![](https://www.kindai.ac.jp/data/images/professor/2387.jpg)
HARUTA Masakazu
Department of Electric and Electronic Engineering | Associate Professor |
Last Updated :2024/08/31
■Researcher basic information
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J-Global ID
Research Keyword
- エネルギー材料 電気・電子材料 リチウムイオン電池 薄膜 超伝導
Research Field
- Manufacturing technology (mechanical, electrical/electronic, chemical engineering) / Electronic devices and equipment
- Nanotechnology/Materials / Energy chemistry
- Manufacturing technology (mechanical, electrical/electronic, chemical engineering) / Electric/electronic material engineering
- Nanotechnology/Materials / Crystal engineering
- Nanotechnology/Materials / Applied materials
■Career
Career
- 2020 - Today Kindai UniversityFaculty of Humanity-Oriented Science and Engineering准教授
- 2014 - 2020 Doshisha UniversityOffice for Research Initiatives and Development准教授
- 2013 - 2014 Tohoku University原子分子材料科学高等研究機構助手
- 2010 - 2013 Kochi University of TechnologySchool of Environmental Science and Engineering助教
- 2007 - 2010 産業技術総合研究所エレクトロニクス研究部門産総研特別研究員
- 2007 - 2007 Kumamoto Universityベンチャービジネスラボラトリーポスドク研究員
Educational Background
■Research activity information
Award
Paper
- Erika Svensson; Masakazu Haruta; Minoru Inaba; Takayuki DoiThe Journal of Physical Chemistry C American Chemical Society ({ACS}) 127 (17) 7921 - 7928 1932-7447 2023/05
- Ryosuke Sugimoto; Kohei Marumoto; Masakazu Haruta; Minoru Inaba; Takayuki DoiChemElectroChem 9 (17) 2022/09 [Refereed]
A flat and smooth Li6.6La3Zr1.6Ta0.4O12 (LLZT) pellet was used as a model solid electrolyte to evaluate Li+ transfer resistivity (Ω cm2) at an interface between an LLZT electrolyte and a silicon suboxide (SiOx) electrode. Two types of interfaces were employed; one was a “joint interface” that was formed by depositing a SiOx thin film directly on the LLZT pellet. The other was a “contact interface” that was formed by compressing a SiOx thin film on a Cu foil to the LLZT pellet, which is a more realistic and practicable interface in all-solid-state batteries. The quantitative evaluation of interfacial resistances revealed that Li+ transfer at the solid/solid interfaces was intrinsically more sluggish than that for a solid/liquid one using an electrolyte solution. The interfacial resistivity could be reduced by introducing an artificial solid electrolyte interphase (SEI) to the contact SiOx/LLZT interface. - Masakazu Haruta; Hiroto Konaga; Takayuki Doi; Minoru InabaJournal of The Electrochemical Society The Electrochemical Society 169 (2) 020519 - 020519 0013-4651 2022/01 [Refereed]
Cycle performance of silicon nano-flake powder (LeafPower® Si) anodes was improved by coating of perfluorosulfonic acid (PFSA) polymers (Nafion® and Aquivion®) as an artificial solid electrolyte interphase (SEI). The Si electrodes were coated with PFSA ionomer by addition of PFSA ionomer solution to aqueous slurry of the Si composite electrode. H+-type Nafion®-coated Si electrodes demonstrated improved capacity retentions and Coulombic efficiencies owing to the formation of a LiF-rich SEI composed of reductive decomposition products of Nafion®. The Nafion® coating suppressed the increase in polarization and the electrode swelling upon cycling because the LiF-rich SEI effectively suppressed electrolyte decomposition. Li+ and Cs+-type Nafion® and H+-type Aquivion®, which has a shorter side chain than Nafion®, provided similar positive effects on cycle performance of the Si electrodes. Furthermore, the Si electrodes achieved good cycleability up to 500 cycles owing to synergy effects of the Nafion® coating and an SEI-forming additive of fluoroethylene carbonate (FEC). - Cao, Z.; Haruta, M.; Doi, T.; Inaba, M.Journal of the Electrochemical Society The Electrochemical Society 167 (4) 040508 - 040508 2020/02 [Refereed]
- Kei Hosoya; Toshiki Kamidaira; Tetsuya Tsuda; Akihito Imanishi; Masakazu Haruta; Takayuki Doi; Minoru Inaba; Susumu KuwabataMaterials Advances Royal Society of Chemistry ({RSC}) 1 (4) 625 - 631 2020 [Refereed]
An appropriate combination of Si anodes and binary bis(fluorosulfonyl)amide-based ionic liquid electrolytes significantly improves Li-ion battery performances.
- Ziyang Cao; Masakazu Haruta; Takayuki Doi; Minoru InabaJournal of the Electrochemical Society 166 (16) A4005 - A4013 0013-4651 2019 [Refereed]
© 2019 The Electrochemical Society. In highly concentrated LiBF4/dimethyl carbonate (DMC) electrolyte, Ni-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) positive-electrode exhibited a good cycle performance and the crack formation in NCM811 particles was remarkably suppressed. However, the high concentration causes some problems, such as a high viscosity, a low ionic conductivity and a high cost. To solve these problems, we chose 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether (HFE) to dilute the concentrated LiBF4/ and LiPF6/DMC systems. The cycle performance of NCM811 electrode remarkably deteriorated in 0.96 mol kg-1 LiBF4/DMC+HFE (1:2 by volume). Raman spectra indicated that the fraction of freeDMCincreased in the diluted electrolyte, which led to instability against oxidation. However, in the LiPF6/DMC system, the fraction of free DMC had rarely increased after diluted with HFE. The diluted electrolyte showed a high stability against oxidation comparable to the nearly saturated electrolyte, and the NCM811 electrode showed an excellent cycle performance. - Masakazu Haruta; Takayuki Doi; Minoru InabaJournal of the Electrochemical Society 166 (2) A258 - A263 0013-4651 2019 [Refereed]
© 2019 The Electrochemical Society. The silicon - oxygen binary system (SiOx) is a promising candidate as a negative electrode for next-generation lithium-ion batteries. Thin SiOx films of different oxygen contents were prepared by magnetron sputtering. Although almost all Si atoms in SiOx at low oxygen contents (x = 0.21 and 0.48) contributed to the reversible alloying/dealloying reactions, an irreversible fraction of Si in SiOx at high oxygen contents (x = 1.09 and 1.78) increased owing to the formation of Li4SiO4. In return for the decrease of reversible capacity, the capacity retention of heavily O-doped SiOx films improved owing to the buffer effect of Li4SiO4 matrix against volume changes. The addition of vinylene carbonate (VC) to the electrolyte further improved the cyclability of the SiOx films, especially those of higher oxygen contents. For the pure-Si film, a sponge-like porous structure appeared after cycling owing to repeated crack formation and inhomogeneous volume changes, and resulted in massive electrode swelling. The morphology change with cycling was suppressed by the presence of Li4SiO4 matrix and a homogeneous solid electrolyte interphase derived from VC, resulting in a superior cycle performance of the heavily O-doped SiOx negative electrodes. - Satoshi Hashigami; Kei Yoshimi; Yukihiro Kato; Hiroyuki Yoshida; Toru Inagaki; Masakazu Haruta; Michihiro Hashinokuchi; Takayuki Doi; Minoru InabaChemistrySelect 4 (29) 8676 - 8681 2019 [Refereed]
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim LiNi0.5Co0.2Mn0.3O2 (NCM) particles coated with lithium boron oxide were prepared by an antisolvent precipitation method. In the antisolvent precipitation method, ethanol was used to strip off the hydrated water coordinated with lithium ions and borate ions. By the antisolvent precipitation method, the NCM particles were coated with a uniform layer of LiBO2. The capacity fading on cycling was successfully suppressed for the lithium boron oxide-coated samples. In addition, the rate capability was also improved by the coating. The lithium boron oxide coating effectively suppressed the increase of the electrode impedance associated with the electrolyte decomposition. Crack formation in the secondary particles after charge-discharge cycling was greatly inhibited for lithium boron oxide-coated NCM. It was demonstrated that the lithium boron oxide coating layer suppressed the side reactions not only on the particle surface, but also in the intergranular cracks by inhibiting the penetration of the electrolyte solution. - Takayuki Doi; Ryo Matsumoto; Takatsugu Endo; Ziyang Cao; Taishin Sato; Masakazu Haruta; Michihiro Hashinokuchi; Yoshifumi Kimura; Minoru InabaACS Applied Energy Materials 2019 [Refereed]
© 2019 American Chemical Society. A stability against oxidation of ester-based electrolyte solution was highly improved by a tandem preparation method, i.e., increasing concentration of lithium salt and diluting with a miscible diluent. The resultant saturated electrolyte solution offered a wide anodic potential window and allowed a LiNi0.5Mn0.2Co0.3O2 positive electrode to deliver charge/discharge capacities over 200 mAh g-1 up to 4.6 V almost without capacity fading after 50 cycles. The solution structure was studied to clarify the stabilizing mechanism of the electrolyte solution. On the basis of the results, this study presents a viable strategy to design an electrolyte solution with a wide potential window for various electrochemical systems. - Yukihiro Kato; Michihiro Hashinokuchi; Satoshi Hashigami; Kei Yoshimi; Hiroyuki Yoshida; Toru Inagaki; Masakazu Haruta; Takayuki Doi; Minoru InabaJournal of the Electrochemical Society 166 (6) A941 - A943 0013-4651 2019 [Refereed]
© 2019 The Electrochemical Society. Lithium silicate was incorporated within Ni0.5CoZMn0.3(OH)2 precursor particles via an anti-solvent precipitation method to prepare lithium silicate-added LiNi0.5Co0.2Mn0.3O2 (NCM) particles. Lithium silicate was found at the grain boundaries in the NCM secondary particles, which significantly improved the capacity retention in high voltage operation (3.0 4.6 V). Cross-sectional SEM images revealed that cracks were seriously formed inside the lithium silicate-free NCM particles after cycling, while crack formation was remarkably inhibited for lithium silicate-added NCM. These results suggested that lithium silicate at the grain boundaries strengthened the interfacial-adhesion between primary particles, resulting in the improved cycling stability. - Satoshi Hashigami; Yukihiro Kato; Kei Yoshimi; Akihiro Fukumoto; Ziyang Cao; Hiroyuki Yoshida; Toru Inagaki; Michihiro Hashinokuchi; Masakazu Haruta; Takayuki Doi; Minoru InabaACS Applied Materials and Interfaces 11 (43) 39910 - 39920 1944-8244 2019 [Refereed]
Copyright © 2019 American Chemical Society. The microstructure of LiNi0.8Co0.1Mn0.1O2 cathode materials was controlled by the addition of lithium silicate, and the influence on the cycle performance and the rate capability was investigated. Si was not included within the lattice, but localized at the grain boundaries of the primary particles and the pores inside the secondary particles. The addition of the lithium silicate greatly decreased the density of the pores between the primary particles and improved the density of the secondary particles. The capacity retention was successfully improved for lithium silicate-added LiNi0.8Co0.1Mn0.1O2. When lithium silicate-free LiNi0.8Co0.1Mn0.1O2 was charged to 4.3 V, many cracks were formed along the grain boundaries even in the first cycle, while crack formation was remarkably inhibited for lithium silicate-added LiNi0.8Co0.1Mn0.1O2. Moreover, lithium silicate-added LiNi0.8Co0.1Mn0.1O2 particles were almost free from visible microcracks even after 100 cycles at the discharged state. These results suggest that the lithium silicate reinforces the grain-adhesion at the grain boundaries, inhibiting crack formation and electrolyte decomposition inside the cracks. - Masakazu Haruta; Ryuya Hioki; Takashi Moriyasu; Akira Tomita; Toshio Takenaka; Takayuki Doi; Minoru InabaElectrochimica Acta Elsevier Ltd 267 94 - 101 0013-4686 2018/03 [Refereed]
Silicon flake powder (Si LeafPowder®, Si-LP) with the thickness and lateral dimension of 100 nm and 3–5 μm, respectively, demonstrated superior cycle performance as a negative electrode in lithium-ion batteries. A multi-folded layered structure with many voids was spontaneously formed in Si-LP composite electrodes by morphology changes of Si-LP sheets in repeated charge and discharge cycles. The multi-folded layered structure accommodated volumetric changes of the Si active material and prevented exfoliation of the active material from the current collector, which led to the superior long-term cyclability of the Si-LP electrode. The main factor for capacity fading in long-term cycling was a gradual loss of conduction pathways between Si-LP sheets due to the accumulation of electrolyte reduction products in the electrode. The film-forming additives, vinylene carbonate and fluoroethylene carbonate, effectively suppressed the electrolyte decomposition and remarkably improved the cycle performance of the Si-LP electrode. - Haruta, M.; Kijima, Y.; Hioki, R.; Doi, T.; Inaba, M.Nanoscale Royal Society of Chemistry ({RSC}) 10 (36) 2018 [Refereed]
- Haruta, M.; Moriyasu, T.; Tomita, A.; Takenaka, T.; Doi, T.; Inaba, M.Journal of the Electrochemical Society The Electrochemical Society 165 (9) A1874 2018 [Refereed]
- Doi, T.; Matsumoto, R.; Cao, Z.; Haruta, M.; Hashinokuchi, M.; Inaba, M.Sustainable Energy and Fuels Royal Society of Chemistry ({RSC}) 2 (6) 1197 2018 [Refereed]
- Minoru Inaba; Masakazu Haruta; Morihiro Saito; Takayuki DoiELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 85 (10) 623 - 629 1344-3542 2017/10 [Refereed]
