers  [Not invited]
    1st International Sympsium on Organic Electron Transfer Chemistry Directed Toward Organic Synthesis (ISOETC-2005) (Higashi-Osaka)  2005
  • Polymerizability of Vinyl Monomers in the Reaction Field of Polymers in Polar Solvents  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Preparation of Carbon Fiber-immobilized Functional Molecules by Electrochemical Surface Modification  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Electrode Effect of Surface Modified Carbon Fiber Electrodes on the Electroreduction of Unsaturated Esters in Water  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Copolymerization of Trichlorosilane with Styrene by Electron Transfer Reaction  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Preparation of Alkali Metal Ion-Benzo-18-crown-6 Ether Complexes Modified Electrode for the Electroreduction of Hardly Electroreducible Compounds  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Study on the Stereochemistry of Si-Si Main Chain in the Electroreductive Polymerization of Dichlorosilanes  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Electroreduction of Aromatic Compounds by Using Mg Electrodes  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Copolymerization of Dichlorosilane with Styrene by Electroreduction and Reduction Using Mg Metal as Reductant  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Synthesis of Polysilane by Using Electroreduction and Mg Metal Promoted Reduction  [Not invited]
    The 85th Annual Meeting of the Chemical Society of Japan (Yokohama)  2005
  • Preparation of Modified Electrodes Having Mediatory System to Reduce Hardly Reducible Compounds  [Not invited]
    The 29th Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Sendai)  2005
  • Preparation of Functional Molecules Fixed Carbon Fiber by Using Electrochemical Surface Modification Methods  [Not invited]
    The 29th Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Sendai)  2005
  • Exploitation of Novel Electroreduction System Using Chemically Reactive Electrodes and Polymer Complexes Modified Electrodes  [Not invited]
    The 29th Symosium on Organic Electron Transfer Chemistry (Symposium of Electroorganic Chemistry) (Sendai)  2005
  • 溶存金属イオン存在下におけるオルガノクロロシラン類の電極還元カップリング反応ならびに電極還元重合  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • ジクロロシラン類の電極還元カップリング反応における置換基効果及び溶存イオン効果  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 電極還元法および金属Mg、Lewis酸系を用いたクロロシラン、クロロゲルマンとスチレンとの共重合反応  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 電極反応を利用したポリ(N-イソプロピルアクリルアミド-co-カルバゾール)グラフト炭素繊維の調製と評価  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 電気化学的手法による炭素繊維の表面改質と選択的電極反応への応用  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 電極酸化を用いた機能性炭素材料の合成  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 水溶媒中ポリアクリルアミド系高分子のつくる反応場における極性ビニルモノマーの重合反応性  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 不飽和エステルの電極還元反応における表面改質炭素繊維電極の電極効果  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 18-クラウン-6エーテル系配位子の調製およびその白金電極表面への固定化  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 側鎖に光学活性部位を有するジクロロシラン類の電解重合とその立体規則性  [Not invited]
    日本化学会第84春季年会(西宮)  2004
  • 炭素電極表面の電解改質および電解グラフト化と電極還元反応への応用  [Not invited]
    第28回エレクトロオーガニックケミストリー討論会(福岡)  2004
  • ポリシラン類の電解合成における金属イオンの添加効果  [Not invited]
    第28回エレクトロオーガニックケミストリー討論会(福岡)  2004
  • New paired electrolysis system using the platinum electrode modified with the crown ether - alkali metal ion complexes  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreduction of aromatic compounds using chemically reactive Mg electrode  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreduction of aromatic compounds using chemically reactive Mg electrode  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreductive Synthesis and Polymer Reaction of Silan-Germane Copolymers  [Not invited]
    2004 Joint International Meeting (206th Meeting of the Electrochemical Society and 2004 Fall Meeting of the Electrochemical society of Japan) (Hawaii)  2004
  • Electroreductive Coupling Reaction and Polymerization of Organochlorosilanes in the Presence of Dissolved Metal Ions  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Effect of the Neighboring Groups and the Dissolved Metal Ions in the Electroreduction of Dichlorosilanes  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Copolymerization of Chlorosilane, Chlorogermane, and Styrene by Electroreduction or Reduction Using Mg Metal and Lewis Acid  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Electrochemical Preparation and Characterization of Poly(N-isopropylacrylamide-co-carbazole) Graft Carbon Fibers  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Surface Modification of Carbon Fibers by the Electrochemical Procedures and Their Utilization for Selective Electrochemical Reactions  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Synthesis of Functional Carbon Materials Using Anodic Oxidation  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Polymerizability of Polar Vinyl Monomers in the Reaction Field of Polyacrylamides and Water  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Electrode Effect of Surface Modified Carbon Fiber Electrodes on the Electroredcution of Unsaturated Esters  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Preparation of 18-Crown-6 Type Ligand and Its Fixation on the Platinum Electrode Surface  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Preliminary Study on the Stereoselectivity in the Electroreductive Polymerization of the Dichlorosilanes Having Optically Active Substituents  [Not invited]
    The 84th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  2004
  • Electrochemical Modification, Grafting, Application of Carbon Fiber Electrodes  [Not invited]
    The 28th Symposium of Electroorganic Chemistry (Fukuoka)  2004
  • Effect of Metal Ions on the Electroreductive Synthesis of Polysilanes  [Not invited]
    The 28th Symposium of Electroorganic Chemistry (Fukuoka)  2004
  • New paired electrolysis system using the platinum electrode modified with the crown ether - alkali metal ion complexes  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreduction of aromatic compounds using chemically reactive Mg electrode  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreduction of aromatic compounds using chemically reactive Mg electrode  [Not invited]
    55th Annual Meeting of the International Society of Electrochemistry (Greece)  2004
  • Electroreductive Synthesis and Polymer Reaction of Silan-Germane Copolymers  [Not invited]
    2004 Joint International Meeting (206th Meeting of the Electrochemical Society and 2004 Fall Meeting of the Electrochemical society of Japan) (Hawaii)  2004
  • アルカリ金属イオン固定化-ジベンゾ-18-クラウン-6配位子修飾白金電極の調製およびこれを用いた難還元性化合物の電極還元反応  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • 不飽和エステルの電極還元反応系へのアルカリ金属イオンおよびランタノイド金属イオン錯体の添加効果  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • 電極酸化還元反応を連続的に利用した機能性カーボンファイバー修飾電極の調製  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • 電極酸化によるカーボンファイバー及び炭化珪素の表面酸化と電気伝導性の制御  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • 電極還元法および金属Mgを用いたジクロロシランとスチレンの共重合反応  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • 電極還元法および金属Mgを用いたトリクロロシランとスチレンとの共重合反応  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • オルガノクロロシラン類の電極還元カップリング反応ならびに電極還元重合における溶存金属イオンの効果  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • カルボニル化合物溶媒中におけるアクリルアミドと種々の極性ビニルモノマーとのラジカル共重合とその溶媒効果  [Not invited]
    日本化学会第83春季年会(東京)  2003
  • グリーンケミストリーを指向した有機電解合成における反応性電極ならびにメディエーター固定化修飾電極の可能性  [Not invited]
    電気化学会創立70周年記念大会(東京)  2003
  • 陽極酸化-陰極還元処理を連続的に用いた炭素繊維の表面改質とその機能性電極としての利用  [Not invited]
    第27回エレクトロオーガニックケミストリー討論会(札幌)  2003
  • Preparation of the Platinum Electrodes Modified with Dibenzo-18-crown-6 Ligands and Fixation of Alkali Metal Ions, and its Application for the Electroreduction of Hardly Reducible Compounds  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Additive Effect of Alkali Metal Ion Complexes and Lanthanide Ion Complexes in the Electroreduction of Unsaturated Esters  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Preparation of Functional Carbon Fiber Electrodes by Using Electro-oxidation and -reduction Sequential Procedure  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Conductivity Control of Carbon Fiber and Silicon Carbide Using Anodic Oxidation  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Copolymerization of Dichlorosilane with Styrene by Electroreduction and Reduction Using Mg Metal as a Reductant  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Copolymerization of Trichlorosilane with Styrene by Electroreduction and Reduction Using Mg Metal as a Reductant  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Effect of Dissolved Metal Ions on the Electroreductive Coupling Reaction and Polymerization of Organochlorosilanes  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Solvent Effect on the Radical Co-polymerization of Acrylamide with Various Kinds of Polar Vinyl Monomers in Carbonyl Compounds Media  [Not invited]
    The 83rd Annual Meeting of the Chemical Society of Japan (Tokyo)  2003
  • Application of Chemically Reactive Electrodes and Mediatory System Fixed Electrodes to the Electroorganic Synthesis Aimed for Green Chemistry  [Not invited]
    The 70th Annual Meeting of the Electrochemical Society of Japan (Tokyo)  2003
  • Surface Modification of Carbon Fiber by Using the Electro-oxidation and -reduction Sequential Procedure, and its Utilization as Functional Electrodes  [Not invited]
    The 27th Symposium of Electroorganic Chemistry (Sapporo)  2003
  • 反応性Mg電極を用いた芳香族化合物の電極還元  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • アルカリ金属イオン固定化電極を利用した難還元性化合物の電極還元反応  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • 電解酸化ならびに還元反応を利用したカーボンファイバーの表面改質  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • 電極酸化によるカーボンファイバーの表面酸化と電気伝導性の制御  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • オルガノジクロロシランの電解重合におけるジシラン類の添加効果  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • 反応性電極と金属Mgを用いたポリシランの新規合成法の開拓  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • 長鎖アルキル基を有するシラン-ゲルマン共重合体の電解合成とその構造制御  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • クラウンエーテル系配位子の調製およびその白金電極表面への固定化  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • サマリウムイオンをメディエーターに用いたケトンおよび活性オレフィンの電極還元反応  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • アクリルアミドと種々の極性ビニルモノマーとのラジカル共重合における溶媒効果  [Not invited]
    日本化学会第81春季年会(東京)  2002
  • 高分子配位子修飾電極への金属イオンの固定化とその電極還元反応への利用  [Not invited]
    第26回エレクトロオーガニックケミストリー討論会(岡山)  2002
  • メディエーター機能を固定化した修飾電極の調製とこれを用いた脂肪族エステルの電極還元反応  [Not invited]
    2002年 電気化学会秋季大会(厚木)  2002
  • Electroreductive Formation of Silyl Anion and Its Reactions  [Not invited]
    53rd Annual Meeting of the International Society of Electrochemistry (Germany)  2002
  • Paired Electrolysis System Using the Crown Ether - Alkali Metal Ion Complexes  [Not invited]
    53rd Annual Meeting of the International Society of Electrochemistry (Germany)  2002
  • Electroreduction of Aromatic Compounds by Using Mg Electrodes  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Electroreduction of Hardly Electroreducible Compounds by Using the Alkali Metal Ion Fixed Electrodes  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Surface Modification of Carbon Fiber by Using Electro-oxidation and -reduction Sequence  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Conductivity Control of Carbon Fiber Using Anodic Oxidation  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Effect of Disilane Additives on the Electroreductive Polymerization of Organodichlorosilane  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • New Synthesis of Polysilanes Using Mg  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Electroreductive Synthesis and Structure Control of Silane-Germane Copolymers Bearing Long Chain Alkyl Groups  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Preparation of a Crown Ether Type Ligand and its Fixation on the Platinum Electrode Surface  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Electroreduction of Activated Olefins by Using Samarium Ions as Mediators  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Solvent Effect on the Radical Co-polymerization of Acrylamide with Various Kinds of Polar Vinyl Monomers  [Not invited]
    The 81st Annual Meeting of the Chemical Society of Japan (Tokyo)  2002
  • Fixation of Metal Ions on the Electrodes Modified with the Polymer Ligands, and its Application to the Electroreduction  [Not invited]
    The 26th Symposium of Electroorganic Chemistry (Okayama)  2002
  • Preparation of the Modified Electrode Having Mediatory Functionalized Centers and its Utilization for the Electroreduction of Aliphatic Esters  [Not invited]
    2002 Fall Meeting of the Electrochemical Society of Japan (Atsugi)  2002
  • Electroreductive Formation of Silyl Anion and its Reactions  [Not invited]
    53rd Annual Meeting of the International Society of Electrochemistry (Duesseldorf, Germany)  2002
  • Paired Electrolysis System Using the Crown Ether - Alkali Metal Ion Complexes  [Not invited]
    53rd Annual Meeting of the International Society of Electrochemistry (Duesseldorf, Germany)  2002
  • 架橋反応を用いた高分子量ポリシランの合成  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 側鎖に光学活性部位を有するオリゴシランおよびポリシランの電解合成  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 電極還元法を用いた光学活性ポリシランの合成  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 自動合成を志向した脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • LCSTを有する鋳型ポリマー存在下におけるアクリルアミドの重合反応性  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 種々のカルボニル化合物存在下における極性ビニルモノマーの重合反応(カルボニル化合物の構造と重合性との相関)  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 電極還元法によるシラン-ゲルマン共重合体の合成および元素組成制御  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • 脂肪族エステルの電極還元反応におけるアルカリ金属イオン-アザクラウンエーテル錯体の添加効果  [Not invited]
    日本化学会第79春季年会(神戸)  2001
  • Electroreductive Synthesis of Polysilanes and Related Polymers by Using Magnesium Electrodes  [Not invited]
    22nd Sandbjerg Meeting on Organic Electrochemistry (Sandbjerg)  2001
  • Synthesis of High Molecular Weight Polysilanes Using Polymer Reaction  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Electroreductive Synthesis of Oligosilanes and Polysilanes Having Oprically Active Substituents on their Side Chain  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Electroreductive Synthesis of Optically Active Polysilane  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Electroreduction of Aliphatic Esters Aimed for Automated Synthesis  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Polymerizability of Acrylamide in the Presence of the Template Polymer Having LCST  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Study on Polymerization of Vinyl Monomers in the Presence of Carbonyl Compounds(Relation between the Structure of Carbonyl Compounds and Polymerizability)  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Electroreductive Synthesis and Unit Control of Silane-Germane Copolymers  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Effects of Alkali Metal Ions-Azacrown Ether Complexes in the Electroreduction of Aliphatic Esters  [Not invited]
    The 79th Annual Meeting of the Chemical Society of Japan (Kobe)  2001
  • Electroreductive Synthesis of Polysilanes and Related Polymers by Using Magnesium Electrodes  [Not invited]
    22nd Sandbjerg Meeting on Organic Electrochemistry (Sandbjerg)  2001
  • アミド-アミド基間相互作用に基づくアクリルアミドの鋳型重合  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • カルボニル-アミド基間相互作用により誘発されるアクリルアミドの鋳型重合  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • いくつかの電極還元反応における表面酸化および表面修飾カーボンファイバー電極の電極効果  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • 電解酸化によるカーボンファイバーの表面酸化と電気伝導性の制御  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • ポリシラン・ポリカルボシラン類の電解合成とそのユニット配列制御  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • 電極還元によるサマリウム錯体の活性化とその還元能  [Not invited]
    電極還元によるサマリウム錯体の活性化とその還元能  2000
  • アルカリ金属-クラウンエーテル高分子錯体を用いた脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • 電極還元法を用いた光学活性ポリシランの合成  [Not invited]
    日本化学会第78春季年会(船橋)  2000