Silicon is electrochemically alloyed and de-alloyed with Li at potentials close to Li+/Li and is widely recognized as the most promising candidate for the anode of LIBs with a high energy density (250-300 Wh kg(-1)) in the next generation. The most serious issue of Si anode is poor capacity retention owing to large volume changes during charging and discharging. We developed Si LeafPowder (R) with a nano-flake structure to overcome the poor capacity retention. However Si anodes still have some problems such as large irreversible capacity, ceaseless electrolyte decomposition, swelling of the electrode, etc. for use in high-energy density LIBs in the next generation. In this article, these problems and the challenges to mitigate them are overviewed based on our resent data obtained by Si nano-flakes (Si LeafPowder (R)). (C) The Electrochemical Society of Japan, All rights reserved. - Shuhei Yoshida; Takashi Okubo; Yuta Masuo; Yasuyuki Oba; Daisuke Shibata; Masakazu Haruta; Takayuki Doi; Minoru InabaELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 85 (7) 403 - 408 1344-3542 2017/07 [Refereed]
Charge and discharge properties of a graphite/SiOx composite electrode were studied over a wide range of charge/ discharge rates (1/20 to 5C) for use in automotive applications. The graphite/SiOx (90/10 by weight) composite electrode gave a high reversible capacity (453 mAh.g(-1)), and showed a good capacity retention at a low rate of 1/ 20 C. However, the capacity decreased significantly on cycling at a high rate of 2 C. From the analysis of the charging and discharging processes, it was found that the charging reaction occurs predominantly at SiOx particles initially at higher potentials and then proceeds at graphite particles at lower potentials to be fully charged. This tendency was also supported by a dependence of the activation energy of the charge transfer reaction on the state of charge (SOC) estimated by ac impedance analysis. Because the composite electrode contains only 10% SiOx the current was excessively concentrated to the SiOx particles at the initial state when charged at high rates. This caused crack formation in SiOx particles, and the resulting contact loss between particles was considered as the reason for the observed poor cycleability at 2 C. (c) The Electrochemical Society of Japan, All rights reserved. - Masakazu Haruta; Takashi Okubo; Yuta Masuo; Shuhei Yoshida; Akira Tomita; Toshio Takenaka; Takayuki Doi; Minoru InabaELECTROCHIMICA ACTA PERGAMON-ELSEVIER SCIENCE LTD 224 186 - 193 0013-4686 2017/01 [Refereed]
Silicon nanoflake powder (Si LeafPowder (R), Si-LP) used as an anode material for lithium-ion batteries has demonstrated superior cycle performance at 30 degrees C in an ethylene-carbonate-based electrolyte solution because its characteristic thin-film-based structure resists pulverization. However, capacity fading was accelerated at 60 degrees C owing to enhanced decomposition of the electrolyte solution and growth of a solid electrolyte interface (SEI), which leads to loss of the electronic contact between Si-LP particles. The SEI-forming additives vinylene carbonate (VC), fluoroethylene carbonate (FEC), and difluoroethylene carbonate improved the capacity retention and Coulombic efficiency at 30 degrees C. Although VC is the most effective additive at 60 degrees C, the discharge capacity was decreased dramatically at - 5 degrees C owing to poor ionic and electronic conductivity of the SEI layer formed from the VC-added electrolyte solution. The added FEC produced better performance in a wide temperature range of - 5 to 60 degrees C because the SEI layer formed in the FEC-added electrolyte solution had higher ionic and electronic conductivity than that formed from VC, even at - 5 degrees C. To obtain Si anodes with high discharge capacity and long cycle life, an appropriate choice of SEI-forming additive taking into account the operating temperature is important. (C) 2016 Elsevier Ltd. All rights reserved. - Shuhei Yoshida; Yuta Masuo; Daisuke Shibata; Masakazu Haruta; Takayuki Doi; Minoru InabaJOURNAL OF THE ELECTROCHEMICAL SOCIETY ELECTROCHEMICAL SOC INC 164 (1) A6084 - A6087 0013-4651 2017 [Refereed]
The amounts of adsorbed water on several kinds of carbon and silicon materials including Si nano-flake powder (Si LeafPowder, Si-LP) were determined at 250 degrees C. It was found that nano-sized Si materials adsorb a large amount of water even after being dried at 120 degrees C because of the hydrophilicity of the surface and the high specific surface area. The adsorbedwater on Si-LP can be removed, but not completely, after drying at a 180 degrees C. The charge and discharge characteristics of Si-LP, especially the initial irreversible capacity and the coulombic efficiencies upon repeated cycling, were significantly improved by removal of the adsorbed water at 180 degrees C. The 180 degrees C-dried sample also suppressed gas evolution during the initial charging and discharging cycle. From the results of gas analysis, it was found that gases evolved from the Si-LP electrodes were mainly H-2 and CO2. From the results of charge and discharge tests and gas analysis, the effect of the adsorbed water on the irreversible decomposition of the electrolyte solution was discussed. (C) The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved. - Zhe Li; Yutaro Kamei; Masakazu Haruta; Toshio Takenaka; Akira Tomita; Takayuki Doi; Shiguo Zhang; Kaoru Dokko; Minoru Inaba; Masayoshi WatanabeELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 84 (11) 887 - 890 1344-3542 2016/11 [Refereed]
A lithium-sulfur cell was developed, consisting of a Si nanoflake negative electrode, a Li2S/graphene positive electrode, and a non-flammable solvate ionic liquid electrolyte. This cell configuration allows us to avoid the use of Li metal electrode and the concomitant dendritic deposition of Li metal at the negative electrode during charging, thereby rendering the cell operation highly safe and stable. The solvate ionic liquid electrolyte solution was composed of tetraglyme, lithium bis(trifluoromethanesulfonyl)amide, and a hydrofluoroether. The solubility of lithium polysulfide (reaction intermediate of the positive electrode) is very low, resulting in high Coulombic efficiency of discharge/charge and long cycle life of the Si/Li2S cell. (C) The Electrochemical Society of Japan, All rights reserved. - Chih-Yao Chen; Teruki Sano; Tetsuya Tsuda; Koichi Ui; Yoshifumi Oshima; Masaki Yamagata; Masashi Ishikawa; Masakazu Haruta; Takayuki Doi; Minoru Inaba; Susumu KuwabataSCIENTIFIC REPORTS NATURE PUBLISHING GROUP 6 2045-2322 2016/10 [Refereed]
A comprehensive understanding of the charge/discharge behaviour of high-capacity anode active materials, e.g., Si and Li, is essential for the design and development of next-generation high-performance Li-based batteries. Here, we demonstrate the in situ scanning electron microscopy (in situ SEM) of Si anodes in a configuration analogous to actual lithium-ion batteries (LIBs) with an ionic liquid (IL) that is expected to be a functional LIB electrolyte in the future. We discovered that variations in the morphology of Si active materials during charge/discharge processes is strongly dependent on their size and shape. Even the diffusion of atomic Li into Si materials can be visualized using a back-scattering electron imaging technique. The electrode reactions were successfully recorded as video clips. This in situ SEM technique can simultaneously provide useful data on, for example, morphological variations and elemental distributions, as well as electrochemical data. - Masakazu Haruta; Susumu Shiraki; Takeo Ohsawa; Tohru Suzuki; Akichika Kumatani; Yoshitaka Takagi; Ryota Shimizu; Taro HitosugiSOLID STATE IONICS ELSEVIER SCIENCE BV 285 118 - 121 0167-2738 2016/02 [Refereed]
An all-in-vacuum (in-vacuo) fabrication and evaluation system for thin-film all-solid-state lithium batteries was designed and constructed. To prepare clean solid electrolyte/electrode interfaces, ultra-high-vacuum (UHV) chambers for the deposition of cathode, electrolyte, and anode thin films were directly connected to each other. Thus, throughout the fabrication and evaluation, the samples were maintained under UHV conditions, not exposed to air. The thin-film lithium battery, with a clean and well-defined solid electrolyte/electrode interface, exhibited very good electrochemical properties even without post-deposition annealing. This performance is attributed to the clean solid electrolyte/electrode interface prepared in the vacuum. (C) 2015 Elsevier B.V. All rights reserved. - Susumu Shiraki; Yoshitaka Takagi; Ryota Shimizu; Tohru Suzuki; Masakazu Haruta; Yukio Sato; Yuichi Ikuhara; Taro HitosugiTHIN SOLID FILMS ELSEVIER SCIENCE SA 600 175 - 178 0040-6090 2016/02 [Refereed]
We demonstrate the deposition of LiCoO2(11-20) epitaxial thin films on chemically etched Pt(110) substrates, and compare their electrochemical properties with those of LiCoO2(10-14) epitaxial thin films on sputter-annealed Pt(110) reconstructed substrates. Cyclic voltammogram measurements of LiCoO2(11-20) epitaxial films exhibit stable charge and discharge operations, despite the application of a compressive strain on the films. (C) 2016 Elsevier B.V. All rights reserved. - Ryotaro Kanazawa; Masakazu Haruta; Takayuki Doi; Minoru InabaELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 83 (10) 867 - 869 1344-3542 2015/10 [Refereed]
Carbon-modified ramsdellite titanium dioxide, TiO2(R), was prepared without using metallic Ti powder, and its charge and discharge properties was investigated as an anode of lithium ion batteries. Carbon sources (citric acid and multi-walled carbon nanotubes) were added in the calcination process to obtain a LiTi2O4 precursor. The carbon addition was indispensable to obtain stoichiometric LiTi2O4 as a precursor and the resulting Li+-free TiO2(R). The carbon-modified TiO2(R) had a round shape and a smaller particle size of 0.5-1.5 mu m. The discharge capacity and rate-capability were improved by carbon modification due to an enhancement of the electronic conductivity and a reduction of the lithium-ion diffusion path. (C) The Electrochemical Society of Japan, All rights reserved. - Shuhei Yoshida; Yuta Masuo; Daisuke Shibata; Masakazu Haruta; Takayuki Doi; Minoru InabaELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 83 (10) 843 - 845 1344-3542 2015/10 [Refereed]
To compensate a large initial irreversible capacity (Q(irr)) of silicon electrode, a novel Li pre-doping technique using Li-naphthalene complex/tetrahydrofuran solutions was developed. Li was successfully doped to amorphous silicon nano-flake particles, and the doping level of Li was easily controlled by adjusting naphthalene concentration. A large Q(irr) of the pristine electrode (1200 mAh g(-1)) was almost completely compensated after pre-doped in 0.1 mol dm(-3) Li-naphthalene solution for 1 h. In addition, no harmful effects of pre-doping on cycleability were observed. (C) The Electrochemical Society of Japan, All rights reserved. - Shigeru Horii; Masakazu Haruta; Ataru Ichinose; Toshiya DoiJOURNAL OF APPLIED PHYSICS AMER INST PHYSICS 118 (13) 0021-8979 2015/10 [Refereed]
We report the dependence of critical temperature (T-c), the irreversibility line, the microstructure of nanorods with perovskite-based barium niobates (BNOs), and the c-axis length of the YBa(2)Cu(3)Oy (Y123) superconducting matrix on the BNO-doping level and growth temperature for Y123 thin films with BNO nanorods. The characteristic field (B-cr) determined from the vortex-Bose-glass-like irreversibility lines in Y123+BNO films is strongly correlated to the BNO nanorod density and the growth temperature. Despite a monotonic decrease in T-c with increasing B-cr and nanorod density, the irreversibility fields (B-irr) were enhanced up to B-cr similar to 5 T. From the B-cr value and the mean diameter of the BNO nanorod (similar to 10 nm), we estimate that a lower T-c matrix annulus with a diameter of 12-14 nm exists around each BNO nanorod due to the strong interface strains. Our present study suggests that generation of this lower T-c region around each BNO nanorod increases the vortexpinning strength significantly and, moreover, may offer a new way of enhancing B-irr for REBa2Cu3Oy film with nanorods. (C) 2015 AIP Publishing LLC. - Masakazu Haruta; Yuta Masuo; Takashi Moriyasu; Akira Tomita; Chihiro Sakakibara; Akika Kamei; Masato Hirota; Toshio Takenaka; Takayuki Doi; Minoru InabaELECTROCHEMISTRY ELECTROCHEMICAL SOC JAPAN 83 (10) 837 - 839 1344-3542 2015/10 [Refereed]
Charge and discharge properties of amorphous Si nano-flake powder (Si Leaf Powder (R), Si-LP) in lithium bis(trifluoromethanesulfonyl)amide-tetraglyme complex electrolyte, [Li(G4)][TFSA], were investigated for use as an anode in silicon-sulfur battery. Though a high reversible capacity (2,300-2,700 mAh g(-1)) was obtained initially in [Li(G4)][TFSA], the overpotential gradually increased upon cycling. The increase in overpotential was reduced by dilution with 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether. The addition of fluoroethylene carbonate (FEC) further reduced the overpotential and improved cycleability. Electrochemical impedance spectroscopy analysis revealed that the observed improvements in charge and discharge characteristics are due to the formation of solid electrolyte interface layer with a high ionic-conductivity in the presence of FEC. (C) The Electrochemical Society of Japan, All rights reserved. - Masakazu Haruta; Susumu Shiraki; Tohru Suzuki; Akichika Kumatani; Takeo Ohsawa; Yoshitaka Takagi; Ryota Shimizu; Taro HitosugiNANO LETTERS AMER CHEMICAL SOC 15 (3) 1498 - 1502 1530-6984 2015/03 [Refereed]