  • アルカリおよびアルカリ土類金属イオン固定化電極を用いた難還元性化合物の電極還元反応  [Not invited]
    第24回エレクトロオーガニックケミストリー討論会(埼玉)  2000
  • シラン-ゲルマン共重合体の電解合成とその高分子反応  [Not invited]
    第24回エレクトロオーガニックケミストリー討論会(埼玉)  2000
  • Indirect Anodic Oxdation of Carbon Fiber Using NO3 Radical  [Not invited]
    51st Annual ISE Meeting (Warsaw)  2000
  • Electroreductive Synthesis of Silicon and/or Germanium Containing Polymers  [Not invited]
    51st Annual ISE Meeting (Warsaw)  2000
  • Electrochemical Preparation of 1,2-Diketones for Automated Synthesis  [Not invited]
    2000 International Chemical Congeress of Pacific Basin Societies (Hawaii)  2000
  • Electroreduction of Aliphatic Esters for Automated Synthesis  [Not invited]
    2000 International Chemical Congeress of Pacific Basin Societies (Hawaii)  2000
  • Template Polymerization of Acrylamides Induced by the Amide-Amide Groups Interaction  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Polymerization of Acrylamide Induced by the Carbonyl-Amide Groups Interaction  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electrode Effects of the Surface Oxidized and Modified Carbon Fiber Electrodes in Some Electroreductive Reactions  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Control of Electric Conductivity of the Anodically Oxidized Carbon Fiber  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electroreductive Synthesis and Sequence Control of Polysilanes and Polycarbosilanes  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electroreductive Activation of Samarium Complexes and their Reducing Ability  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electroreduction of Aliphatic Esters by Using Alkali Metal-Crownether Polymer Complexes  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electroreductive Synthesis of Optically Active Polysilanes  [Not invited]
    The 78th Annual Meeting of the Chemical Society of Japan (Funabashi)  2000
  • Electroreduction of Hardly Reducible Compounds by Using the Alkali and Alkaline-earth Metals Fixed Electrodes  [Not invited]
    The 24th Symposium of Electroorganic Chemistry (Saitama)  2000
  • Electroreductive Synthesis and Polymer Reaction of Silane-Germane Copolymers  [Not invited]
    The 24th Symposium of Electroorganic Chemistry (Saitama)  2000
  • Indirect Anodic Oxidation of Carbon Fiber Using NO3 Radical  [Not invited]
    51st Annual ISE Meeting(Warsaw)  2000
  • Electroreductive Synthesis of Silicon and/or Germanium containing Polymers  [Not invited]
    51st Annual ISE Meeting (Warsaw)  2000
  • Electrochemical Preparation of 1, 2-Diketones for Automated Synthesis  [Not invited]
    2000 International Chemical Congeress of Pacific Basin Societies (Hawaii)  2000
  • Electroreduction of Aliphatic Esters Aimed for Automated Synthesis  [Not invited]
    2000 International Chemical Congeress of Pacific Basin Societies (Hawaii)  2000
  • 電解発生硝酸ラジカルによるカーボンファイバーの表面酸化における導入官能基の評価とその修飾電極への応用  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • 電極酸化によるカーボンファイバーの表面酸化と電気伝導性の制御  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • シラン-ゲルマン共重合体の電解合成における構造制御  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • 電極還元におけるポリシランの構造制御  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • アルカリ金属イオン-クラウンエーテル錯体修飾電極を用いた脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • 立体規則性ポリメタクリル酸メチル存在下におけるアクリルアミドの鋳型重合  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • カルボニル-アミド基間相互作用により誘発されるアクリルアミドの重合とその重合機構  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • ランタノイド金属-シクロペンタジエニル錯体の電気化学的活性化  [Not invited]
    日本化学会第76春季年会(横浜)  1999
  • 電極反応によって生成した硝酸ラジカルによる炭素繊維表面の電極酸化  [Not invited]
    第23回エレクトロオーガニックケミストリー討論会(長岡)  1999
  • 構造規制シラン-ゲルマン共重合体の電解合成とその電極還元条件下における挙動  [Not invited]
    第23回エレクトロオーガニックケミストリー討論会(長岡)  1999
  • 電極反応によって生成した硝酸ラジカルによる炭素繊維表面の電極酸化  [Not invited]
    日本化学会第77秋季年会(札幌)  1999
  • 高分子電解塩基を利用した有機合成  [Not invited]
    日本化学会第77秋季年会(札幌)  1999
  • アルカリ金属イオン-クラウンエーテル錯体修飾電極を用いた難還元性化合物の電極還元反応  [Not invited]
    日本化学会第77秋季年会(札幌)  1999
  • 電解発生硝酸ラジカルによるカーボンファイバーの表面酸化と修飾電極への利用  [Not invited]
    日本化学会第77秋季年会(札幌)  1999
  • Indirect Anodic Oxdation of Carbon Fiber Using NO3 Radical  [Not invited]
    The 1999 Joint International Meeting (196th Meeting of the Electrochemical Society and 1999 Fall Meeting of the Electrochemical society of Japan) (Hawaii)  1999
  • Electroreductive Synthesis and Polymer Reaction of Silan-Germane Copolymers  [Not invited]
    The 1999 Joint International Meeting (196th Meeting of the Electrochemical Society and 1999 Fall Meeting of the Electrochemical society of Japan) (Hawaii)  1999
  • Estimation of Functional Groups on Carbon Fiber Oxidized by the Electrogenerated NO3 Radical and Application of the Oxidized Carbon Fiber on the Modified Electrode  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Conductivity Control of Carbon Fiber Using Anodic Oxidation  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Sequence Control in the Electroreductive Synthesis of Silane-Germane Copolymers  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Control of Polysilane Structure by the Electroreduction  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Alkali Electroreduction of Aliphatic Esters Using Alkali Metal Ion-Crown Ether Complexes Modified Electrodes  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Template Plymerization of Acrylamide in the Presence of the Stereoregular Poly(methyl methacrylate)s  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Mechanistic Study of Polymerization of Acrylamide Induced by the Interaction between the Carbonyl and Amide Groups  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Electrochemical Activation of the Lanthanide Metal-Cyclopentadienyl Complexes  [Not invited]
    The 76th Annual Meeting of the Chemical Society of Japan (Yokohama)  1999
  • Oxidation of Carbon Fiber by the Electrogenerated No3 Radical  [Not invited]
    The 23rd Symposium of Electroorganic Chemistry (Nagaoka)  1999
  • Electroreductive Synthesis of Structure Controlled Silane-Germane Copolymers and their Behaviour under the Electroreduction Conditions  [Not invited]
    The 23rd Symposium of Electroorganic Chemistry (Nagaoka)  1999
  • Anodic Oxidation of Carbon Fiber Surface Using the Electrochemically Generated No3 Radical  [Not invited]
    The 77th Annual Meeting of the Chemical Society of Japan (Sapporo)  1999
  • Organic Synthesis by Using the Electrogenerated Polymeric Bases  [Not invited]
    The 77th Annual Meeting of the Chemical Society of Japan (Sapporo)  1999
  • Electroreduction of Hardly Reducible Compounds Using Alkali Metal Ion-Crown Ether Complexes Modified Electrodes  [Not invited]
    The 77th Annual Meeting of the Chemical Society of Japan (Sapporo)  1999
  • Surface Oxidation of Carbon Fiber by the Electrogenerated NO3 Radical and its Application to Modified Electrodes  [Not invited]
    The 77th Annual Meeting of the Chemical Society of Japan (Sapporo)  1999
  • Indirect Anodic Oxidation of Carbon Fiber Using NO3 Radical  [Not invited]
    The 1999 Joint International Meeting (196th Meeting of the Electrochemical Society and 1999 Fall Meeting of the Electrochemical Society of Japan) (Hawaii)  1999
  • Electroreductive Synthesis and Polymer Reaction of Silane-Germane Copolymers  [Not invited]
    The 1999 Joint International Meeting (196th Meeting of the Electrochemical Society and 1999 Fall Meeting of the Electrochemical Society of Japan) (Hawaii)  1999
  • クラウンエーテル部位を有する高分子配位子を用いたアルカリ金属イオンメディエーター電極還元反応およびその修飾電極への利用  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • ランタノイド金属錯体存在下におけるアクリル酸エステルの電解重合  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • ポリシランの電極還元による活性種の生成とその有機合成への応用  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • ポリシランの高分子反応を用いた構造制御  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • ハイドロオリゴシランの電解合成とこれを鍵化合物とした構造制御ポリシランおよびポリカルボシランの合成  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • 電解発生硝酸ラジカルによるカーボンファイバーの表面酸化とピログルタミン酸誘導体による化学修飾  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • 電極反応により生成する硝酸ラジカルを用いた異方性カーボンファイバーの表面酸化  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • ケトン類存在下におけるアクリルアミドの重合とその重合機構  [Not invited]
    日本化学会第74春季年会(京都)  1998
  • 自動合成を指向した新しい電極反応の開拓  [Not invited]
    電気化学会第65回大会(東京)  1998
  • 高分子配位子を用いたアルカリ金属イオン還元メディエーター系の電極上への固定化  [Not invited]
    電気化学会第65回大会(東京)  1998
  • 電解発生硝酸ラジカルによるカーボンファイバーの表面酸化とその化学修飾  [Not invited]
    第22回エレクトロオーガニックケミストリー討論会(大阪)  1998
  • Indirect Anodic Oxidation of Carbon Fiber Using NO3・ Radical  [Not invited]
    1998 International Symposium on Organic Reactions Hsinchu (Taiwan)  1998
  • Electroreductive Synthesis and Polymer Reaction of Polysilanes  [Not invited]
    1998 International Symposium on Organic Reactions Hsinchu (Taiwan)  1998
  • Alkali Matal Mediatory Electroreduction System by Using of Polymer Ligands Bearing Crown Ether Pendants, and their Utilization for the Modified Electrodes  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Electroreductive Polymerization of Acrylic Esters in the Presence of Lanthanide Metal  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Formation of Active Species by the Electroreduction of Polysilane and its Application to Organic Synthesis  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Control of Polysilane Structure Using Polymer Reaction  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Synthesis of Structure Controlled Polysilanes and Polycarbosilanes by Using the Electrochemically Prepared Hydrooligosilanes as Key Compounds  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Surface Oxidation of Carbon Fiber by Using the Electrogenerated NO3 Radical, and its Chemical Modification with Pyroglutamic Acid Derivatives  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Surface Oxidation of High Performance Carbon Fiber Using the Electrochemically Generated NO3 Radical  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • Mechanistic Study of Polymerization of Acrylamides in the Presence of Ketones  [Not invited]
    The 74th Annual Meeting of the Chemical Society of Japan (Tokyo)  1998
  • New Electroorganic Reaction for Automated Synthesis  [Not invited]
    The 65th Annual Meeting of the Electrochemical Society of Japan (Tokyo)  1998
  • Fixation of the Alkali Ion Mediatory System on the Electrode Using the Polymer Ligands  [Not invited]
    The 65th Annual Meeting of the Electrochemical Society of Japan (Tokyo)  1998
  • Surface Oxidation of Carbon Fiber by Anodically Generated NO3 Radical, and its Chemical Modification  [Not invited]
    The 22nd Symposium of Electroorganic Chemistry (Osaka)  1998
  • Indirect Anodic Oxidation of Carbon Fiber Using NO3 Radical  [Not invited]
    1998 International Symposium on Organic Reactions Hsinchu(Taiwan)  1998
  • Electroreductive Synthesis and Polymer Reaction of Polysilanes  [Not invited]
    1998 International Symposium on Organic Reactions Hsinchu(Taiwan)  1998
  • ポリビニルイミダゾール存在下におけるメタクリル酸ヒドロキシエチルの重合反応性  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • マグネシウムイオン担持電極を用いた脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • 電極反応によって生成した硝酸ラジカルによるカーボンファイバーの表面酸化  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • 電極反応を用いて合成したカーボンファイバーの特性  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • ポリシランの高分子反応を用いた構造制御  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • マグネシウム電極を用いたハイドロオリゴシラン類の電解合成とその反応  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • マグネシウム電極を用いたジクロロオリゴシラン類の電解重合  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • ポリ(N-イソプロピルアクリルアミド)の電極還元により生成する電解塩基を用いたカルボニル化合物のトリフルオロメチル化反応  [Not invited]
    日本化学会第72春季年会(東京)  1997
  • 電極反応によって生成した硝酸ラジカルによるカーボンファイバーの表面酸化  [Not invited]
    第21回エレクトロオーガニックケミストリー討論会(長崎)  1997
  • ポリアクリルアミド類の電極還元により生成する活性アニオン種の電解塩基としての利用  [Not invited]
    第21回エレクトロオーガニックケミストリー討論会(長崎)  1997
  • Trihalomethylation of Carbonyl Compounds by Using the Polymer-Supported Electrogenerated Base  [Not invited]
    The 1997 Joint International Meeting (192nd Meeting of the Electrochemical Society and 48th Annual Meeting of the International Society of Electrochemistry (Paris)  1997
  • Electrochemical Synthesis of Polysilanes  [Not invited]
    The 1997 Joint International Meeting (192nd Meeting of the Electrochemical Society and 48th Annual Meeting of the International Society of Electrochemistry (Paris)  1997
  • ジクロロオリゴシランの電極還元反応を利用したポリシランの構造規制  [Not invited]
    1997年電気化学秋季大会(東京)  1997
  • Electroreductive Synthesis of Sequence-Ordered Polysilanes Using Mg Electrodes  [Not invited]
    第3回有機電解合成国際会議(倉敷)  1997
  • Polymerizability of Hydroxyethyl Methacrylate in the Presence of Polyvinylimidazole  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Electroreduction of Aliphatic Esters by Using Magnesium Ion Supported Electrodes  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Oxidation of Carbon Fiber Using Radical NO3・Generated by Anodic Oxidation  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Characteristics of Carbon Fiber Using Elecrode Reaction  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Control of Polysilane Structure Using Polymer Reaction  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Electroreductive Synthesis and Reactions of Hydrooligosilanes Using Magnesium Electrodes  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Electroreductive Polymerization of Dichlorooligosilanes Using Magnesium Electrodes  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Trifluoromethylation of Carbonyl Compounds Using the Electrogenerated Base Prepared by the Cathodic Reduction of Poly(N-isopropylacrylamide)Derivatives  [Not invited]
    The 72nd Annual Meeting of the Chemical Society of Japan (Tokyo)  1997
  • Oxidation of Carbon Fiber Surface by Electrochemically Generated NO3 Radical  [Not invited]
    The 21st Symposium of Electroorganic Chemistry (Nagasaki)  1997
  • Synthetic Application of the Anionic Species Generated by the Electroreduction of Polyacrylamides as Electrogenerated Bases  [Not invited]
    The 21st Symposium of Electroorganic Chemistry (Nagasaki)  1997
  • Trihalomethylation of Carbonyl Compounds Using the Polymer-Supported Electrogenerated Base  [Not invited]
    The 1997 Joint International Meeting(192nd Meeting of the Electrochemical Society)and 48th Annual Meeting of the Internationl Society of Electrochemistry (Paris)  1997
  • Electrochemical Synthesis of Polysilanes  [Not invited]
    The 1997 Joint Internationl Meeting(192nd Meeting of the Electrochemical Society and 48th Annual Meeting of the International Society of Electrochemistry (Paris)  1997
  • Synthesis of Structure-Ordered Polysilanes by the Electroreduction of Dichlorooligosilanes  [Not invited]
    1997 Fall Meeting of the Electrochemical Society of Japan (Tokyo)  1997
  • Electroreductive Synthesis of Sequence-Ordered Polysilanes Using Mg Electrodes  [Not invited]
    The 3rd International Symposium on Electroorganic Synthesis (Kurashiki)  1997
  • アクリルアミド類の重合反応におけるケトンの添加効果  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • イミダゾール存在下におけるアクリル酸ヒドロキシエチル類の重合性  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • Mgを反応性電極に用いた非対称1,2-ジケトンの合成  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • 反応性電極を用いた電極還元反応による脂肪族エステルとオレフィンとの分子内環化  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • Mgメディエーターを用いる電極還元系における配位子効果  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • ジクロロオリゴシランの電極還元反応  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • Mg電極を用いた電解重合法による水溶性ポリシランの合成  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • 2-ピロリドンアニオン(EGB)の新規合成法の開拓とその反応  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • ポリ(N-イソプロピルアクリルアミド)誘導体の電極還元による電解塩基の生成とその有機合成への応用  [Not invited]
    日本化学会第70春季年会(東京)  1996
  • ランタノイドイオンをメディエーターに用いた脂肪族エステルの電極還元反応  [Not invited]
    日本希土類学会第13回希土類討論会(京都)  1996
  • Electroreduction of Aliphatic Ester and Amide with Chemically Reactive Mg Electrode  [Not invited]
    189th Society Meeting of the Electrochemical Society (Los Angeles)  1996
  • 電極反応による新規オリゴシランおよびポリシラン類の合成  [Not invited]
    第20回エレクトロオーガニックケミストリー討論会(徳島)  1996
  • Electroreduction of Aliphatic Esters and Amides Using Metal Ions as Mediators  [Not invited]
    47th Annual Meeting of the International Society of Electrochemistry (Hungary)  1996