In this paper, we report the surprisingly low electrolyte/electrode interface resistance of 8.6 Omega cm(2) observed in thin-film batteries. This value is an order of magnitude smaller than that presented in previous reports on all-solid-state lithium batteries. The value is also smaller than that found in a liquid electrolyte-based batteries. The low interface resistance indicates that the negative space-charge layer effects at the Li3PO4-xNx/LiCoO2 interface are negligible and demonstrates that it is possible to fabricate all-solid state batteries with faster charging/discharging properties. - Susumu Shiraki; Hideki Oki; Yoshitaka Takagi; Tohru Suzuki; Akichika Kumatani; Ryota Shimizu; Masakazu Haruta; Takeo Ohsawa; Yukio Sato; Yuichi Ikuhara; Taro HitosugiJOURNAL OF POWER SOURCES ELSEVIER SCIENCE BV 267 881 - 887 0378-7753 2014/12 [Refereed]
We demonstrate the orientation control of LiCoO2 epitaxial thin films deposited on (110)-2 x 1 reconstructed surfaces of Au and Pt by using pulsed laser deposition. The epitaxial LiCoO2 thin films have CoO2 layers tilted with respect to the surface normal, which is suitable for Li-ion insertion/extraction reactions in LiCoO2. We show the successful operation of all-solid-state thin-film Li-ion batteries by employing the epitaxial LiCoO2 thin films as cathodes. The electrochemical properties of epitaxial films in all-solid-state batteries are improved compared to the batteries using liquid electrolyte. (C) 2014 Elsevier B.V. All rights reserved. - Shigeru Horii; Momoko Yamaki; Masakazu Haruta; Jun-Ichi ShimoyamaELECTRONICS AND COMMUNICATIONS IN JAPAN WILEY-BLACKWELL 97 (4) 10 - 18 1942-9533 2014/04 [Refereed]
We report changes in the degree of triaxial orientation as functions of the applied magnetic field and rotation rate for Y2Ba4Cu7Oy powder samples oriented in epoxy resin under modulated rotating magnetic fields (MRFs). Although the degrees of orientation were reduced as a result of a decrease in both the applied field and rotation rate, the mechanisms of the reduction of the degrees of orientation were found to be different. Optimization of the MRF conditions or quantification of triaxial magnetic anisotropy in a target substance is required for the production of triaxially oriented ceramics based on a colloidal process. - R. Nagai; S. Horii; T. Maeda; M. Haruta; J. ShimoyamaPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 494 50 - 53 0921-4534 2013/11 [Refereed]
We report relationship between the degrees of tri-axial orientation and doping level of rare earth (RE) ions in Bi2Sr2(Ca1 xREx)Cu2Oy (RE-doped Bi2212; RE = Dy, Ho, Er and Tm) powder samples aligned under a modulated rotation magnetic field (MRF) of 10 T. Tri-axial magnetic alignment of the RE-doped Bi2212 with x = 0-0.5 was achieved by single-ion magnetic anisotropy of RE3+ and tri-axial magnetic anisotropy induced by modulation microstructure in a grain level. The degrees of in-plane and c-axis orientation with similar to 3 degrees were achieved for the case of the Tm-doped Bi2212 with x = 0.5. The findings in the present study give us important information for the fabrication of triaxially oriented Bi-based cuprate superconductor materials by the magneto-scientific process. (C) 2013 Elsevier B.V. All rights reserved. - T. Ugawa; S. Horii; T. Maeda; M. Haruta; J. ShimoyamaPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 494 41 - 45 0921-4534 2013/11 [Refereed]
We report magnetic alignment of YBa2(Cu-1 Fe-x(x))(3)O-y (Fe-doped Y123, x = 0-0.1) powders under modulated rotation magnetic fields (MRFs) and roles of Fe ion as a determination factor of magnetic anisotropy in Y123. The Fe-free and Fe-doped Y123 powder samples aligned in the MRF of 10 T showed two different orientation types of the hard axis in Y123 grains. From an X-ray rocking curve measurement for the magnetically aligned powder samples of the Fe-doped Y123, inplane magnetic anisotropy for Y123 grains with the hard axis parallel to the [110] direction was found to be higher than that for Y123 grains with the hard axis parallel to the [010] direction. (C) 2013 Elsevier B.V. All rights reserved. - N. Fujita; M. Haruta; A. Ichinose; T. Maeda; S. HoriiPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 494 140 - 143 0921-4534 2013/11 [Refereed]
The vortex-Bose-glass-like irreversibility lines (ILs) emerged for 2.5 and 5.0 at.% Ba-Nb-O (BNO)-doped YBa2Cu3Oy films deposited by PLD using Nd:YAG-laser. The ILs strongly depended on growth temperature (T-s) in addition to the doping level of BNO. The vortex glass region was expanded with increasing T-s or doping level of BNO. Drastic change of the nanorod morphology from short and bended nanorods to long and linear nanorods with increasing T-s was clarified. Moreover, it was found that T-s-dependent ILs were quite different from our previous results in BNO-doped ErBa2Cu3Oy films. (C) 2013 Elsevier B. V. All rights reserved. - S. Horii; T. Ugawa; M. Haruta; A. Ishihara; J. ShimoyamaIEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC 23 (3) 1051-8223 2013/06 [Refereed]
The effects of doping of the cobalt ion on magnetic anisotropy in twinned and orthorhombic YBa2Cu3Oy (Y123) were clarified from their magnetic alignment behaviors under a modulated rotating field of 10 T. The cobalt-free Y123 shows two different types of inplane orientation due to the twin microstructure, and the cobalt-doping induced a structural change into a tetragonal phase and conversion of the magnetic hard axis from the b-axis ([100] grain) into a [110] direction ([110] grain). Furthermore, magnetic alignment under a modulated rotating field of 5 T revealed that the inplane magnetic anisotropy of the [110] grains is superior to that of the [100] grain. It is likely that crystallochemical control at the chain site in Y123 promotes the bi-axial orientation using the [110] grains as a grain alignment type for the bi-axial magnetic alignment of twined Y123. - M. Haruta; A. Ichinose; N. Fujita; K. Saura; T. Maeda; S. HoriiIEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC 23 (3) 1051-8223 2013/06 [Refereed]
Growth temperature (T-s) dependent microstructures of nanorods were clarified for BaNb2O6 (BNO)-doped YBa2Cu3Oy (Y123) films. The morphology of BNO in the Y123 matrix was changed from fluctuated nanorods to uniform nanorods with the increase in T-s. Reflecting this change in the nanorod morphology, spatial distribution of local critical current density (J(cl)) determined from the percolation transition model became sharp with the increase in T-s. The sharp distribution of J(cl) led to a steep slope of electric field vs. current density curve and a sharp J(c) peak under B//c in the magnetic field angular dependence. The evaluation of the distribution of J(cl) is a strong tool to understand quantitatively the relationship between the microstructure of nanorods and critical current properties for RE123 films with nanorods. To optimize the critical current properties under the magnetic field for RE123 coated conductors with nanorods, precise control of T-s is very important in the production process. - Relationship between critical current properties and nanorod morphology in REBa2Cu3Oy thin filmsM. Haruta; N. Fujita; Y. Ogura; T. Nakata; T. Maeda; A. Iichinose; P. Mele; K. Matsumoto; S. HoriiMat. Res. Soc. Symp. Proc. 1434 1588 - 1593 2013 [Refereed]
- Relationship between grain size and the degrees of orientation in a twinned ErBa2Cu3Oy superconductor oriented in modulated rotating magnetic fieldsS. Horii; S. Okuhira; M. Yamaki; M. Haruta; J. ShimoyamaMat. Res. Soc. Symp. Proc. 1434 918 - 923 2013 [Refereed]
- Masakazu Haruta; Keisuke Saura; Natsuto Fujita; Yuta Ogura; Ataru Ichinose; Toshihiko Maeda; Shigeru HoriiPhysica C: Superconductivity and its Applications 494 158 - 162 0921-4534 2013 [Refereed]
In-field Jcs were improved by introducing Ba-Nb-O (BNO)-nanorods in YBa2Cu3Oy (Y123) and ErBa 2Cu3Oy (Er123) films. Retention of J c against the magnetic field for the BNO-doped Er123 film was superior to that for the BNO-doped Y123 film. Sharp distribution of local critical current density originating from vortex pinning by nanorods with uniform morphology was demonstrated in the Er123 film. On the other hand, fluctuating microstructures of nanorods formed in the Y123 film prepared by the same deposition conditions. Moreover, different growth temperature dependences of nanorod morphology between the Y123 and Er123 films were clarified. © 2013 Elsevier B.V. All rights reserved. - Shigeru Horii; Natsuki Okamoto; Keisuke Aoki; Masakazu Haruta; Jun-ichi Shimoyama; Kohji KishioJOURNAL OF APPLIED PHYSICS AMER INST PHYSICS 112 (4) 0021-8979 2012/08 [Refereed]
The tri-axial grain alignment of thermoelectric Bi-based cobaltites with a misfit-layered structure by a modulated rotation magnetic field (MRF) of 10 tesla (T) was demonstrated. To maximize the degrees of tri-axial grain alignment in [ (Bi2-xPbx)(AE(2-y)RE(y))O-4](p)CoO2 powder samples aligned under the MRF of 10 T, the following three crystallochemical approaches are important: doping of Pb into the Bi site, appropriate choice of an alkali earth (AE) ion, and doping of the appropriate rare earth (RE) ion into an AE site. Namely, simultaneous introduction of the relaxation effect of the misfit structure, creation of a domain structure with shear-type discontinuity, and single-ion magnetic anisotropy, which are induced by doping of Pb, Sr, and RE (Pr and Nd), respectively, into the Bi-based cobaltite achieved high degrees of tri-axial grain alignment below 4 degrees. The present study provides a crystallochemical strategy for the fabrication of grain-aligned ceramics of misfit-layered Bi-based cobaltites with high thermoelectric performance by the magneto-scientific technique using MRF. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4747940] - Masakazu Haruta; Ataru Ichinose; Natsuto Fujita; Yuta Ogura; Takahiro Nakata; Toshihiko Maeda; Shigeru HoriiAPPLIED PHYSICS EXPRESS JAPAN SOC APPLIED PHYSICS 5 (7) 1882-0778 2012/07 [Refereed]
Uniform irreversibility lines (ILs) and the morphology of nanorods independent of the growth temperature (T-s) were demonstrated by controlling the chemical compositions in superconducting REBa2Cu3Oy (RE123) matrix. Tailoring the composition ratios of Y and Er in an RE123 matrix using Ba-Nb-O-doped Y123 and Er123 films with opposite T-s-dependent ILs, almost constant ILs with a matching field of similar to 4 T, and linear growth of nanorods were achieved in a wide T-s region of 40 degrees C (T-s = 850-890 degrees C). The present study provides a novel strategy for the doping of nanorods in RE123-coated conductors with spatially uniform and high in-field critical current properties. (C) 2012 The Japan Society of Applied Physics - T. Tashiro; T. Maeda; R. Abe; S. Takechi; T. Takahashi; M. Haruta; S. HoriiADVANCES IN SUPERCONDUCTIVITY XXIV ELSEVIER SCIENCE BV 27 21 - 23 1875-3892 2012 [Refereed]
One of related materials to high-temperature superconductors (HTSC's) with nominal compositions of (Pb0.5Co0.5)Sr-2(Y1-xCax) Cu(2)Oz (x=0 similar to 0.6) is synthesized and characterized. All samples are nearly single-phase, and its crystal structure is likely to be so-called '' 1-2-1-2 '' type which is one of typical structures of HTSC's. Electrical resistivity is decreased as x increases. While superconductivity is not observed at temperatures between room-temperature and 20 K for all samples, temperature dependence of the resistivity exhibits metallic behavior down to 150 K for x=0.5. Phase formation and transport behavior are discussed focusing on mixed valence-state of Co2+ and Co3+. (C) 2011 Published by Elsevier Ltd. Selection and/or peer-review under responsibility of ISS Program Committee. - M. Yamaki; S. Horii; M. Haruta; J. ShimoyamaADVANCES IN SUPERCONDUCTIVITY XXIV ELSEVIER SCIENCE BV 27 136 - 139 1875-3892 2012 [Refereed]
We report an effect of rotation speed (Omega) on the degrees of orientation of three different crystallographic axes for Y2Ba4Cu7Oy powders oriented under modulated rotation magnetic fields (MRFs) of 10 T. The degrees of inplane and c-axis orientations below 4 degrees were achieved for the MRFs with Omega >= 10 rpm in 10 T. The hard magnetic axis, the b-axis, of Y247 was highly oriented even for the lowest rotation speed, Omega = 1 rpm, within the present study. However, the degrees of orientations of the first and secondary easy axes, were drastically reduced for Omega < 10 rpm. The present study revealed that, under the MRF of 10 T, the decrease in Omega induced the following of the first easy axis synchronized with by the rotation of magnetic fields, and gives us important information for the fabrication of tri-axially oriented RE-based cuprate superconductors by the magneto-scientific process using MRF. (C) 2012 Published by Elsevier B.V. Selection and/or peer-review under responsibility of ISS Program Committee - Masakazu Haruta; Natsuto Fujita; Toshihiko Maeda; Shigeru HoriiSUPERCONDUCTIVITY CENTENNIAL CONFERENCE 2011 ELSEVIER SCIENCE BV 36 1576 - 1581 1875-3892 2012 [Refereed]