  • Electroreductive Synthesis of Oligo- and Poly-Silanes Using Magnesium Electrodes  [Not invited]
    47th Annual Meeting of the International Society of Electrochemistry (Hungary)  1996
  • ジクロロシラン類の電極還元反応によるポリシラン類の合成  [Not invited]
    第5回ポリマー材料フォーラム(大阪)  1996
  • Addition Effect of Ketone in the Polymerization of Acrylamides  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Polymerizability of Hydroxyethyl Acrylates in Presence of Imidazole  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Synthesis of Unsymmetrical 1,2-Diketone Utilizing Chemically Mg Electrode  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Intramolecular Cyclization of Aliphatic Ester and Olefin Using Chemically Reactive Electrode  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Ligand Effects of the Electroreduction System Using Mg Ion as a Mediator  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Electroreduction of Dichlorooligosilanes  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Electroreductive Synthesis of Water-Soluble Polysilanes Using Mg Electrodes  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • New Method for the Preparation of 2-Pyrrolidone Anion (EGB) and its Reaction  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Synthetic Unilization of Electrogenerated Base Prepared by the Cathodic Reduction of Poly(N-isopropylacrylamide)Derivatives  [Not invited]
    The 70th Annual Meeting of the Chemical Society of Japan (Tokyo)  1996
  • Electroreduction of Aliphatic Esters by Using Lanthanide Ions as Mediators  [Not invited]
    The 13rd Symposium of Rare Earth (Kyoto)  1996
  • Electroreduction of Aliphatic Ester and Amide with Chemically Reactive Mg Electrode  [Not invited]
    189th Society Meeting of the Electrochemical Society (Los Angeles)  1996
  • Electroreductive Synthesis of New Oligosilanes and Polysilanes  [Not invited]
    The 20th Symposium of Electroorganic Chemistry (Tokushima)  1996
  • Electroreduction of Aliphatic Esters and Amides Using Metal Ions as Mediators  [Not invited]
    47th Annual Meeting of the International Society of Electrochemistry (Hungary)  1996
  • Electroreductive Synthesis of Oligo- and Poly-Silanes Using Magnesium Electrodes  [Not invited]
    47th Annual Meeting of the International Society of Electrochemistry (Hungary)  1996
  • Synthesis of Polysilanes by the Cathodic Reduction of Dechlorosilanes  [Not invited]
    The 5th Forum of Polymeric Materials (Osaka)  1996
  • カルボニル-アミド基間相互作用を用いたアクリルアミド類のマトリックス重合  [Not invited]
    日本化学会第69春季年会(京都)  1995
  • 反応性電極を用いた二官能性ポリシラン類の合成  [Not invited]
    日本化学会第69春季年会(京都)  1995
  • ランタノイド金属をメディエーターに用いた脂肪族エステル類の電極還元反応  [Not invited]
    日本化学会第69春季年会(京都)  1995
  • ポリアクリルアミド誘導体の電極還元によるEGBの生成とその反応  [Not invited]
    日本化学会第69春季年会(京都)  1995
  • 反応性電極を用いた電極還元法による新規ポリシランおよびポリゲルマンの実用的合成法の開拓  [Not invited]
    第18回エレクトロオーガニックケミストリー討論会(名古屋)  1995
  • Synthetic Utilizations of the Electrochemically Activated Polyacrylamide Derivatives  [Not invited]
    4th Pacific Polymer Conference (Kauai, Hawaii)  1995
  • Matrix Polymerization of Acrylamide Using Stereoregular Poly(methyl methacrylate) as a Template  [Not invited]
    4th Pacific Polymer Conference (Kauai, Hawaii)  1995
  • Electroreduction of Aliphatic Esters Using Magnesium and Lanthanide Metal Ions as Mediators  [Not invited]
    1995 International Chemical Congress of Pacific Basin Societies (Honolulu, Hawaii)  1995
  • Electroreductive Synthesis of Silicon Containing Polymers Using Magnesium Electrodes  [Not invited]
    1995 International Chemical Congress of Pacific Basin Societies (Honolulu, Hawaii)  1995
  • Synthetic Utilization of Electrogenerated Base Prepared by the Cathodic Reaction of Polyacrylamide Derivatives  [Not invited]
    1995 International Chemical Congress of Pacific Basin Societies (Honolulu, Hawaii)  1995
  • Matrix Polymerization of Acrylamides Induced by the Interaction between Carbonyl-Amide Groups  [Not invited]
    The 69th Annual Meeting of the Chemical Society of Japan (Kyoto)  1995
  • Electroreductive Synthesis of Polysilanes Bearing Two Functional Groups by Using Reactive Electrodes  [Not invited]
    The 69th Annual Meeting of the Chemical Society of Japan (Kyoto)  1995
  • Electroreduction of Aliphatic Esters by Using Lanthanide Metal Ion as a Mediator  [Not invited]
    The 69th Annual Meeting of the Chemical Society of Japan (Kyoto)  1995
  • Generation and Synthetic Utilization of EGB Prepared by the Electroreduction of Polyacrylamide Derivatives  [Not invited]
    The 69th Annual Meeting of the Chemical Society of Japan (Kyoto)  1995
  • Practive Electrochemical Method for Synthesizing New Polysilanes and Polygermanes  [Not invited]
    The 18th Symposium of Electroorganic Chemistry (Nagoya)  1995
  • Synthetic Utilizations of the Electrochemically Activated Polyacrylamide Derivatives  [Not invited]
    4th Pacific Polymer Conference (Kauai,Hawaii)  1995
  • Matrix Polymerization of Acrylamide Using Stereoregular Poly(methyl methacrylate) as a Template  [Not invited]
    4th Pacific Polymer Conference (Kauai,Hawaii)  1995
  • Electroreduction of Aliphatic Esters Using Magnesium and Metal Ions as Mediators  [Not invited]
    1995International Chemical Congress of Pacific Basin Societies (Honolulu,Hawaii)  1995
  • Electroreductive Synthesis of Silicon Containing Polymers Using Magnesium Electrodes  [Not invited]
    1995International Chemical Congress of Pacific Basin Societies (Honolulu,Hawaii)  1995
  • Synthetic Utilization of Electrogenerated Base Prepared by the Cathodic Reaction of Polyacrylamide Derivatives  [Not invited]
    1995International Chemical Congress of Pacific Basin Societies (Honolulu,Hawaii)  1995
  • 電極還元反応を用いた二官能性ポリシラン類の合成  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • マグネシウム電極を用いたアズレンの電極還元反応  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • Mgをメディエーターに用いた脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • マグネシウム電極を用いた脂肪族アミドの電極還元二量化によるα-アミノケトンの合成  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • トリエノールエステルの電極酸化反応  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • 電解塩基を開始剤に用いたビニル重合  [Not invited]
    日本化学会第67春季年会(東京)  1994
  • Cathodic Coupling of Ketone with Trimethyl Substituted Olefins  [Not invited]
    185th Society Meeting of the Electrochemical Society (San Fransisco)  1994
  • Electrosynthesis of Polysilane  [Not invited]
    185th Society Meeting of the Electrochemical Society (San Fransisco)  1994
  • Electroreduction of Organic Compounds Using Chemically Reactive Mg Electrode  [Not invited]
    Symposium on Novel Aspects of Electrogenerated Active Species and Their Reactions (Okayama)  1994
  • Electroreduction of Aliphatic Esters Using Mg and Sm as Mediators  [Not invited]
    第2回有機電解合成国際会議(倉敷)  1994
  • Electroreduction of Organic Comounds Using Chemically Reactive Mg Electrode  [Not invited]
    第2回有機電解合成国際会議(倉敷)  1994
  • 反応性電極を用いた脂肪族アミドとオレフィンとの分子内環化反応  [Not invited]
    第16回エレクトロオーガニックケミストリー討論会(東京)  1994
  • Smをメディエーターに用いた脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第68秋季年会(名古屋)  1994
  • Electroreductive Synthesis of Polysilanes Bearing Two Functional Groups  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Electroreduction of Azulenes Using Magnesium Electrodes  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Electroreduction of Aliphatic Esters with Using Mg as a Mediator  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Electroreductive Acyloin Type Condensation of Aliphatic Amides Using Mg Electrodes. Synthesis of α-Aminoketones  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Anodic Oxidation of Trienolesters  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Polymerization of Vinyl Monomers Induced by the Electrogenerated Base  [Not invited]
    The 67th Annual Meeting of the Chemical Society of Japan (Tokyo)  1994
  • Cathodic Coupling of Ketone with Trimethyl Substituted Olefins  [Not invited]
    185th Society Meeting of the Electrochemical Society (San Fransisco)  1994
  • Electrosynthesis of Polysilane  [Not invited]