Bi-axially oriented YBCO thin films with BNO-nanorods were obtained by a low cost PLD process using Nd:YAG-laser in the substrate temperature (T-s) range of 850-890 degrees C, and the degrees of orientation for the films are comparable to those of YBCO films prepared by PLD with excimer-laser. The vortex-Bose-glass-like behavior of irreversibility lines emerged and strongly depended on T-s in the YBCO films with BNO-nanorods. Dependence of J(c) on the magnetic field was improved by introduction of BNO-nanorods, whereas J(c) properties were sensitively affected by T-s. Control of T-s is an important factor for the production of high-performance REBCO coated conductors with nanorods. (C) 2012 Published by Elsevier B. V. Selection and/or peer-review under responsibility of the Guest Editors. - Shigeru Horii; Natsuto Fujita; Yuta Ogura; Toshihiko Maeda; Masakazu HarutaADVANCES IN SUPERCONDUCTIVITY XXIV ELSEVIER SCIENCE BV 27 220 - 223 1875-3892 2012 [Refereed]
We report optimization of substrate temperature (T-s) regions for achievement of the bi-axially oriented growth without the a-axis oriented domains, critical current properties and crystallinities in REBa2Cu3Oy (RE123) films (RE= Y and Er) grown by pulsed laser deposition using a Nd:YAG laser. Appropriate T-s regions for achieving both high critical temperature and self-field critical current density in Y123 and Er123 films were found to be similar. In the case of Y123, infield critical current densities and inplane lattice parameters for the Y123 films grown in a lower T-s region were slightly changed compared with those for the films grown at a higher T-s region. Our findings in the present study give us fundamental information to understand intrinsic effects of introduction of nanorods in the RE123 films containing nanorods. (C) 2012 Published by Elsevier B.V. Selection and/or peer-review under responsibility of ISS Program Committee. - K. Aoki; S. Horii; M. Haruta; H. Ogino; J. ShimoyamaADVANCES IN SUPERCONDUCTIVITY XXIV ELSEVIER SCIENCE BV 27 164 - 167 1875-3892 2012 [Refereed]
From magnetic orientation under static and rotating magnetic fields for REOFeAs, REOCuS and FeCh, we discuss determination factors of magnetic anisotropies for the above compounds. Behaviours of the magnetic orientation were quite different between REOFeAs and REOCuS, and revealed that FeAs layers and RE3+ ions played main roles as determination factors of magnetic anisotropies in REOFeAs and REOCuS, respectively. Furthermore, FeSe and FeTe compounds with the same crystal structure possess different magnetic axes, and we clarified that FeTe was the one and only compound with the easy axis parallel to the c-axis among the Fe-based layered compounds. (C) 2012 Published by Elsevier B.V. Selection and/or peer-review under responsibility of ISS Program Committee - Horii, S.; Yamaki, M.; Haruta, M.; Shimoyama, J.-I.IEEJ Transactions on Fundamentals and Materials Institute of Electrical Engineers of Japan ({IEE} Japan) 132 (6) 397 2012 [Refereed]
- Momoko Yamaki; Shigeru Horii; Masakazu Haruta; Jun-ichi ShimoyamaJAPANESE JOURNAL OF APPLIED PHYSICS JAPAN SOC APPLIED PHYSICS 51 (1) 010107 0021-4922 2012/01 [Refereed]
Tri-axial orientation under modulated rotation magnetic fields (MRFs) and the growth of single crystals in ambient pressure were demonstrated in various REBa2Cu4O8 (RE124; RE, rare earth elements) compounds. RE124 crystals have been successfully grown for RE = Y, Sm, Eu, Gd, Dy, Ho, and Er. Optimal growth temperature regions for RE124 largely depended on the type of RE and became narrower in the case of lighter RE ions. By applying an MRF of 10 T, powders of all the grown RE124 were tri-axially oriented in epoxy resin at room temperature, and their orientation axes were clearly dependent on the type of RE ions in RE124. Furthermore, it was found from the changes in the degree of orientation under three different MRF conditions that tri-axial single-ion magnetic anisotropies of heavy RE3+ ions were highest among magnetic anisotropies generated by Cu-O networks and RE3+ ions. The appropriate choice of RE ions in RE-based cuprate superconductors enables the reduction of the magnetic field required for the production of bulk and thick films based on the magnetic orientation technique. (C) 2012 The Japan Society of Applied Physics - M. Yamaki; S. Horii; M. Haruta; T. Maeda; J. ShimoyamaPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 471 (21-22) 872 - 875 0921-4534 2011/11 [Refereed]
We report the rare-earth (RE)-dependent magnetization axes of REBa2Cu4O8, which was synthesized by a flux method under ambient pressure, using powder samples tri-axially oriented in a modulated rotating magnetic field of 10 T. By optimizing the growth temperature and cooling rate, RE124 crystals were successfully grown for RE = Y, Sm, Eu, Gd, Dy, Ho, and Er. From the X-ray diffraction measurement, the magnetically oriented directions were largely dependent on the type of RE ions of RE124. However, the tri-axial magnetic anisotropies of RE124 could be qualitatively understood in terms of the magnitude relation between the single-ion magnetic anisotropy of RE3+ ions and the magnetic anisotropy generated by the CuO2 plane and Cu-O chain. For the practical use of this magneto-scientific process, the control of magnetization axes and tri-axial magnetic anisotropies through crystallochemical control is indispensable. (C) 2011 Elsevier B.V. All rights reserved. - S. Horii; S. Okuhira; M. Yamaki; M. Haruta; T. Maeda; J. ShimoyamaPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 471 (21-22) 867 - 871 0921-4534 2011/11 [Refereed]
We report the tri-axial grain-orientation effects under a modulated rotation magnetic field for (Y1-xErx)(2) Ba4Cu7Oy), [ (Y, Er)247]. The magnetic easy axis at room temperature was drastically changed around x similar to 0.1: however, the Er-doping levels for the conversion of magnetic easy axes from the c-axis to the ab-direction and from the a- to b-axes were quite different. Tr-axial single-ion magnetic anisotropy of Er3+ was roughly 10 times greater than tri-axial magnetic anisotropy generated by both the superconducting CuO2 plane and the blocking Cu-O chain layer. An appropriate choice of rare-earth (RE) ions in RE-based cuprate superconductors enables the reduction of the required magnetic field for the production of bulks and thick films based on the magnetic orientation technique. (C) 2011 Elsevier B.V. All rights reserved. - M. Haruta; T. Sueyoshi; T. Fujiyoshi; M. Mukaida; H. Kai; K. Matsumoto; P. Mele; T. Maeda; S. HoriiPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 471 (21-22) 944 - 946 0921-4534 2011/11 [Refereed]
Irreversibility lines and distributions of local critical current density (J(cl)) based on the percolation transition model were affected by the growth temperature (T-s) in 3.5 wt.%-BaNb2O6-doped ErBa2Cu3Oy thin films. The vortex-Bose-glass-like state appeared by the introduction of nano-rods, and this vortex state was affected by T-s The shape and width of the J(cl) distribution strongly depended on T-s. These results are probably caused by variations of the density and the growth direction for nano-rods reflecting T-s. The growth temperature is an important factor to achieve higher critical current properties under magnetic fields for coated conductors of rare-earth-based cuprates with nano-rods. (C) 2011 Elsevier B.V. All rights reserved. - T. Maeda; S. Takechi; K. Yamasaki; S. Isono; T. Tashiro; M. Haruta; S. HoriiPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 471 (21-22) 608 - 610 0921-4534 2011/11 [Refereed]
(Pb0.5Fe0.5)Sr-2(Y0.5Ca0.5)Cu2O2 is known to have so-called "1-2-1-2" crystallographic structure which is one of typical structures of high-temperature superconducting cuprates (HTSC's). While it possesses structural characteristics of HTSC's, superconductivity has not been reported so far. In this study, phase formation, electrical properties and structural characteristics of this compound are investigated. It is shown that this phase can be synthesized using several kinds of rare-earth element and that post-annealing in O-2 is effective for decreasing electrical resistivity. The latter suggests that this "1-2-1-2" can be made superconducting by appropriate carrier-doping into the [Cu-O-2] plane. Preliminary Rietveld structural refinement using powder X-ray diffraction data show that the initial structural model based on the nominal (Pb,Fe)Sr-2(Y,Ca)Cu2Oz is basically correct except for true site-distribution of Fe and Cu. (C) 2011 Elsevier B.V. All rights reserved. - 春田正和; 堀井滋高知工科大学紀要 高知工科大学 8 (1) 81 - 87 1348-4842 2011/07希土類系高温超伝導薄膜における実用レベルの磁場中臨界電流密度の実現を目的として、第二相であるナノロッドを超伝導母相中に導入し、成膜温度が臨界電流特性(不可逆曲線、電流-電圧特性)に与える影響を明らかにした。ナノロッドが一次元欠陥として作用すれば、磁場中臨界電流密度の向上が期待される。不可逆曲線からは欠陥導入による磁束状態の変化を評価でき、また電流-電圧特性から超伝導組織の均一性・高性能性を表す臨界電流密度の空間分布を評価できる。Ba-Nb-O系ナノロッドを導入したErBa2Cu3Oy薄膜において、一次元欠陥導入時に特徴的なBoseグラス的磁束状態に起因した不可逆曲線が現れ、成膜温度によって不可逆曲線の振る舞い及び、臨界電流密度の空間分布が変化することを見出した。これらの結果は、成膜温度によってナノロッドの密度および形態が変化することにより、磁場中超伝導特性が大きく変化したことを示唆する。本研究から、磁場中送電能力の高い希土類系高温超伝導線材の製造プロセスの制御因子としての成膜温度の重要性が明らかとなった。査読あり論文
- S. Horii; H. Ogino; M. Yamaki; M. Haruta; T. Maeda; J. ShimoyamaIEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC 21 (3) 2741 - 2744 1051-8223 2011/06 [Refereed]
Tri-axial orientation of twin-free powder of Y2Ba4Cu7O15-delta (Y247) and uni-axial orientation of various FeAs-based compounds were attempted using modulated rotating and rotating magnetic fields, respectively. Tri-axial orientation with high degrees of inplane and c-axis orientation of Y247 was achieved under magnetic fields above 5 T, while magnetic fields at which reduction of the degrees began were different. We found from these crossover fields that quantitative magnetic anisotropy could be obtained. This determination method is particularly useful in that single crystalline samples are not required. From the magnetic orientation using the rotating field, all the obtained FeAs-based compounds showed a hard axis of magnetization parallel to the c-axis direction. On the other hand, the degrees of c-axis orientation were dependant on the types of ions in the blocking layers, and almost complete c-axis orientation was achieved for the compounds with transition-metal ions containing 3d electrons. Magnetic orientation using powder samples is a strong tool for the clarification of physical properties of Cooper pairs and critical current properties in FeAs-based superconductors. - Masakazu Haruta; Shigeki SakaiSUPERCONDUCTOR SCIENCE & TECHNOLOGY IOP PUBLISHING LTD 23 (11) 0953-2048 2010/11 [Refereed]
Thin films of Bi2Sr2CaCu2O8+delta (Bi-2212) covered by layers of Ag in selected regions were grown by pulsed-laser deposition with subsequent annealing. The grain size at the Ag-covered region was as large as 60-90 mu m. These grains were about three times as large as those in conventional films lacking the covering layer of silver, and the optimal annealing temperature for the silver-covered films was 15 degrees C lower than that for the uncovered films. The technique was adopted for use in the fabrication of intrinsic Josephson junctions (IJJs). The mesa structure for IJJs was fabricated on a Bi-2212 film with a 60 nm thick layer of silver annealed at 876 degrees C, and the resulting IJJs exhibited current-voltage characteristics that showed clear multiple branches. - FUJIYOSHI Takanori; SUEYOSHI Tetsuro; HARUTA Masakazu; YONEKURA Kenji; IKEGAMI Tomoaki; ISHIKAWA Norito; AWAJI Satoshi; WATANABE KazuoTEION KOGAKU (Journal of Cryogenics and Superconductivity Society of Japan) CRYOGENICS AND SUPERCONDUCTIVITY SOCIETY OF JAPAN 44 (12) 517 - 522 0389-2441 2009/12 [Refereed]
The effects of columnar defects on the critical current density (Jc) and electric (E) vs. current density (J) characteristics were investigated for a YBa2Cu3Oy thin film prepared using a pulsed-laser deposition method. The YBa2Cu3Oy thin film was irradiated with 200 MeV Au ions from a direction θ=8.8°off the c-axis. Two peaks in the angular dependence of Jc were observed at the angles of θ=8.8°and θ=90°. These angles correspond to the directions of the columnar defect and intrinsic pinning, respectively. The E-J characteristics at various magnetic field angles can be described by the percolation transition model. The value of pinning parameter m increases at the angles of θ=8.8°and θ=90°. This result indicates that the efficiency of flux pinning is enhanced because fluxoids are effectively pinned by the columnar defects and intrinsic pinning or stacking faults in these directions. - Masakazu Haruta; Eiji Kume; Shigeki SakaiSUPERCONDUCTOR SCIENCE & TECHNOLOGY IOP PUBLISHING LTD 22 (12) 125004 0953-2048 2009/12 [Refereed]
Intrinsic Josephson junctions were fabricated on Bi2Sr2CaCu2O8+delta thin films. The thin films were prepared by a pulsed-laser-deposition technique at the substrate temperature of 500. C. The deposited films were annealed at 884-890 degrees C for crystallization. Bi2Sr2CaCu2O8+delta thin films were successfully obtained with the stoichiometric composition. At the annealing temperature of 888 degrees C, a film consisting of large crystalline grains has been obtained; a flat terrace area reaches several tens of mu m and is larger than the typical mesa size for the intrinsic Josephson junction. The mesa structure patterned on the annealed film has exhibited clear multiple branches in the current-voltage characteristic peculiar to the intrinsic Josephson junctions. - T. Fujiyoshi; M. Haruta; T. Sueyoshi; K. Yonekura; M. Watanabe; M. Mukaida; R. Teranishi; K. Matsumoto; Y. Yoshida; A. Ichinose; S. Horii; S. Awaji; K. WatanabePHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 468 (15-20) 1635 - 1637 0921-4534 2008/09 [Refereed]
Flux pinning properties in ErBa2Cu3Oy and YBa2Cu3Oy thin films with BaZrO3 nano-rods prepared by PLD were measured to investigate the flux pinning mechanism. The enhancement of J(c) was confirmed by the measurement of the dependence of J(c) on magnetic field. The angular dependence of J(c) has a broad peak at B parallel to c-axis. This result indicates that the BaZrO3 nano-rods work as the c-axis-correlated pinning centers, The pinning parameter m was evaluated from the electric fields versus current density characteristics and the peak of m appears in the magnetic field dependence. The characteristic behavior of m is caused by the matching of the density of BaZrO3 nano-rods with that of fluxoids. It is found that the relative distribution width of the local critical current density for the ErBa2Cu3Oy film with BaZrO3 nano-rods is smaller than that of the YBa2Cu3Oy films with BaZrO3 nano-rods. (C) 2008 Elsevier B.V. All rights reserved. - T. Sueyoshi; M. Watanabe; M. Haruta; T. Fujiyoshi; K. Miyahara; T. Ikegami; K. Ebihara; R. MiyagawaPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 468 (15-20) 1266 - 1269 0921-4534 2008/09 [Refereed]
We present the experimental studies on structures and superconducting properties of two different types of YBa2Cu3O7-delta multilayered films with second phases prepared by pulsed laser deposition. As second phase materials, Y2O3 and ZnO were inserted into films, respectively. The nano-particles were observed on a YBa2Cu3O7-delta layer when several pulses for second phase materials target ablation were chosen for both Y2O3 and ZnO. The critical temperatures of almost multilayered films were slightly reduced as compared to that of the pure YBa2Cu3O7-delta film, while the superconductivity was destroyed in the case of excess doping of ZnO. For half-multilayered films which consist of a lower layer with multilayer and an upper one with mono-YBa2Cu3O7-delta the most improved critical current densities were observed in both cases of Y2O3 and ZnO inclusions. This result indicates that there is a hope of further enhancement of critical current density by choosing the optimum in variety of spatial distributions of nano-particles, in addition to optimizing the dope level. (C) 2008 Elsevier B.V. All rights reserved. - M. Haruta; T. Fujiyoshi; R. Kajita; K. Yonekura; T. Sueyoshi; T. Doi; H. Kitaguchi; S. Awaji; K. WatanabeJOURNAL OF APPLIED PHYSICS AMER INST PHYSICS 102 (7) 0021-8979 2007/10 [Refereed]
As-grown MgB2 thin films on Si substrates with high J(c) under magnetic fields were prepared by electron-beam evaporation. The value of J(c) has been enhanced by the deposition of MgB2 thin film in an O-2 atmosphere. The MgB2 thin film deposited in the O-2 atmosphere (O-2-doped film) has exhibited considerably higher J(c) in magnetic fields among MgB2 thin films reported before. It has been found that the high J(c) of the O-2-doped film is attributable to the flux pinning with grain boundaries strengthened by an introduction of MgO along grain boundaries. In a high magnetic field, a peculiar behavior of E-J characteristics where E-J curves vary in two stages was observed. This behavior also originates from the flux pinning with strengthened grain boundaries. - M. Hurata; T. Fujiyoshi; S. Kihara; T. Sueyoshi; K. Miyahara; Y. Harada; M. Yoshizawa; T. Takahashi; H. Iriuda; T. Oba; S. Awaji; K. Watanabe; R. MiyagawaSUPERCONDUCTOR SCIENCE & TECHNOLOGY IOP PUBLISHING LTD 20 (1) L1 - L4 0953-2048 2007/01 [Refereed]
As-grown MgB2 thin films were prepared by a MBE method under the conditions of low temperature, low deposition rate and high vacuum for applications in electric devices. The MgB2 thin films deposited on MgO and Ti buffered ZnO substrates have considerably higher J(c) under magnetic fields among MgB2 thin films reported before. The value of Jc for the MgB2 thin film deposited on Ti buffered ZnO has been 5.8 x 10(5) A cm(-2) at 10 K, 5 T in the magnetic field applied parallel to the c axis. In the angular dependence of J(c), the peak of J(c) attributable to c-axis-correlated pinning centres has been observed when the magnetic field was applied parallel to the c axis. - M. Haruta; T. Fujiyoshi; T. Sueyoshi; K. Dezaki; D. Ichigosaki; K. Miyahara; R. Miyagawa; M. Mukaida; K. Matsumoto; Y. Yoshida; A. Ichinose; S. HoriiSUPERCONDUCTOR SCIENCE & TECHNOLOGY IOP PUBLISHING LTD 19 (8) 803 - 807 0953-2048 2006/08 [Refereed]
ErBa2Cu3Oy (ErBCO) thin films with BaZrO3 (BZO) nanorods were prepared by a PLD method for an enhancement of the critical current density J(c). The values of J(c) for the ErBCO thin film containing 1.5 wt% BZO (Er15) in magnetic fields are higher than those for the ErBCO thin film containing 0.5 wt% BZO (Er05). The peaks of J(c) have been observed in the angular dependence of Jc in both the films when the magnetic field is applied parallel to the c-axis. It has been found that the peak is attributed to the flux pinning by BZO nanorods oriented parallel to the c-axis. The vortex glass - liquid transition temperature T-g and the pinning parameter m were derived by fitting observed electric transport properties to the theoretical expression based on the percolation transition model. The value of Tg of Er15 is higher than that of Er05. This result indicates that the vortex glass phase extends to a higher temperature region on increasing the fraction of BZO. The peak of m has been found in the magnetic field dependence. This fact is probably due to matching the density of BZO nanorods with that of fluxoids, which was confirmed by TEM observations. - M Haruta; T Fujiyoshi; T Sueyoshi; K Miyahara; T Doi; H Kitaguchi; S Awaji; K WatanabeSUPERCONDUCTOR SCIENCE & TECHNOLOGY IOP PUBLISHING LTD 18 (11) 1460 - 1463 0953-2048 2005/11 [Refereed]
Critical current densities J(c) of MgB2 thin films have been measured; these were prepared by an electron beam evaporation method without any post-annealing. In order to improve the characteristics of J(c) in high magnetic fields, a MgB2 thin film was deposited in an O-2 atmosphere. The values of J(c) of the O-2-doped film have exceeded those of the non-doped film in magnetic fields applied perpendicular and also parallel to the c-axis. The peak of J(c) caused by the c-axis correlated pinning centres has been observed in the angular dependence of J(c). The upper critical field B-c2 and the vortex glass-liquid transition field B-g have been estimated from temperature dependences of resistivity curves in both directions of the magnetic fields perpendicular and parallel to the c-axis. It is found that B-c2 and B-g are increased by the introduction of O-2 in both the directions of the applied field. This fact indicates that effective pinning centres have been introduced by the deposition of the MgB2 thin film in an O-2 atmosphere. - M Haruta; T Fujiyoshi; T Sueyoshi; K Miyahara; T Doi; H KitaguchiPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 426 (I) 174 - 178 0921-4534 2005/10 [Refereed]
The E-J characteristics of MgB2 thin film prepared by the electron beam evaporation method were investigated. The film has a fairly higher T-c of 35 K and J(c) of 0.48 MA/cm(2) at 20 K and 1 T among as-grown MgB2 films prepared by various methods. The E-J characteristics at various temperatures and magnetic fields can be described by the percolation transition model. The pinning parameters and the distribution of pinning forces of the MgB2 thin film were estimated. It was found that the MgB2 thin film has the uniform distribution of pinning forces by grain boundaries. (c) 2005 Elsevier B.V. All rights reserved. - T Fujiyoshi; M Haruta; K YamafujiPHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 424 (1-2) 29 - 39 0921-4534 2005/08 [Refereed]
As one of the bases of the theoretical estimation of the electromagnetic properties for practical purposes in wires, conductors and coils using high-T-c cuprate superconductors, the expression for the time decay of the magnetization in a slab sample of the high-T-c cuprate superconductor is derived by solving the Maxwell equations with the aid of the expression for the electric field, E, vs. current density, J, characteristic that was derived recently by the authors. The obtained expression, which is noticeably different from the one for the low-T-c metallic superconductors, is compared quantitatively with the numerical calculations, and the agreement between them seems to be satisfactory. (c) 2005 Elsevier B.V. All rights reserved. - Masakazu HARUTA; Takanori FUJIYOSHI; Tetsuro SUEYOSHI; Kuniyuki MIYAHARA; Toshiya DOI; Hitoshi KITAGUCHI; Satoshi AWAJI; Kazuo WATANABECryogenic Egineering Cryogenic Association of Japan 40 (11) 473 - 478 2005 [Refereed]
- M Haruta; T Fujiyoshi; T Sueyoshi; K Miyahara; T Ikegami; K Ebihara; R Miyagawa; N Ishikawa; S Awaji; K WatanabePHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS ELSEVIER SCIENCE BV 412 (SPEC. ISS.) 511 - 514 0921-4534 2004/10 [Refereed]
The influence of columnar defects introduced by the heavy-ion irradiation on the pinning parameters in YBa2Cu3O7-delta thin films was investigated. The pinning parameters n, J(cm) and DeltaJ(c) were derived by fitting the experimentally obtained E-J characteristics to the theoretical curves calculated from the percolation transition model. The values of n and J(cm) have been increased and the value of DeltaJ(c), has been decreased by the introduction of columnar defects. (C) 2004 Elsevier B.V. All rights reserved.
MISC
- 春田 正和; 稲葉 稔 車載テクノロジー = Automotive technology 7- (6) 23 -26 2020/03
- 春田正和; 土井貴之; 稲葉稔; 富田明; 竹中利夫 月刊Material Stage 17- (5) 34‐38 -38 2017/08
- 稲葉稔; 春田正和; 橋之口道宏; 土井貴之 ケミカルエンジニヤリング 61- (5) 314‐318 -318 2016/05
- 春田正和; 白木将; 一杉太郎 自動車技術 69- (9) 116 -117 2015/09
- 春田正和; 白木将; 一杉太郎 エネルギーデバイス 2- (6) 42 -45 2015/08
- 堀井滋; 山木桃子; 奥平翔太; 春田正和 化学工業 64- (3) 194 -201 2013/03
- 末吉哲郎; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二 超伝導システム科学研究センター報告 5- 59 -65 2008/03
- 藤吉孝則; 春田正和; 梶田龍; 米倉健志; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2006- 59 -61 2007/06
- 春田正和; 藤吉孝則; 梶田龍; 米倉健志; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄 FSST NEWS (Form Supercond Sci Technol News) (113) 4 -6 2007/04
- FUJIYOSHI T.; HARUTA M.; SUEYOSHI T.; DEZAKI K.; ICHIGOSAKI D.; MIURA M.; MATSUMOTO K.; YOSHIDA Y.; ICHINOSE A.; HORII S.; AWAJI S.; WATANABE K. 低温工学・超電導学会講演概要集 = Meetings of Cryogenics and Superconductivity 75- 175 2006/11
- 藤吉孝則; 春田正和; 木原眞太郎; 末吉哲郎; 吉澤正人; 入宇田啓樹; 高橋輝一; 原田善之; 宮川隆二; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2005- 47 -50 2006/06
- 藤吉孝則; 春田正和; 末吉哲郎; 吉田隆; 三浦正志; 松本要; 向田昌志; 宮川隆二; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2005- 18 -21 2006/06
- FUJIYOSHI T.; HARUTA M.; SUEYOSHI T.; DEZAKI K.; ICHIGOSAKI D.; MIYAGAWA R.; MIURA M.; MATSUMOTO K.; YOSHIDA Y.; ICHINOSE A.; HORII S. 低温工学・超電導学会講演概要集 = Meetings of Cryogenics and Superconductivity 74- 17 2006/05
- 末吉哲郎; 春田正和; 藤吉孝則; 宮原邦幸; 池上知知顕; えび原健治; 宮川隆二; 知見康弘; 石川法人; 淡路智; 渡辺和雄 超伝導システム科学研究センター報告 3- 108 -113 2006/03
- 春田 正和; 藤吉 孝則; 末吉 哲郎 超伝導システム科学研究センター報告 3- 102 -107 2006/03
- 末吉哲郎; 高橋献一; 佐藤直哉; 渡邊昌孝; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二 熊大極低温 17- (17) 39 -43 2006
- 末吉哲郎; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二; 知見康弘; 石川法人; 向田昌志; 堀井滋; 一瀬中; 吉田隆; 松本要 電気学会基礎・材料・共通部門大会(CD-ROM) 2006- 2006
- 末吉 哲郎; 春田 正和; 藤吉 孝則; 宮原 邦幸; 池上 知顯; 蛯原 健治; 宮川 隆二; 知見 康弘; 石川 法人; 向田 昌志 平成18年度第59回電気関係学会九州支部連合大会講演論文集 (電気関係学会九州支部) 04-1A-08-04-1A-08 2006
- 藤吉孝則; 春田正和; 末吉哲郎; 宮原邦幸; 土井俊哉; 北口仁; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2004- 46 -49 2005/06
- 春田正和; 藤吉孝則; 末吉哲郎; 宮原邦幸; 土井俊哉; 北口仁 超伝導システム科学研究センター報告 2- 65 -71 2005/03
- 藤吉孝則; 末吉哲郎; 春田正和; 宮原邦幸; 池上知顕; 宮川陸二; 石川法人; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2003- 27 -30 2004/06
- 藤吉孝則; 春田正和; 末吉哲郎; 宮原邦幸; 池上知顕; 宮川隆二; 石川法人; 淡路智; 渡辺和雄 超伝導システム科学研究センター報告 1- 49 -54 2004/03
- 春田 正和; 藤吉 孝則; 末吉 哲郎; 土井 俊哉; 白樂 善則 熊大極低温 15- (15) 20 -23 2004
- 藤吉孝則; 末吉哲郎; 米村洋幸; 春田正和; 宮原邦幸; 宮川隆二; 石川法人; 淡路智; 渡辺和雄 東北大学金属材料研究所強磁場超伝導材料研究センター年次報告 2002- 19 -22 2003/06
- 春田正和; 蔵満健二; 藤吉孝則 超伝導科学研究センター報告 10- 97 -103 2003/03
Books and other publications
- EV用電池の安全性向上、高容量化と劣化抑制技術:表面被膜制御による鱗片状シリコン負極のサイクル寿命特性向上春田正和; 土井貴之; 稲葉稔 (Contributorpp. 256-261)技術情報協会 2023/11
- “Silicon LeafPowder® anode”, in: Kiyoshi Kanamura (Eds.), Next Generation Batteries –Realization of High Energy Density Rechargeable BatteriesMasakazu Haruta, Takayuki Doi, Minoru Inaba (Contributorpp. 323-332)Springer 2021/03
- 春田正和; 稲葉稔; (監)境哲男 (Contributor3-10)シーエムシー出版 2019/11 9784781314853 vii, 251p
- 春田正和、土井貴之、稲葉稔;(編)技術情報協会 (Contributor155-161)技術情報協会 2019/11 9784861047701 522p
- 鱗片状シリコン負極のサイクル特性と劣化要因春田正和; 土井貴之; 稲葉稔; 富田明; 竹中利夫 (Joint workpp.34-38)MATERIAL STAGE, Vol.17 (招待、解説記事) 2017/05
- 次世代リチウムイオン電池の実現に向けた取り組み稲葉稔; 春田正和; 橋之口道宏; 土井貴之 (Joint workpp.314-318)ケミカルエンジニヤリング, Vol.61 (招待、解説記事) 2016/05
- 極めて低い電解質/電極界面抵抗を有する全固体リチウム電池の作製―液体電解質系リチウムイオン電池を凌駕する高速充放電に向けて―春田正和; 白木将; 一杉太郎 (Joint workpp.116-117)自動車技術, Vol.69 (招待、解説記事) 2015/09
- 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性春田正和; 白木将; 一杉太郎 (Joint workpp.42-45)エネルギーデバイス Vol.2 (招待、解説記事) 2015/06
- 応用物理学的アプローチを活用した全固体Li電池研究:電極/電解質界面抵抗の低減に向けた界面研究白木将; 河底秀幸; 一杉太郎; 春田正和 (Joint workpp.212-217)応用物理学会 有機分子・バイオエレクトロニクス分科会誌, Vol.26 (招待、解説記事) 2015/04
- イオン伝導経路を規定した電解質・電極界面尾イオン伝導性定量評価白木将; 春田正和; 一杉太郎 (Contributorpp.280-284)LiBの高容量・高耐久化のための電極―電解液(質)の界面制御技術と解析・評価方法 (技術情報協会出版) (依頼執筆) 2015/02
- 磁気科学プロセスのための層状機能性物質の磁気異方性制御堀井滋; 山木桃子; 奥平翔太; 春田正和 (Joint workpp.194-201)化学工業, Vol.64 (招待、解説記事) 2013/03
- 酸素中成膜によりピンニングセンターを導入したSi基板MgB2薄膜の磁束ピンニング特性春田正和; 藤吉孝則; 梶田龍; 米倉健志; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄 (Joint workpp.4-6)未踏科学技術協会超伝導科学技術研究会 FSST NEWS, Vol.113 (招待、解説記事) 2007
Lectures, oral presentations, etc.