    185th Society Meeting of the Electrochemical Society (San Fransisco)  1994
  • Electroreduction of Organic Compounds Using Chemically Reactive Mg Electrode  [Not invited]
    Symposium on Novel Aspects of Electrogenerated Active Species and Their Reactions (Okayama)  1994
  • Electroreduction of Aliphatic Esters by Using Mg and Sm as Mediators  [Not invited]
    The 2nd International Symposium on Electroorganic Synthesis (Kurashiki)  1994
  • Electroreduction of Organic Compunds Using Chemically Reactive Mg Electrode  [Not invited]
    The 2nd International Symposium on Electoorganic Synthesis (Kurashiki)  1994
  • Intramolecular Coupling of Aliphatic Esters with Olefins Using Chemically Reactive Electrodes  [Not invited]
    The 16th Symposium of Electroorganic Chemistry (Tokyo)  1994
  • Electroreduction of Aliphatic Esters by Using Sm as a Mediator  [Not invited]
    The 68th Annual Meeting of the Chemical Society of Japan (Nagoya)  1994
  • 電極反応を主反応に用いた官能基を有するトリシラン・テトラシラン類の合成  [Not invited]
    日本化学会第65春季年会(東京)  1993
  • 電極還元反応を用いた官能基を有するポリシラン類の合成  [Not invited]
    日本化学会第65春季年会(東京)  1993
  • シリル基を有するアリルアルコール類とケトンの立体選択的電極還元カップリング反応  [Not invited]
    日本化学会第65春季年会(東京)  1993
  • ベンジル基を有するアリルアルコール類とケトンとの電極還元カップリング反応  [Not invited]
    日本化学会第65春季年会(東京)  1993
  • ケイ素官能基及び水酸基を有するオレフィン類とケトンとの電極還元カップリング反応  [Not invited]
    電気化学協会第60回大会(東京)  1993
  • 反応性電極を用いる芳香族化合物の電極還元  [Not invited]
    第15回エレクトロオーガニックケミストリー討論会(熊本)  1993
  • マグネシウムをメディエーターに用いる脂肪族エステルの電極還元反応  [Not invited]
    日本化学会第66秋季年会(西宮)  1993
  • Electroreduction of Non-benzenoid Aromatic Compounds with Mg Electrode  [Not invited]
    1993 International Symposium on Organic Reactions Tainan (Tainan)  1993
  • Electroreductive Synthesis of Trisilanes and Tetrasilanes Bearing Functional Groups  [Not invited]
    The 65th Annual Meeting of the Chemical Society of Japan (Tokyo)  1993
  • Electroreductive Synthesis of Polysilanes Bearing Functional Groups  [Not invited]
    The 65th Annual Meeting of the Chemical Society of Japan (Tokyo)  1993
  • Stereoselective Cathodic Coupling of Ketones with Allylic Alcohols Having Silyl Group  [Not invited]
    The 65th Annual Meeting of the Chemical Society of Japan (Tokyo)  1993
  • Cathodic Coupling of Ketones with Allylic Having Benzyl Group  [Not invited]
    The 65th Annual Meeting of the Chemical Society of Japan (Tokyo)  1993
  • Cathodic Coupling of Ketnes with Olefinic Systems Having Trimethylsilyl and Hydroxy Groups  [Not invited]
    The 60th Annual Meeting of the Electrochemical Society of Japan (Tokyo)  1993
  • Electroreducation of Aromatic Compounds Using Chemically Reactive Electrodes  [Not invited]
    The 15th Symposium of Electroorganic Chemistry (Kumamoto)  1993
  • Electroreducation of Aliahatic Estes Using Magnesium as a Mediator  [Not invited]
    The 66th Annual Meeting of the Chemical Society of Japan (Nishinomiya)  1993
  • Electroreducation of Non-benzenoid Aromatic Compounds with Mg Erectrode  [Not invited]
    1993 International Symposium on Organic Reactions Tainan (Tainan)  1993
  • ケトンとアリルアルコール類の不斉電極還元カップリング反応  [Not invited]
    日本化学会第63春季年会(東大阪)  1992
  • ケトンとb-トリメチルシリルアリルアルコール類との電極還元カップリング反応によるホモアリルアルコールの合成  [Not invited]
    日本化学会第63春季年会(東大阪)  1992
  • マグネシウム反応性電極を用いたスチレンとエステルの電極還元カップリング反応  [Not invited]
    日本化学会第63春季年会(東大阪)  1992
  • ケトンとオレフィンとの電極還元不斉カップリング反応  [Not invited]
    第14回エレクトロオーガニックケミストリー討論会(北海道)  1992
  • ケイ素官能基を有するオレフィン系とケトンとの電極還元カップリング反応  [Not invited]
    日本化学会第64秋季年会(新潟)  1992
  • マグネシウム反応性電極を用いた1,3-ジエンとエステルとの電極還元カップリング反応  [Not invited]
    特別研究員フォーラム-機能の創出を目指して(大阪)  1992
  • Asymmetric Cathodic Coupling of Ketones with Allylic Alcohols  [Not invited]
    The 63rd Annual Meeting of the Chemical Society of Japan (Higasi-Osaka)  1992
  • Synthesis of Homoallylic Aicohols by the Cathodic Coupling of Ketones with β-Trimethylsilylallyl Alcohols  [Not invited]
    The 63rd Annual Meeting of the Chemical Society of Japan (Higasi-Osaka)  1992
  • Cathodic Coupling of Styrenes with Esters Using Chemically Reactive Magnesium Electrode  [Not invited]
    The 63rd Annual Meeting of the Chemical Society of Japan (Higasi-Osaka)  1992
  • Asymmetric Cathodic Coupling Reaction of Ketones with Olefins  [Not invited]
    The 14th Symposium of Electroorganic Chemistry (Hokkaido)  1992
  • Cathodic Coupling of Ketones with the Olefinic Systems Bearing the Silicon Functionalities  [Not invited]
    The 64th Annual Meeting of the Chemical Society of Japan (Niigata)  1992
  • Cathodic Coupling of 1,3-Dienes with Esters Using Chemically Reactive Magunesium Electrodes  [Not invited]
    Forum of Fellowship of the Japan Society for the Promotion of Science for Japanese Junior Scientists (Osaka)  1992
  • 1,3-ジエンとエステルとの電極還元カップリング反応  [Not invited]
    日本化学会第61春季年会(東京)  1991
  • マグネシウム電極を用いたポリ[p-(ジシラニレン)フェニレン]類の合成  [Not invited]
    日本化学会第61春季年会(東京)  1991
  • ケトンとオレフィンとの電極還元カップリング反応を鍵反応とする1,3-および1,4-ジオール類の合成  [Not invited]
    日本化学会第61春季年会(東京)  1991
  • Electroreductive Coupling of 1,3-Dienes with Esters Using Magnesium Electrodes  [Not invited]
    1991 International Symposium on Organic Reactions Kyoto (Kyoto)  1991
  • Electroreductive Formation of Polysilanes with Mg Electrodes  [Not invited]
    1991 International Symposium on Organic Reactions Kyoto (Kyoto)  1991
  • 反応性電極を用いた1,3-ジエンとエステルとの電極還元カップリング反応  [Not invited]
    日本化学会第62秋季年会(札幌)  1991
  • ケトンとビニルシラン類の電極還元カップリング反応  [Not invited]
    有機合成化学協会第60回有機合成シンポジウム(東京)  1991
  • Cathodic Coupling of 1,3-Dienes with Esters  [Not invited]
    The 61st Annual Meeting of the Chemical Society of Japan (Tokyo)  1991
  • Electroreductive Synthesis of Poly[p-(disilanylene)phenylene]s by Using Magnesium Erectrodes  [Not invited]
    The 61st Annual Meeting of the Chemical Society of Japan (Tokyo)  1991
  • Synthesis of 1,3-and 1,4-Diols by Using the Cathodic Coupling of Ketones with Olefins as a Key Reaction  [Not invited]
    The 61st Annual Meeting of the Chemical Society of Japan (Tokyo)  1991
  • Electroreductive Coupling of 1,3-Dienes with Esters Using Magnesium Electlodes  [Not invited]
    1991 International Symposium on Organic Reactions Kyoto (Kyoto)  1991
  • Electroreductive Formation of polysilanes with Mg Electrodes  [Not invited]
    1991 International Symposium on Organic Reactions Kyoto (Kyoto)  1991
  • Cathodic Coupling of 1,3-Dienes with Esters by Using Chemically Reactive Electrodes  [Not invited]
    The 62nd Annual Meeting of the Chemical Society of Japan (Sapporo)  1991
  • Cathodic Coupling of Ketones with Vinylsilanes  [Not invited]
    60th Symposium on Organic Synthesis (Tokyo)  1991
  • 亜鉛-DMF系を用いたカルボニル化合物のアリル化反応  [Not invited]
    日本化学会第59春季年会(神奈川)  1990
  • ビニルシラン類とカルボニル化合物の電極還元カップリング反応  [Not invited]
    日本化学会第59春季年会(神奈川)  1990
  • EGBを用いたカルボニル化合物のトリフルオロメチル化  [Not invited]
    日本化学会第59春季年会(神奈川)  1990
  • Allylation of Carbonyl Compounds Using Zn-DMF System  [Not invited]
    The 59th Annual Meeting of the Chemical Society of Japan (Kanagawa)  1990
  • Cathodic Coupling of Carbonyl Compounds with Vinylsilanes  [Not invited]
    The 59th Annual Meeting of the Chemical Society of Japan (Kanagawa)  1990
  • Trifluoromethylation of Carbonyl Compounds Using EGB  [Not invited]
    The 59th Annual Meeting of the Chemical Society of Japan (Kanagawa)  1990
  • 2-ピロリドンの電極還元により生成する活性アニオン種を塩基として用いたb-トリクロロメチルエステル類の合成  [Not invited]
    日本化学会第58春季年会(京都)  1989
  • Synthesis of β-Trichloromethylesters Using Active Anionic Species Generated by the Electroreduction of 2-Pyrrolidone  [Not invited]
    The 58th Annual Meeting of the Chemical Society of Japan (Kyoto)  1989
  • アミノアセチレンの遷移金属を用いる分子内アミノカルボニル化およびアミノヒドロキシル化反応  [Not invited]
    日本化学会第56春季年会(東京)  1988
  • シクロヘプタトリエン及びその誘導体の電極還元条件下における挙動  [Not invited]
    日本化学会第56春季年会(東京)  1988
  • Electrochemical Behaviour of Cycloheptatriene and its Derivatives under Cathodic Reducation Conditions  [Not invited]
    The 56th Annual Meeting of the Chemical Society of Japan (Tokyo)  1988
  • Intramolecular Aminocarbonylation and Aminohydroxylation of Aminoacetylene by Using Transition Metals  [Not invited]
    The 56th Annual Meeting of the Chemical Society of Japan (Tokyo)  1988

MISC

Awards & Honors

  • 2005 有機電子移動化学奨励賞
     JPN

Research Grants & Projects

  • Japan Society for the Promotion of Science:Grants-in-Aid for Scientific Research
    Date (from‐to) : 2008 -2010 
    Author : ISHIFUNE Manabu
     
    Optically active thermoresponsive polymers have been newly synthesized by polymerization of amino acid-derived acrylamide type monomers. The resulting polymers have successfully applied for the stereoselective encapsulation of organic molecules and environmental benign organic reactions. Moreover the thermoresponsive polymers have been fixed on the carbon-based materials by using living radical polymerization technique. The resulting functionalized carbon-based composites have been characterized in detail and used as functional electrodes in several electrochemical model reactions in aqueous media. Preliminary results indicating the switching phenomena of the electron transfer on the electrode were also obtained.
  • ジクロロシランの電極還元反応によるポリシランの精密重合法の開発
    JST地域イノベーション創出総合支援事業
    Date (from‐to) : 2008 -2008
  • ケイ素-ケイ素結合の電気化学的活性化を利用した新規ケイ素系デンドリマーの合成
    科学研究費補助金
    Date (from‐to) : 2002 -2004
  • Synthesis of New Silylene-dendrimers by Using the Electrochemical Activation of the Si-Si bonds
    Grant-in-Aid for Scientific Research
    Date (from‐to) : 2002 -2004
  • 下部臨界共溶温度を有する高分子存在下におけるアクリルアミド類の特異的重合反応
    科学研究費補助金
    Date (from‐to) : 2002 -2003
  • Characteristic Polymerization of Acrylamides in the Presence of the Polymers having Lower Critical Solution Temperature
    Grant-in-Aid for Scientific Research
    Date (from‐to) : 2002 -2003
  • Japan Society for the Promotion of Science:Grants-in-Aid for Scientific Research
    Date (from‐to) : 2001 -2002 
    Author : KASHIMURA Shigenori; ISHIFUNE Manabu
     
    It has been found in this study that, in the electroreduction of optically active dichlorosilanes with chemically reactive Mg electrode led to the formation of optically active polysilanes in high yields. In addition it was also found in this study that partial trnsfomation of phenyl group of phenylmethylpolysilane synthesized by the electroreduction to chloro group followed by the reaction with optically active Grignard reagents led to the formation of optiaclly active polysilanes with high yields. The reaction of above mentioned chlorosilane with optically active alcohols such as menthol also gave optically active polysilanes in reasonable yields. These methods can be carried out at room temperature and under ordinal pressure without using dangerous metal, and hence, the methods are practical for the synthesis of optically active polysilanes.
  • Japan Society for the Promotion of Science:Grants-in-Aid for Scientific Research
    Date (from‐to) : 2001 -2002 
    Author : KASHIMURA Shigenori; ISHIFUNE Manabu
     
    It has been found in this study that, in the electroreduction of optically active dichlorosilanes with chemically reactive Mg electrode led to the formation of optically active polysilanes in high yields. In addition it was also found in this study that partial trnsfomation of phenyl group of phenylmethylpolysilane synthesized by the electroreduction to chloro group followed by the reaction with optically active Grignard reagents led to the formation of optiaclly active polysilanes with high yields. The reaction of above mentioned chlorosilane with optically active alcohols such as menthol also gave optically active polysilanes in reasonable yields. These methods can be carried out at room temperature and under ordinal pressure without using dangerous metal, and hence, the methods are practical for the synthesis of optically active polysilanes.
  • Japan Society for the Promotion of Science:Grants-in-Aid for Scientific Research
    Date (from‐to) : 2000 -2001 
    Author : YAMASHITA Natsuki; ISHIFUNE Manabu; KASHIMURA Shigenori
     
    Template polymerization of acrylamide (Aam) was found to proceed in the presence of poly(methyl methacrylate) (PMMA) as a template polymer which have carbonyl groups in its side chains. Especially, the stereoregular PMMA which was syndiotactic or isotactic rich was prepared by the anionic polymerization using an adequate initiator., Using the prepared PMMA the polymerization of AAm was performed in THF, and the triad tacticlty of the resulting poly(acrylamide) (PAAm) was determined by NMR. At the beginning of the polymerization (conversion<10%), both of the syndiotactic rich (n>73.8%) and isotactic rich (mm>98.6%) PMMA as template polymers were found to afford relatively high content of rr and mm sequences respectively. However, the stereoregularity of the resulting polymers tended to decrease with the progress of polymerization. Furthermore, the polymerizability of AAm in the presence of isotactic rich PMMA was found to be much lower than syndiotactic rich PMMA. Aiming the formation of the strong interaction, the polymerization of AAm was carried out in the presence of poly (N-isopropylacrylamide) (PNIPAAm) which has amide groups in its side chains. Resultingly the transcription effect of the template polymer was found to increase in comparison with PMMA. Furthermore, several PNIPAAm templates having various molecular weights were prepared by the radical polymerization and subsequent fractionation, and the polymerization of AAm was also carried out in the presence of the resulting PNIPAAm templates in THF solvent. The polymerizability was remarkably affected by the molecular weight of the templates, that is, the increase of the molecular weight of PNIPAAm resulted in considerable decrease of the polymerizability. We have also investigated polymerization system because of its distinctive characters such as high polarity and viscosity. We have investigated the temperature effects in this polymerization and found that the LCST (Lower Critical Solution Temperature) of PNIPAAm as a template polymer concerns the polymeriability of AAm. Expecially, the polymerizability of AAm in the presence of PNIPAAm was found to be lower at the polymerization temperature below the LCST.
  • 金属-高分子錯体修飾電極の調製とこれを利用したレドックス反応系の高機能化
    科学研究費補助金
    Date (from‐to) : 1999 -2000
  • Japan Society for the Promotion of Science:Grants-in-Aid for Scientific Research
    Date (from‐to) : 1999 -2000 
    Author : KASHIMURA Shigenori; ISHIFUNE Manabu
     
    It has been found in this study that, in the electroreductive intermolecular coupling of ketones with silyl substituted olefins, the existence of silyl group was found to play a important role for the regioselectivity and stereoselectivity of the reaction. This reaction is highly useful for the preparation of diols, formation of Si-Si bonds, and Si- carbon bonds. The elimination of Si atom in the coupling products was found to lead to the formation of the corresponding alcohols. This electroreductive method was also found to be useful for the reductive coupling of Si- and Ge-containing organic compounds. For examples, the electroreductive coupling of hydrosilanes led to the formation of new Si-Si and Si-C bonds with ordered sequences. The electroreduction of dichlorogerman gave poly- and oligo-germans, and poly silane-germans in good yields. By utilizing this method, the synthesis of optically active poly- and oligo-silanes has also been attained in this study.
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1999 -1999 
    Author : 柏村 成史; 石船 学
     
    本研究では、反応性電極を用いた電極還元反応においてSi-Si結合が開烈し、活性なシリルアニオン種が発生することを見出した。特に、オリゴシランおよびポリシランを形成するケイ素連鎖の数により結合開烈の傾向が異なり、電極還元法を用いることで、この差異を積極的に利用して、位置選択的に結合切断を行うことができることが明らかになった。また、このようにして発生されたシリルアニオン種を求核剤とすることで、新規ケイ素-ケイ素結合、ケイ素-ゲルマニウム結合、および、ケイ素ー炭素結合形成反応が起こることを見出した。この方法の開発により、従来に例を見ない全く新しいタイプのポリシランを合成出来るだけでなく、シラン-ゲルマン共重合体を合成することも可能になった。また、電極還元反応により生成するシリルアニオンの再結合反応をも見出したが、この反応を利用すると、ポリシランや、シラン-ゲルマン共重合体の分子量を顕著に向上出来ることも明らかになった。さらに、ヒドロシラン類の電極還元重合反応により、構造制御を行ったジクロロシラン類を合成することにも成功し、このジクロロシラン類の電極還元により、構造の制御されたポリシランを高収率で合成することにも成功した。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1999 -1999 
    Author : 柏村 成史; 石船 学
     