- Structure of Vanadate Glasses developed for Cathode Active Material of Lithium-ion Battery, and Evaluation of Charge and Discharge Properties松迫駿介; 森元悠眞; 松尾紗絵子; 今村涼太; 櫻木貴久; 春田正和; 西田哲明; 岡伸人応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2021
- Preparation of All-Solid-State Lithium Batteries with SiOx Negative Electrodes春田正和; 松田章正; 福山智也; 岡伸人; 土井貴之; 稲葉稔応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2021
- Charge/discharge Characteristics and Electrode Swelling of Siloxene/CNT composite electrodes稲葉稔; 森井雄大; 廣岡聖也; 中村由芽; 土井貴之; 春田正和電池討論会PDF要旨集(CD-ROM) 2021
- Li Deposition on Rapid Battery Heating Using Alternative Current from Sub-Zero Temperatures高橋明沙; 春田正和; 土井貴之; 稲葉稔; 山上雄史; 梅本久; 吉田周平電池討論会PDF要旨集(CD-ROM) 2021
- Charge-discharge capacity of Li-ion battery with a cathode active material of vanadate glass松迫駿介; 森本悠眞; 松尾紗絵子; 今村涼太; 櫻木貴久; 春田正和; 西田哲明; 岡伸人電気化学秋季大会講演要旨集(CD-ROM) 2021
- Improvement of cycle performance of Si negative electrodes by fluorinated polymer coating for lithium-ion batteries春田正和; 小長啓人; 富田明; 竹中利夫; 土井貴之; 稲葉稔応用物理学会春季学術講演会講演予稿集(CD-ROM) 2020
- SiOx薄膜の酸素量に依存した充放電特性と形態変化 [Not invited]春田正和; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2019/03
- リチウムイオン二次電池負極用チタンニオブ複合系酸化物の合成および充放電特性評価 [Not invited]杉本賢吾; 春田正和; 土井貴之; 稲葉稔日本化学会春季年会講演予稿集(CD-ROM) 2019/03
- リチウムイオン電池用SiOx負極の酸素量に依存した形態変化 [Not invited]春田正和; 土井貴之; 稲葉稔応用物理学会春季学術講演会講演予稿集(CD-ROM) 2019/02
- In-situ AFM Observation of Morphological Changes of Si Film Electrode with FEC-derived SEI in LiTFSI/G4 Electrolyte Solution小倉奈那子; 春田正和; 土井貴之; 稲葉稔電池討論会PDF要旨集(CD-ROM) 2019
- The interface analysis between a LiNi0.5Co0.2Mn0.3O2 positive electrode and fluorinated phosphate-based electrolyte solution佐藤大進; 春田正和; 土井貴之; 稲葉稔電池討論会PDF要旨集(CD-ROM) 2019
- Effects of PVdF coating on Li deposition/dissolution reactions田邉凌祐; 春田正和; 土井貴之; 稲葉稔電池討論会PDF要旨集(CD-ROM) 2019
- Charge and discharge properties of Ti2Nb2O9 as a high potential negative electrode for lithium ion batteries池田皓平; 春田正和; 土井貴之; 稲葉稔電池討論会PDF要旨集(CD-ROM) 2019
- Improvement of charge and discharge characteristics of amorphous silicon-flake-powder negative electrode by formation of fluorinated polymer artificial SEI小長啓人; 春田正和; 富田明; 竹中利夫; 土井貴之; 稲葉稔電池討論会PDF要旨集(CD-ROM) 2019
- Li-S batteries using Li2S cathode and sparingly solvating electrolytes上野和英; 清田大勝; 松前義治; 春田正和; 獨古薫; 稲葉稔; 渡邉正義電池討論会PDF要旨集(CD-ROM) 2019
- In‐situ AFM analysis of SEI formation process in LiFSI, LiTFSI/G4 electrolyes on Si thin film electrodes [Not invited]小倉奈那子; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2018/11
- 鱗片状Si負極のオペランドSEM観察―イオン液体電解液が負極挙動に与える影響― [Not invited]上平峻己; 津田哲哉; 今西哲士; 春田正和; 土井貴之; 稲葉稔; 桑畑進溶融塩化学討論会要旨集 2018/11
- 炭素被覆Si負極における被膜形成過程のin‐situ AFM観察 [Not invited]春田正和; 木島友規; 小倉奈那子; 土井貴之; 稲葉稔応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2018/09
- リチウムイオン電池用Si負極における被膜形成過程のin‐situ AFM観察 [Not invited]春田正和; 木島友規; 日置龍矢; 小倉奈那子; 土井貴之; 稲葉稔応用物理学会春季学術講演会講演予稿集(CD-ROM) 2018/03
- 鱗片状Si負極のオペランドSEM観察-イオン液体電解液が負極挙動に与える影響-上平峻己; 津田哲哉; 今西哲士; 春田正和; 土井貴之; 稲葉稔; 桑畑進溶融塩化学討論会要旨集 2018
- Improvement of cyclability and suppression of electrode swelling in Si flake powder negative electrode [Not invited]春田正和; 日置龍矢; 木島友規; 富田明; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2017/11
- 関口奈都美; 岩田学; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2017/11
- In situ AFM analysis of SEI formation process on surface-coated Si thin-film electrodes [Not invited]木島友規; 日置龍矢; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2017/11
- シリコン負極における人工被膜形成と充放電特性への影響 [Not invited]春田正和; 日置龍矢; 木島友規; 富田明; 竹中利夫; 土井貴之; 稲葉稔電気化学秋季大会講演要旨集(CD‐ROM) 2017/08
- リチウム金属負極の被膜形成が炭酸エステル系濃厚電解液中のデンドライト抑制に与える効果 [Not invited]関口奈都美; 春田正和; 土井貴之; 稲葉稔電気化学秋季大会講演要旨集(CD‐ROM) 2017/08
- リチウムイオン電池用シリコン負極の表面被覆による充放電特性の向上 [Not invited]日置龍矢; 春田正和; 木島友規; 土井貴之; 稲葉稔応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2017/08
- 濃厚電解液を用いたリチウム金属負極のデンドライト抑制 [Not invited]関口奈都美; 春田正和; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2017/03
- 溶媒和イオン液体中におけるシリコン負極の充放電特性への表面被膜の影響 [Not invited]春田正和; 森安貴士; 日置龍矢; 富田明; 竹中利夫; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2017/03
- リチウムイオン電池用シリコン負極の高性能化を目指した表面被膜形成 [Not invited]春田正和; 日置龍矢; 木島友規; 森安貴士; 土井貴之; 稲葉稔応用物理学会春季学術講演会講演予稿集(CD-ROM) 2017/03
- カーボン被覆によるリチウムイオン電池用シリコン負極における充放電特性の向上 [Not invited]日置龍矢; 春田正和; 木島友規; 森安貴士; 土井貴之; 稲葉稔応用物理学会春季学術講演会講演予稿集(CD-ROM) 2017/03
- リチウムイオン電池用Ti‐Nb系酸化物負極の充放電特性評価 [Not invited]松本正憲; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2016/11
- 鱗片状Si負極の表面被膜が溶媒和イオン液体中の充放電サイクル特性に与える影響 [Not invited]森安貴士; 日置龍矢; 吉田周平; 春田正和; 富田明; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2016/11
- 鱗片状シリコン負極の形態とサイクル特性の関係 [Not invited]春田正和; 森安貴士; 日置龍矢; 富田明; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2016/11
- 鱗片状Si負極の溶媒和イオン液体におけるサイクル特性と表面形態変化 [Not invited]春田正和; 森安貴士; 日置龍矢; 益尾雄太; 富田明; 竹中利夫; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2016/03
- TiO2(B)の新規固相合成法の開発とその充放電特性 [Not invited]松本正憲; 春田正和; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2016/03
- 鱗片状シリコン粉末を用いた次世代リチウムイオン電池用高容量負極の開発 [Not invited]春田正和; 森安貴士; 日置龍矢; 土井貴之; 稲葉稔同志社大学ハリス理化学研究所研究発表会・学内研究センター合同シンポジウム講演予稿集 2016
- リチウム酸化物薄膜電極の作製とナノ電気化学セル顕微鏡による電池特性評価 [Not invited]熊谷明哉; 高橋康史; 白木将; 春田正和; 猪又宏貴; 渡邊徹弥; 井田大貴; 珠玖仁; 一杉太郎; 末永智一; 末永智一電気化学会東北支部セミコンファレンス講演論文集 2015/12
- 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性 [Not invited]白木将; 春田正和; 鈴木竜; 清水亮太; 河底秀幸; 一杉太郎電池討論会講演要旨集 2015/11
- In Situ AFMによるEC系電解液中のシリコン薄膜負極の表面被膜形成反応の解析 [Not invited]WU ZhengJie; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2015/11
- 溶媒和イオン液体中における鱗片状Si負極の表面被膜とサイクル特性の関係 [Not invited]森安貴士; 益尾雄大; 春田正和; 富田明; 榊原千裕; 亀井明果; 廣田真人; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2015/11
- 電気化学的in situ SEM観察法による鱗片状シリコン負極充放電挙動の観察 [Not invited]佐野輝樹; 津田哲哉; CHEN Chih‐Yao; 春田正和; 土井貴之; 稲葉稔; 桑畑進電池討論会講演要旨集 2015/11
- 鱗片状シリコン負極におけるサイクル特性への添加剤効果とインピーダンス解析 [Not invited]春田正和; 森安貴士; 益尾雄大; 富田明; 榊原千裕; 亀井明果; 廣田真人; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2015/11
- グライム電解液中での鱗片状シリコン負極の充放電特性 [Not invited]稲葉稔; 春田正和; 土井貴之日本化学会講演予稿集 2015/03
- ナノ電気化学セル顕微鏡:有機ゲルピペットの電池材料評価への応用 [Not invited]熊谷明哉; 高橋康史; 猪又宏貴; 白木将; 山本邦子; 春田正和; 伊野浩介; 珠玖仁; 一杉太郎; 末永智一電気化学会大会講演要旨集(CD-ROM) 2015/03
- グライム系電解液における鱗片状Si負極のサイクル特性とインピーダンス評価 [Not invited]春田正和; 益尾雄大; 森安貴士; 富田明; 榊原千裕; 亀井明果; 廣田真人; 竹中利夫; 土井貴之; 稲葉稔電気化学会大会講演要旨集(CD-ROM) 2015/03
- ナノ電気化学セル顕微鏡:有機ゲルピペットを用いた局所電気化学測定条件の検討 [Not invited]熊谷明哉; 高橋康史; 猪又宏貴; 白木将; 山本邦子; 春田正和; 伊野浩介; 珠玖仁; 一杉太郎; 末永智一応用物理学会春季学術講演会講演予稿集(CD-ROM) 2015/02
- 全固体リチウム電池の酸化物電解質/電極界面におけるイオン伝導特性 [Not invited]白木将; 春田正和; 鈴木竜; 高木由貴; 清水亮太; 一杉太郎応用物理学会春季学術講演会講演予稿集(CD-ROM) 2015/02
- ラムスデライト型酸化チタンの粒径制御と充放電特性評価 [Not invited]金澤亮太郎; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2014/11
- Li‐Naphthalene錯体溶液を用いた鱗片状シリコン負極へのプレドープ法の検討 [Not invited]益尾雄大; 吉田周平; 柴田大輔; 春田正和; 土井貴之; 稲葉稔電池討論会講演要旨集 2014/11
- Glyme‐Li錯体電解液を用いた鱗片状シリコン負極のサイクル特性 [Not invited]春田正和; 益尾雄大; 富田明; 榊原千裕; 亀井明菓; 廣田真人; 竹中利夫; 土井貴之; 稲葉稔電池討論会講演要旨集 2014/11
- LiFePO4正極薄膜材料表面のイオン電流応答における結晶粒・粒界の影響 [Not invited]熊谷明哉; 高橋康史; 猪又宏貴; 白木将; 山本邦子; 春田正和; 伊野浩介; 珠玖仁; 一杉太郎; 末永智一電池討論会講演要旨集 2014/11
- 全固体リチウムイオン電池の酸化物電解質/電極界面におけるイオン伝導特性 [Not invited]白木将; 春田正和; 鈴木竜; 高木由貴; 清水亮太; 一杉太郎固体イオニクス討論会講演要旨集 2014/11
- LiCoO2エピタキシャル薄膜の配向制御と電気化学評価 [Not invited]白木将; 高木由貴; 春田正和; 清水亮太; 鈴木竜; 佐藤幸生; 幾原雄一; 一杉太郎電気化学秋季大会講演要旨集 2014/09
- 全固体リチウムイオン電池の酸化物電解質/電極界面におけるイオン伝導特性 [Not invited]春田正和; 鈴木竜; 高木由貴; 清水亮太; 白木将; 一杉太郎電気化学秋季大会講演要旨集 2014/09
- ナノロッドを導入したPLD‐REBa2Cu3Oy薄膜における臨界電流特性のナノロッド材料・RE種に対する影響 [Not invited]堀井滋; 一瀬中; 春田正和; 土井俊哉応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2014/09