    硝酸イオン(NO3-)の電極酸性化により生成する硝酸ラジカル(NO3・)を用いて、グラファイト電極や、炭酸繊維電極の表面酸化を行うことにより炭素電極表面上に高効率で酸素官能基および、窒素官能基を導入できることを見出した。この方法は、等方性炭素繊維、PAN系炭素繊維、および、グラファイト等に広範に適用可能であることが明らかになった。また。この方法は、炭素繊維電極の表面改質、特に、親水性炭素繊維の有効な作成法として極めて有効であり、酸化処理した炭素繊維を用いた複合プラスチック材料は未処理の炭素繊維を用いた場合と比べ約1,5倍の強度を示すことが明らかになった。さらに、炭素繊維上の官能基の反応性を利用して、炭素繊維電極の表面を化学的に修飾することも可能であることが明らかになった。これらの官能基により修飾した修飾炭素電極は、反応性に大きな違いがあり、たとえば、水酸基で修飾した電極を用いてベンゾフェノンの還元カップリングを行った結果生成物のd,1体の比率が未修飾の電極を用いた場合の約倍になり、電極表面の水酸基の効果が顕著に現われることを見出した。また、水酸基を立体的に嵩高いエステル基で修飾すると、カップリング生成物の比率が顕著に減少し、単純還元体であるアルコールの比率が増加することが明らかになった。さらに、光学活性なシトロネリックアシッドで修飾した電極ではd,1体の比率が顕著に変化することも分かった。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1998 -1998 
    Author : 柏村 成史; 石船 学
     
    本研究では、反応性電極を用いた電極還元反応においてSi-Si結合が開裂し、活性なシリルアニオン種が発生することを見出した。 特に、オリゴシラ ンを形成するケイ素連鎖の数により結合開裂の傾向が異なり、電極還元法を用いることで、この差異を積極的に利用して、位置選択的に結合切断を行うことができることが明らかになった。 また、このようにして発生させたシリルアニオン種を求核剤とすることで、新規ケイ素-ケイ素結合、ケイ素-ゲルマニウム結合、および、ケイ素一炭素結合形成反応が起こることを見出した。この方法の開発により、従来に例を見ない全く新しいタイプのポリシランを合成出来るだけでなく、シラン-ゲルマン共重合体を合成することも可能になった。 また、電極還元反応により生成するシリルアニオンの再結合反応をも見出したが、この反応を利用すると、ポリシランや、シラン-ゲルマン共重合体の分子量を顕著に向上出来ることも明らかになった。さらに、ヒドロシラン類の電極還元重合反応により、構造制御を行ったポリシランを高収率で合成することにも成功した。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1998 -1998 
    Author : 柏村 成史; 石船 学
     
    硝酸イオン(NO3-)の電極酸化により生成する硝酸ラジカル(NO3・)を用いて、グラファイト電極や、炭素繊維電極の表面酸化を行うことにより炭素電極表面上に高効率で酸素官能基および、窒素官能基を導入できることを見出した。 この方法は、ピッチ系炭素繊維、PAN系炭素繊維、およよび、グラファイト等に広範に適用可能であることが明らかになった。また、電極の極性を変換することにより、炭素繊維電極の表面にアミノ基を導入することにも成功した。 この方法は、炭素繊維電極の表面改質、特に、親水性炭素繊維電極の有効な作成法として極めて有効であり、酸化処理した電極は高い親水性を示した。さらに、これらの官能基の反応性を利用して、炭素繊維電極の表面を化学的に修飾することも可能であることが明らかになった。 これらの修飾電極は、反応性に大きな違いがあり、たとえば、水酸基で修飾した電極を用いてベンゾフェノンの還元カップリングを行った結果、生成物のd,l体の比率が未修飾の電極を用いた場合の約倍になり、電極表面の水酸基の効果が顕著に現れることを見出した。 また、水酸基を立体的に嵩高いエステル基で修飾すると、カップリング生成物の比率が顕著に減少し、単純還元体であるアルコールの比率が増加することが明らかになった。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1997 -1997 
    Author : 柏村 成史; 石船 学
     
    本研究では、反応性電極を用いた電極還元反応においてSi-Si結合が開裂し、活性なシリルアニオン種が発生することを見出した。特に、オリゴシランを形成するケイ素連鎖の数により結合開裂の傾向が異なり、電極還元法を用いることで、この差異を積極的に利用して、位置選択的に結合切断を行うことができることが明らかになった。また、このようにして発生させたシリルアニオン種を求核剤とすることで、新規ケイ素-ケイ素結合、ケイ素-ゲルマニウム結合、および、ケイ素-炭素結合形成反応が起こることを見出した。この方法の開発により、従来に例を見ない全く新しいタイプのポリシランを合成出来るだけでなく、シラン-ゲルマン共重合体を合成することも可能になった。また、電極還元反応により生成するシリルアニオンの再結合反応をも見出したが、この反応を利用すると、ポリシランや、シラン-ゲルマン共重合体の分子量を顕著に向上出来ることも明らかになった。さらに、ヒドロシラン類の電極還元重合反応により、構造規制を行ったポリシランを高収率で合成することにも成功した。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1997 -1997 
    Author : 柏村 成史; 石船 学
     
    硝酸イオン(NO_3^-)の電極酸化により生成する硝酸ラジカル(NO_3・)を用いて、グラファイト電極や、炭素繊維電極の表面酸化を行うことにより炭素電極表面上に高効率で酸素官能基および、窒素官能基を導入できることを見出した。この方法は、ピッチ系炭素繊維、PAN系炭素繊維、および、グラファイト等に広範に適用可能であることが明らかになった。また、電極の極性を変換することにより、炭素繊維電極の表面にアミノ基を導入することにも成功した。さらに、短繊維の炭素繊維を用いると、酸素官能基導入の電流効率が飛躍的に向上することが明らかになった。この方法は、炭素繊維電極の表面改質、特に、親水性炭素繊維電極の有効な作成法として極めて有効であり、酸化処理した電極は高い親水性を示した。さらに、これらの官能基の反応性を利用して、炭素繊維電極の表面を化学的に修飾することも可能であることが明らかになった。たとえば、種々のカルボン酸エステルで修飾すると、疎水性電極を作成することが出来、また、光学活性アミノ酸で修飾すると、光学活性修飾電極を作成することができた。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1995 -1995 
    Author : 柏村 成史; 石舟 学; 庄野 達哉
     
    マグネシウムを反応性電極を用いると新しい電極還元法を開拓し、この方法を用いて種々の有機化合物を電極還元すると極めて興味深い反応が進行することを明らかにした。たとえば、反応性電極としてマグネシウムを用いてアズレン、およびグアイヤアズレンを電極還元すると、対応するマグネシウム錯体が生成することを見いだした。さらに、反応性電極としてマグネシウムを用いた場合に、従来電極還元が困難であった脂肪族エステル、脂肪族アミド、芳香族化合物等が容易に電極還元されることを見いだしただけでなく、これらの反応に於て、マグネシウムが触媒的に還元に関与していることも明らかにした。また、マグネシウム以外の金属でもサマリウム、ユーロピウム、および、イッテルビウムのようなランタノイド金属がマグネシウムと同様に作用を有することを明らかにし、電極還元反応を利用したこれらのランタンノイド金属錯体の合成に成功しただけでなく、その特異な反応性を利用した新しい有機合成反応の開拓を行った。さらに、反応性電極による活性金属の生成に着目した研究をも行い、特に電極還元による活性金属マグネシウムの生成を利用した多くの新しい有機合成反応を開発することにも成功した。
  • 日本学術振興会:科学研究費助成事業
    Date (from‐to) : 1994 -1994 
    Author : 柏村 成史; 石舟 学; 庄野 達哉
     
    我々は、陰陽極にマグネシウム電極を用いる電極還元系に於て高度に活性な金属マグネシウムが生成し、これが電極還元系のメディエーターとして興味深い挙動を示すことを既に見い出している。本重点領域研究では、上述の活性な金属マグネシウムをメディエータとして用いて、従来電極還元が不可能であった脂肪族エステル、脂肪族アミド、および、芳香族化合物等の種々の有機化合物の電極還元を効率良く行うことを目的とした研究を行った結果、配位子としてテトラフェニルポルフィリンおよび、オクタエチルポルフィリンを有するマグネシウム錯体が、脂肪族エステルおよび脂肪族アミドを対応するアルコールに還元するためのメディエーターとして極めて有効なことを見い出た。この方法は、ポルフィリン錯体を触媒量反応系中に存在させることで、常温、常圧の温和な条件下で脂肪族エステルおよび脂肪族アミドを還元し、対応するアルコールを高収率で合成することが出来るために有機合成上極めて有用な方法である。さらに、この反応系においては、亜鉛、鉛、銅、ニッケル等の金属はメディエーターとして全く活性を示さないが、ユーロピウム、イッテルビウムおよび、サマリウム等のランタノイド類金属がメディエーターとして高い活性を有することをも明かにし、これらのランタノイド金属をメディエーターに用いる全く新しい間接電極還元系の開拓にも成功した。


Copyright © MEDIA FUSION Co.,Ltd. All rights reserved.