- 金属単結晶基板上に成膜したLiCoO2エピタキシャル薄膜の配向制御 [Not invited]白木将; 高木由貴; 春田正和; 清水亮太; 鈴木竜; 佐藤幸生; 幾原雄一; 一杉太郎応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2014/09
- 界面イオン伝導顕微鏡による正極薄膜材料表面におけるLiイオン挿入・脱離機構の可視化 [Not invited]熊谷明哉; 高橋康史; 猪又宏貴; 白木将; 山本邦子; 春田正和; 伊野浩介; 珠玖仁; 一杉太郎; 末永智一応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2014/09
- 界面イオン伝導顕微鏡による多結晶電極表面の結晶構造とLi挿入脱離の相関性の検討 [Not invited]熊谷明哉; 高橋康史; 猪又宏貴; 白木将; 山本邦子; 春田正和; 伊野浩介; 珠玖仁; 一杉太郎; 末永智一電気化学会大会講演要旨集 2014/03
- 清浄な電解質/電極界面を有する薄膜型リチウムイオン電池の界面抵抗評価 [Not invited]春田正和; 鈴木竜; 高木由貴; 清水亮太; 白木将; 一杉太郎電気化学会大会講演要旨集 2014/03
- 清浄な電解質/電極界面を有する薄膜型全固体電池におけるLiイオン伝導特性 [Not invited]春田正和; 鈴木竜; 高木由貴; 清水亮太; 白木将; 一杉太郎応用物理学会春季学術講演会講演予稿集(CD-ROM) 2014/03
- 全真空プロセスにより作製した薄膜型全固体リチウムイオン電池の電池特性 [Not invited]春田正和; 鈴木竜; 高木由貴; 清水亮太; 白木将; 一杉太郎固体イオニクス討論会講演要旨集 2013/11
- 全真空プロセスによる薄膜型全固体Liイオン電池の作製と電池特性評価 [Not invited]春田正和; 鈴木竜; 熊谷明哉; 高木由貴; 清水亮太; 白木将; 一杉太郎電気化学秋季大会講演要旨集 2013/09
- 全真空プロセスによる全固体薄膜Liイオン電池の作製 [Not invited]春田正和; 鈴木竜; 熊谷明哉; 高木由貴; 清水亮太; 白木将; 一杉太郎応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2013/08
- 金属単結晶基板上に成膜したLiCoO2エピタキシャル薄膜の構造評価 [Not invited]白木将; 高木由貴; 熊谷明哉; 清水亮太; 鈴木竜; 春田正和; 大澤健男; 佐藤幸生; 幾原雄一; 一杉太郎応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2013/08
- ナノロッド導入REBa2Cu3Oy薄膜の組織制御と臨界電流特性 [Not invited]春田正和; 藤田夏斗; 小椋裕太; 一瀬中; 前田敏彦; 堀井滋応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2013/08
- 藤田夏斗; 一瀬中; 春田正和; 前田敏彦; 土井俊哉; 堀井滋応用物理学会秋季学術講演会講演予稿集(CD-ROM) 2013/08
- 90K級Y124系超伝導体の作製と三軸磁場配向 [Not invited]堀井滋; 西川尚志; 山木桃子; 春田正和; 下山淳一; 岸尾光二低温工学・超電導学会講演概要集 2013/05
- 異なる成膜温度よって変化するナノロッド形態と超電導特性 [Not invited]一瀬中; 鶴田彰宏; 三浦峻; 吉田隆; 春田正和; 藤田夏斗; 小椋裕太; 前田敏彦; 堀井滋低温工学・超電導学会講演概要集 2013/05
- YBa2Cu3Oyの結晶磁気異方性に与える遷移金属イオンドープの効果(II) [Not invited]堀井滋; 右川貴子; 新田紀子; 春田正和応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- ナノロッド導入REBa2Cu3Oy薄膜における成膜条件に依存した局所的臨界電流密度分布 [Not invited]春田正和; 一瀬中; 藤田夏斗; 佐浦啓介; 小椋裕太; 前田敏彦; 堀井滋応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- 成膜温度の違いによるナノロッド形態の変化 [Not invited]一瀬中; 春田正和; 藤田夏斗; 小椋裕太; 前田敏彦; 堀井滋; 鶴田彰宏; 吉田隆応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- 強磁場下スリップキャスト法で作製した三軸配向性ErBa2Cu4O8セラミックスにおける分散媒粘性と配向度の関係 [Not invited]山木桃子; 春田正和; 下山淳一; 安田秀幸; 堀井滋応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- 実用銅酸化物系高温超伝導物質の結晶磁気異方性と磁化軸における希土類イオンの役割 [Not invited]堀井滋; 山木桃子; 永井諒太郎; 奥平翔太; 春田正和; 下山淳一応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- 異なった組成のナノロッドを含むYBa2Cu3Oy薄膜の臨界電流特性 [Not invited]春田正和; 佐浦啓介; 藤田夏斗; 小椋裕太; 一瀬中; 前田敏彦; 堀井滋応用物理学会春季学術講演会講演予稿集(CD-ROM) 2013/03
- (Pb,M)Sr2(Y,Ca)Cu2Oz(M:Fe,Co,Ni,Cu,Zn)の単一相組成と電気抵抗率の温度依存性 [Not invited]前田敏彦; 田代大陸; 春田正和; 堀井滋セラミックス基礎科学討論会講演要旨集 2013/01
- Fabrication of tri-axially oriented ErBa2Cu4O8 superconductor ceramics by slip casting in modulated rorating magnetic fields [Not invited]山木桃子; 春田正和; 安田秀幸; 下山淳一; 堀井滋電気学会金属・セラミックス研究会資料 2012/12
- 間欠回転磁場下におけるYBa2Cu3Oyの結晶配向と遷移金属イオンドープの効果 [Not invited]右川貴子; 春田正和; 堀井滋; 下山淳一日本磁気科学会年会プログラム・要旨集 2012/11
- 山木桃子; 春田正和; 堀井滋; 安田秀幸; 下山淳一日本磁気科学会年会プログラム・要旨集 2012/11
- ミスフィット層状コバルト酸化物の三軸磁場配向における希土類イオンの磁気的役割 [Not invited]岡本夏樹; 春田正和; 堀井滋日本磁気科学会年会プログラム・要旨集 2012/11
- 間欠回転磁場下で配向させたBi2Sr2(Ca1-xREx)Cu2Oyの配向度と希土類ドープ量の関係 [Not invited]永井諒太郎; 堀井滋; 春田正和; 下山淳一日本磁気科学会年会プログラム・要旨集 2012/11
- 磁気科学プロセスのための鉄系層状物質の磁化軸・磁気異方性制御指針 [Not invited]青木恵祐; 春田正和; 堀井滋; 荻野拓; 下山淳一日本磁気科学会年会プログラム・要旨集 2012/11
- Ba‐Nb‐O添加RE123薄膜における成膜温度に依存したナノロッド形態の変化と局所的臨界電流密度分布の関係 [Not invited]春田正和; 佐浦啓介; 藤田夏斗; 小椋裕太; 前田敏彦; 堀井滋; 一瀬中低温工学・超電導学会講演概要集 2012/11
- 鉄系層状物質の磁気異方性 [Not invited]青木恵祐; 春田正和; 荻野拓; 下山淳一; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 藤田夏斗; 春田正和; 一瀬中; 前田敏彦; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 強磁場下スリップキャスト法による三軸配向性ErBa2Cu4O8高温超伝導セラミックスの作製 [Not invited]山木桃子; 春田正和; 下山淳一; 安田秀幸; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 三軸磁場配向法を利用した希土類系高温超伝導体の結晶磁気異方性定量化 [Not invited]堀井滋; 山木桃子; 春田正和; 下山淳一応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 製造温度に依存しない臨界電流特性を有するナノロッド導入RE123薄膜の作製と微細組織評価 [Not invited]春田正和; 一瀬中; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 希土類イオンをドープしたビスマス系高温超伝導体の三軸磁場配向 [Not invited]永井諒太郎; 春田正和; 下山淳一; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- YBa2Cu3Oyの結晶磁気異方性に与える遷移金属イオンドープの効果 [Not invited]右川貴子; 春田正和; 下山淳一; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- (RE1-xRE’x)2Ba4Cu7O15-δの三軸磁場配向と結晶磁気異方性 [Not invited]奥平翔太; 山木桃子; 春田正和; 下山淳一; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- 希土類添加によるビスマス系層状コバルト酸化物の三軸磁場配向と磁化軸制御 [Not invited]岡本夏樹; 春田正和; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- Nd:YAG‐PLD法で作製したナノロッド導入ErBa2Cu3Oy薄膜の臨界電流特性 [Not invited]小椋裕太; 春田正和; 一瀬中; 堀井滋; 前田敏彦応用物理学会学術講演会講演予稿集(CD-ROM) 2012/08
- Bi系高温超伝導体の三軸磁場配向 [Not invited]永井諒太郎; 堀井滋; 春田正和; 下山淳一応用物理学関係連合講演会講演予稿集(CD-ROM) 2012/02
- 間欠回転磁場における希土類系高温超伝導体ErBa2Cu4O8の配向度と回転速度の関係 [Not invited]山木桃子; 春田正和; 下山淳一; 堀井滋応用物理学関係連合講演会講演予稿集(CD-ROM) 2012/02
- FeCh(Ch=Se,Te)の磁気異方性決定因子 [Not invited]青木恵祐; 春田正和; 下山淳一; 堀井滋応用物理学関係連合講演会講演予稿集(CD-ROM) 2012/02
- 製造温度に依存しない臨界電流特性を有するナノロッド導入REBCO薄膜の作製 [Not invited]春田正和; 藤田夏斗; 小椋裕太; 中田貴大; 前田敏彦; 堀井滋応用物理学関係連合講演会講演予稿集(CD-ROM) 2012/02
- 希土類系高温超伝導体における希土類イオンの三軸磁気異方性 [Not invited]奥平翔太; 堀井滋; 下元直也; 山木桃子; 春田正和; 下山淳一応用物理学関係連合講演会講演予稿集(CD-ROM) 2012/02
- (Pb,Co)Sr2(Y,Ca)Cu2Ozの組成と電気特性 [Not invited]前田敏彦; 田代大陸; 春田正和; 堀井滋セラミックス基礎科学討論会講演要旨集 2012/01
- REBa2Cu3Oy薄膜組成によるナノロッドの形態制御 [Not invited]春田正和; 藤田夏斗; 小椋裕太; 中田貴大; 前田敏彦; 堀井滋低温工学・超電導学会講演概要集 2011/11
- Nd:YAG‐PLD法によるREBa2Cu3Oy薄膜の作製と臨界電流特性 [Not invited]春田正和; 藤田夏斗; 小椋裕太; 北野弘典; 前田敏彦; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- Nd:YAG‐PLD法を用いたナノロッド導入YBa2Cu3Oy薄膜における磁束ピンニング特性の成膜温度依存性 [Not invited]春田正和; 藤田夏斗; 前田敏彦; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- ビスマス系層状コバルト酸化物の三軸磁場配向に与える希土類イオンの効果 [Not invited]堀井滋; 岡本夏樹; 青木恵祐; 春田正和; 中尾健吾; 荻野拓; 山本明保; 岸尾光二; 下山淳一応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- 層状鉄ニクタイド物質の磁気異方性決定因子 [Not invited]堀井滋; 青木恵祐; 春田正和; 荻野拓; 下山淳一応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- (Pb,M)Sr2(Y,Ca)Cu2Oz(M:Fe,Co,Ni,Zn)の化学組成と特性 [Not invited]前田敏彦; 田代大陸; 阿部雷太; 春田正和; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- 希土類系高温超伝導体REBa2Cu4O8における磁化軸と磁気異方性のRE依存性 [Not invited]山木桃子; 堀井滋; 春田正和; 下山淳一応用物理学会学術講演会講演予稿集(CD-ROM) 2011/08
- (Pb,M)Sr2(Y,Ca)Cu2Oz(M:Fe,Co,Ni)の合成と評価 [Not invited]前田敏彦; 武市将平; 阿部雷太; 田代大陸; 春田正和; 堀井滋低温工学・超電導学会講演概要集 2011/05
- Ba‐Nb‐Oナノロッドを導入したYBa2Cu3Oy薄膜における酸素アニールと臨界電流特性の関係 [Not invited]春田正和; 前田敏彦; 堀井滋; MELE Paolo; 松本要; 下山淳一低温工学・超電導学会講演概要集 2011/05
- 双晶を含まないREBa2Cu4O8の合成と三軸磁場配向 [Not invited]山木桃子; 堀井滋; 春田正和; 前田敏彦; 下山淳一応用物理学関係連合講演会講演予稿集(CD-ROM) 2011/03
- ナノロッドを導入したREBa2Cu3Oy薄膜における臨界電流密度に与える酸素アニール効果 [Not invited]春田正和; MELE P; 松本要; 前田敏彦; 下山淳一; 堀井滋応用物理学関係連合講演会講演予稿集(CD-ROM) 2011/03
- (Y1-xErx)2Ba4Cu7O15-δの三軸磁場配向とErイオンの三軸磁気異方性 [Not invited]奥平翔太; 堀井滋; 山木桃子; 春田正和; 前田敏彦; 下山淳一応用物理学関係連合講演会講演予稿集(CD-ROM) 2011/03
- 層状酸硫化物REOCuS(RE=La,Ce,Pr,Nd,Sm)の磁気異方性決定因子 [Not invited]青木恵祐; 堀井滋; 春田正和; 荻野拓; 下山淳一応用物理学関係連合講演会講演予稿集(CD-ROM) 2011/03
- (Pb,Fe)Sr2(Y,Ca)Cu2Ozにおける元素置換効果 [Not invited]武市将平; 田代大陸; 阿部雷太; 春田正和; 堀井滋; 前田敏彦応用物理学関係連合講演会講演予稿集(CD-ROM) 2011/03
- (Pb,Fe)Sr2(Y,Ca)Cu2Ozの電気抵抗率と結晶構造 [Not invited]前田敏彦; 武市将平; 田代大陸; 山崎一宣; 磯野修三; 春田正和; 堀井滋セラミックス基礎科学討論会講演要旨集 2011/01
- (RE1-xErx)2Ba4Cu7O15-δ(RE=Y,Dy)の三軸磁場配向と重希土類イオンの三軸磁気異方性 [Not invited]奥平翔太; 山木桃子; 春田正和; 下山淳一; 堀井滋応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2011
- (Pb,Co)Sr2(Y,Ca)Cu2Ozの合成と評価 [Not invited]田代大陸; 阿部雷太; 前田敏彦; 春田正和; 堀井滋応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2011
- 鉄ヒ素系超伝導体およびその類縁物質の磁場配向効果と磁気異方性 [Not invited]青木恵祐; 春田正和; 荻野拓; 下山淳一; 堀井滋応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2011
- ナノロッドを導入したYBa2Cu3Oy薄膜の磁束ピンニング特性に対する成膜温度の影響 [Not invited]春田正和; 前田敏彦; 堀井滋; MELE Paolo; 松本要低温工学・超電導学会講演概要集 2010/12
- 組織・組成制御した希土類系高温超伝導体の三軸磁場配向 [Not invited]堀井滋; 奥平翔太; 山木桃子; 春田正和; 下山淳一日本磁気科学会年会プログラム・要旨集 2010/10
- REBa2Cu4O8高温超伝導体の三軸磁場配向と磁化軸のRE依存性 [Not invited]山木桃子; 堀井滋; 春田正和; 前田敏彦; 下山淳一日本磁気科学会年会プログラム・要旨集 2010/10
- ナノロッドを導入したErBa2Cu3Oy薄膜における磁束ピンニング特性の成膜温度依存性 [Not invited]春田正和; 末吉哲郎; 藤吉孝則; 向田昌志; 甲斐英樹; 松本要; MELE P; 前田敏彦; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2010/08
- (Pb,Fe)Sr2(RE,Ca)Cu2Ozの合成と評価(RE:Yあるいは希土類元素) [Not invited]前田敏彦; 山崎一宣; 磯野修三; 田代大陸; 武市将平; 春田正和; 堀井滋応用物理学会学術講演会講演予稿集(CD-ROM) 2010/08
- (Bi,Cu)Sr2(Dy,Ca)Cu2Ozの合成と評価 [Not invited]田代大陸; 武市将平; 春田正和; 堀井滋; 前田敏彦応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2010/07
- 磁場配向法によるYBa2Cu4O8の三軸配向と磁気異方性の定量化 [Not invited]山木桃子; 堀井滋; 前田敏彦; 春田正和; 下山淳一応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2010/07
- (Pb,Fe)Sr2(RE,Ca)Cu2Ozの合成(RE:Yあるいは希土類元素) [Not invited]武市将平; 山崎一宜; 磯野修三; 田代大陸; 春田正和; 堀井滋; 前田敏彦応用物理学会中国四国支部・日本物理学会中国支部・四国支部・日本物理教育学会中国四国支部支部学術講演会講演予稿集 2010/07
- PLD法によるBi2Sr2CaCu2O8+δ薄膜を用いた固有ジョセフソン接合素子の作製 [Not invited]春田正和; 久米英司; 酒井滋樹応用物理学会学術講演会講演予稿集 2009/09
- BaZrO3添加REBa2Cu3Oy薄膜の磁束ピンニング特性 [Not invited]藤吉孝則; 春田正和; 末吉哲郎; 米倉健志; 向田昌志; 寺西亮; 松本要; 吉田隆; 一瀬中; 堀井滋; 淡路智; 渡辺和雄応用物理学会学術講演会講演予稿集 2007/09
- 超伝導混合状態におけるn値とピン力分布の関係 [Not invited]藤吉孝則; 春田正和; 梶田龍; 米倉健志; 末吉哲郎低温工学・超電導学会講演概要集 2007/05
- PLD法で作製したZnO/YBa2Cu3O7-δ多層膜の磁束ピンニング特性 [Not invited]末吉哲郎; 高橋献一; 佐藤直哉; 渡邉昌貴; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二低温工学・超電導学会講演概要集 2007/05
- Si基板上MgB2薄膜の臨界電流密度と磁気相図における酸素導入による影響 [Not invited]梶田龍; 藤吉孝則; 春田正和; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄; 宮川隆二応用物理学会九州支部学術講演会講演予稿集 2006/11
- BaZrO3を導入したErBa2Cu3O7-δ薄膜のピンニング特性 [Not invited]出崎公崇; 藤吉孝則; 春田正和; 末吉哲郎; 一期崎大輔; 向田昌志; 松本要; 吉田隆; 一瀬中; 堀井滋; 淡路智; 渡辺和雄応用物理学会九州支部学術講演会講演予稿集 2006/11
- BZOナノロッドを導入したErBCO薄膜の磁束ピンニング特性(2) [Not invited]藤吉孝則; 春田正和; 末吉哲郎; 出崎公崇; 一期崎大輔; 向田昌志; 松本要; 吉田隆; 一瀬中; 堀井滋; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2006/11
- Si基板上MgB2薄膜の磁束ピンニング特性に対する酸素導入効果 [Not invited]春田正和; 藤吉孝則; 梶田龍; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄; 宮川隆二低温工学・超電導学会講演概要集 2006/11
- 1次元ピンを導入したREBaCuO薄膜の磁束ピンニング特性 [Not invited]末吉哲郎; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二; 知見康弘; 石川法人; 向田昌志; 堀井滋; 一瀬中; 吉田隆; 松本要電気関係学会九州支部連合大会講演論文集(CD-ROM) 2006/09
- BaZrO3添加ErBa2Cu3Oy薄膜の磁束ピンニング特性 [Not invited]藤吉孝則; 春田正和; 末吉哲郎; 出崎公崇; 向田昌志; 松本要; 吉田隆; 一瀬中; 堀井滋; 淡路智; 渡辺和雄応用物理学会学術講演会講演予稿集 2006/08
- 高臨界電流密度を有する分子線エピタキシーによるas‐grown MgB2薄膜 [Not invited]春田正和; 藤吉孝則; 木原眞太郎; 末吉哲郎; 原田善之; 吉澤正人; 高橋輝一; 入宇田啓樹; 淡路智; 渡辺和雄応用物理学会学術講演会講演予稿集 2006/08
- 人工ピンを導入した高温超伝導薄膜における磁束ピンニング特性 [Not invited]末吉哲郎; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顯; 蛯原健治; 宮川隆二; 知見康弘; 石川法人; 向田昌志; 堀井滋; 一瀬中; 吉田隆; 松本要電気学会基礎・材料・共通部門大会(CD-ROM) 2006/08
- BZOナノロッドを導入したErBCO薄膜の磁束ピンニング特性 [Not invited]藤吉孝則; 春田正和; 末吉哲郎; 出崎公崇; 一期崎大輔; 宮川隆二; 向田昌志; 松本要; 吉田隆; 一瀬中; 堀井滋低温工学・超電導学会講演概要集 2006/05
- MBE法で作製した高Jc as‐grown MgB2薄膜の磁束ピンニング特性 [Not invited]春田正和; 藤吉孝則; 木原眞太郎; 末吉哲郎; 吉澤正人; 高橋輝一; 入宇田啓樹; 原田義之; 淡路智; 渡辺和雄; 宮川隆二低温工学・超電導学会講演概要集 2006/05
- MBE法で作製した高Jc as-grown MgB2薄膜の磁束ピンニング特性 [Not invited]春田 正和; 藤吉 孝則; 木原 眞太郎; 末吉 哲郎; 吉澤 正人; 高橋 輝一; 入宇田 啓樹; 原田 義之; 淡路 智; 渡辺 和雄; 宮川 隆二第74回2006年度春季低温工学・超電導学会講演概要集 (低温工学会) 2006
- BZO添加量の異なるErBCO薄膜の磁束ピンニング特性 [Not invited]藤吉 孝則; 春田 正和; 末吉 哲郎; 出崎 公崇; 向田 昌志; 松本 要; 吉田 隆; 一瀬 中; 堀井 滋; 淡路 智; 渡辺 和雄低温工学協会九州・西日本支部 第1回研究会 2006
- 高臨界電流密度を有する分子線エピタキシーによる as-grown MgB2薄膜 [Not invited]春田 正和; 藤吉 孝則; 木原 眞太郎; 末吉 哲郎; 吉澤 正人; 高橋 輝一; 入宇田 啓樹; 原田 義之; 淡路 智; 渡辺 和雄2006年度秋季第68回応用物理学会学術講演会 講演予稿集 ((社)応用物理学会) 2006
- BaZrO3添加ErBa2Cu3Oy 薄膜の磁束ピンニング特性 [Not invited]藤吉 孝則; 春田 正和; 末吉 哲郎; 出崎 公崇; 向田 昌志; 松本 要; 吉田 隆; 一瀬 中; 堀井 滋; 淡路 智; 渡辺 和雄2006年度秋季第68回応用物理学会学術講演会 講演予稿集 ((社)応用物理学会) 2006
- BZrO3を導入したErBa2Cu3O7薄膜のピンニング特性 [Not invited]出崎 公崇; 藤吉 孝則; 春田 正和; 末吉 哲郎; 一期崎 大輔; 向田 昌志; 松本 要; 吉田 隆; 一瀬 中; 堀井 滋; 淡路 智; 渡辺 和雄; 宮川 隆二平成18年度応用物理学会九州支部講演会 講演予稿集 ((社)応用物理学会) 2006
- Si基板上MgB2薄膜の臨界電流密度と磁気相図における酸素導入による影響 [Not invited]梶田 龍; 藤吉 孝則; 春田 正和; 末吉 哲郎; 土井 俊哉; 北口 仁; 淡路 智; 渡辺 和雄; 宮川 隆二平成18年度応用物理学会九州支部講演会 講演予稿集 ((社)応用物理学会) 2006
- 人工ピンを導入したSmBCO薄膜の磁束ピンニング特性 [Not invited]藤吉孝則; 末吉哲郎; 春田正和; 城台憲人; 上野剛; 宮川隆二; 吉田隆; 三浦正志; 松本要; 向田昌志; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2005/11
- 柱状欠陥を導入したYBCO薄膜におけるピンニングパラメータの磁場角度依存性 [Not invited]末吉哲郎; 平湯直志; 春田正和; 藤吉孝則; 宮原邦幸; 池上知顕; えび原健治; 宮川隆二; 知見康弘; 石川法人; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2005/11
- 酸素雰囲気中で作製したMgB2薄膜の磁束ピンニング特性 [Not invited]春田正和; 藤吉孝則; 末吉哲郎; 宮原邦幸; 土井俊哉; 北口仁; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2005/11
- 電子ビーム蒸着法によるMgB2薄膜の臨界電流密度 [Not invited]藤吉孝則; 春田正和; 末吉哲郎; 土井俊哉; 北口仁; 淡路智; 渡辺和雄応用物理学会学術講演会講演予稿集 2005/09
- 電子ビーム蒸着法により作製したMgB2薄膜のピンニング特性(II) [Not invited]春田正和; 藤吉孝則; 末吉哲郎; 宮原邦幸; 土井俊哉; 北口仁; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2005/05
- 人工ピンを導入したREBCO薄膜の磁束ピンニング特性 [Not invited]藤吉孝則; 末吉哲郎; 春田正和; 城台憲人; 上野剛; 宮川隆二; 向田昌志; 松本要; 吉田隆; 三浦正志低温工学・超電導学会講演概要集 2005/05
- 電子ビーム蒸着法により作製したMgB2薄膜のピンニング特性 [Not invited]春田正和; 藤吉孝則; 末吉哲郎; 宮原邦幸; 土井俊哉; 北口仁低温工学・超電導学会講演概要集 2004/11
- RFスパッタリング法により作製されたMgB2薄膜の特性評価 [Not invited]春田正和; 末吉哲郎; 藤吉孝則; 木原真太郎; 村中哲也; 土井俊哉; 白楽善則; 宮川隆二低温工学・超電導学会講演概要集 2004/05
- 柱状欠陥を導入したYBCO超伝導薄膜の電圧‐電流特性の磁場角度依存性 [Not invited]藤吉孝則; 末吉哲郎; 春田正和; 池上知顕; えび原健治; 宮川隆二; 石川法人; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2004/05
- Fujiyoshi Takanori; Sueyoshi Tetsuro; Haruta Masakazu; Ikegami Tomoaki; Ebihara Kenji; Miyagawa Ryuji; Ishikawa Norihito; Awaji Satoshi; Watanabe KazuoRecord of Joint Conference of Electrical and Electronics Engineers in Kyushu 2004 Committee of Joint Conference of Electrical, Electronics and Information Engineers in Kyushu
- 高温超伝導体のピンニング状態における磁化緩和特性 [Not invited]藤吉孝則; 春田正和; 山藤馨低温工学・超電導学会講演概要集 2003/12
- 高温超伝導体における臨界電流密度の温度・磁界依存性に関するスケーリング則 [Not invited]藤吉孝則; 春田正和; 木須隆暢; 岩熊成卓; 山藤馨低温工学・超電導学会講演概要集 2003/05
- 高温超伝導体のピンニング・パラメータに対する柱状欠陥の影響 [Not invited]春田正和; 蔵満健二; 藤吉孝則; 末吉哲郎; 宮原邦幸; 宮川隆二; 石川法人; 淡路智; 渡辺和雄低温工学・超電導学会講演概要集 2003/05
Affiliated academic society
Research Themes
- 全固体電池安定動作の要“電解質/電極界面イオン伝導”を操る日本学術振興会:科学研究費助成事業 基盤研究(B)Date (from‐to) : 2022/04 -2025/03Author : 春田正和
- Japan Society for the Promotion of Science:Grants-in-Aid for Scientific ResearchDate (from‐to) : 2019/04 -2022/03Author : Haruta MasakazuSilicon negative electrodes with high capacities have been developed for next-generation lithium-ion batteries. For practical use of the silicon negative electrodes, suppression of a reductive decomposition of an electrolyte is necessary to achieve a long cycle life. Silicon composite electrodes with Nafion (perfluorinated ionomers) coating demonstrated improved cycle performance. X-ray photoelectron spectroscopy analyses of the Nafion-coated electrodes revealed that Nafion decomposed reductively to form a LiF-rich surface film at the first charging and effectively suppressed the decomposition of the electrolyte. Moreover, the silicon negative electrode was applied to an all-solid-state battery with a garnet-type oxide as a solid electrolyte and showed superior capacity retention.
- 高エネルギー密度シリコン負極の実用化に向けた電極界面制御とイオン伝導機構の解明日本学術振興会:科学研究費補助金・基盤研究(B)Date (from‐to) : 2016/04 -2019/03Author : 春田正和
- 長尺高温超伝導線材の高性能化と安定製造に向けた材料設計日本学術振興会:科学研究費補助金・若手研究(B)Date (from‐to) : 2013/04 -2016/03Author : 春田正和
- ナノ欠陥を導入した希土類系高温超伝導薄膜のキャリア密度制御による高性能化日本学術振興会:科学研究費補助金・若手研究(B)Date (from‐to) : 2011/04 -2013/03Author : 春田正和
- 超伝導/欠陥界面構造制御による実用的高温超伝導線材の製造技術の確立公益財団法人池谷科学技術振興財団:単年度研究助成‐ADate (from‐to) : 2012 -2012Author : 春田正和
- 高温超伝導線材の実用化に向けた結晶組織制御と欠陥/超伝導界面構造の解明公益財団法人東電記念財団:平成23年度研究助成(電気・エネルギー一般研究)Date (from‐to) : 2012 -2012Author : 春田正和
- JSAP-MRSジョイントシンポジウム若手研究者・技術者派遣助成応用物理学会:Date (from‐to) : 2012 -2012Author : 春田正和
- ナノ欠陥の制御導入による実用的希土類系高温超伝導線材の製造技術の確立公益財団法人中部電気利用基礎研究振興財団:研究助成Date (from‐to) : 2011 -2011Author : 春田正和