KINDAI UNIVERSITY


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MATSUO Tsukasa

Profile

FacultyDepartment of Applied Chemistry / Graduate School of Science and Engineering Research
PositionProfessor
Degree
Commentator Guidehttps://www.kindai.ac.jp/meikan/359-matsuo-tsukasa.html
URL
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Last Updated :2020/04/05

Education and Career

Academic & Professional Experience

  •   2012 04 ,  - 現在, Kinki University
  •   2011 10 ,  - 2015 03 , Japan Science and Technology Agency
  •   2008 04 ,  - 2012 03 , RIKEN
  •   2007 04 ,  - 2008 03 , RIKEN
  •   2004 04 ,  - 2007 03 , National Institutes of Natural Sciences

Research Activities

Research Areas

  • Nanotechnology/Materials, Functional solid-state chemistry
  • Life sciences, Bioorganic chemistry
  • Nanotechnology/Materials, Structural/physical organic chemistry
  • Nanotechnology/Materials, Inorganic and coordination chemistry

Published Papers

  • Synthesis and Thermal Reactions of a Spiro-type Cyclotrisilene Obtained from the Reaction between a Disilenide and a Base Adduct of a Bromosilylene, Kosai Tomoyuki, Nishimura Shogo, Hayakawa Naoki, Matsuo Tsukasa, Iwamoto Takeaki, CHEMISTRY LETTERS, CHEMISTRY LETTERS, 48(9), 1168 - 1170, Sep. 2019 , Refereed
  • Reactions of a Silylyne Complex with Aldehydes: Formation of W-Si-O-C Four-Membered Metallacycles and Their Metathesis-Like Fragmentation, Yoshimoto Takashi, Hashimoto Hisako, Takagi Nozomi, Sakaki Shigeyoshi, Hayakawa Naoki, Matsuo Tsukasa, Tobita Hiromi, CHEMISTRY-A EUROPEAN JOURNAL, CHEMISTRY-A EUROPEAN JOURNAL, 25(15), 3795 - 3798, Mar. 12 2019 , Refereed
  • A stable free tetragermacyclobutadiene incorporating fused-ring bulky EMind groups, Suzuki Katsunori, Numata Yasuyuki, Fujita Naoko, Hayakawa Naoki, Tanikawa Tomoharu, Hashizume Daisuke, Tamao Kohei, Fueno Hiroyuki, Tanaka Kazuyoshi, Matsuo Tsukasa, CHEMICAL COMMUNICATIONS, CHEMICAL COMMUNICATIONS, 54(18), Mar. 04 2018 , Refereed
  • Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group, Hayakawa Naoki, Sadamori Kazuya, Mizutani Shinsuke, Agou Tomohiro, Sugahara Tomohiro, Sasamori Takahiro, Tokitoh Norihiro, Hashizume Daisuke, Matsuo Tsukasa, INORGANICS, INORGANICS, 6(1), Mar. 2018 , Refereed
  • pi-Electron systems containing Si=Si double bonds, Matsuo Tsukasa, Hayakawa Naoki, SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 19(1), 108 - 129, Feb. 07 2018 , Refereed
  • 1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids, Hayakawa Naoki, Sugahara Tomohiro, Numata Yasuyuki, Kawaai Hotaka, Yamatani Kenta, Nishimura Shogo, Goda Shun, Suzuki Yuko, Tanikawa Tomoharu, Nakai Hidetaka, Hashizume Daisuke, Sasamori Takahiro, Tokitoh Norihiro, Matsuo Tsukasa, DALTON TRANSACTIONS, DALTON TRANSACTIONS, 47(3), 814 - 822, Jan. 21 2018 , Refereed
  • pi-Conjugation between a Si=Si Double Bond and Thiophene Rings: Synthesis, Structural Characteristics, and Photophysical Properties of 1,2-Bis(thiophen-2-yl)disilene and 1,2-Bis(2,2'-bithiophen-5-yI)disilene, Naoki Hayakawa, Shogo Nishimura, Nobuhiro Kazusa, Nozomu Shintani, Tsukasa Nakahodo, Hisashi Fujihara, Manabu Hoshino, Daisuke Hashizume, Tsukasa Matsuo, ORGANOMETALLICS, ORGANOMETALLICS, 36(17), 3226 - 3233, Sep. 2017 , Refereed
    Summary:The two new disilene compounds, 1,2-bis-(thiophen-2-yl)disilene (1) and 1,2-bis(2,2'-bithiophen-5-yl)disilene (2), supported by the fused-ring bulky Eind groups (Eind = 1,1,3,3,5,S,7,7-octaethyl-s-hydrindacen-4-yl) have been obtained as orange and purple crystals, respectively, by the reduction of the corresponding dibromosilanes. Their X-ray structures and spectroscopic properties demonstrate the effective pi-conjugation between a Si=Si double bond and thiophene units. Notably, the pi-extended 2 exhibits a distinct emission both in solution and in the solid state at room temperature based on the essentially coplanar 1,2-bis-(bithienyl)disilene skeleton. The structural features and electronic properties of 1 and 2 have been thoroughly characterized both experimentally and computationally.
  • A Square-Planar Complex of Platinum(0), Takeuchi Katsuhiko, Taguchi Hiro-omi, Tanigawa Ippei, Tsujimoto Shota, Matsuo Tsukasa, Tanaka Hiromasa, Yoshizawa Kazunari, Ozawa Fumiyuki, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(49), 15347 - 15350, Dec. 05 2016 , Refereed
  • A Silylyne Tungsten Complex Having an Eind Group on Silicon: Its Dimer-Monomer Equilibrium and Cycloaddition Reactions with Carbodiimide and Diaryl Ketones, Yoshimoto Takashi, Hashimoto Hisako, Hayakawa Naoki, Matsuo Tsukasa, Tobita Hiromi, ORGANOMETALLICS, ORGANOMETALLICS, 35(20), 3444 - 3447, Oct. 24 2016 , Refereed
  • Synthesis and Structural Characteristics of Discrete Organoboron and Organoaluminum Hydrides Incorporating Bulky Eind Groups, Murosaki Takahiro, Kaneda Shohei, Maruhashi Ryota, Sadamori Kazuya, Shoji Yoshiaki, Tamao Kohei, Hashizume Daisuke, Hayakawa Naoki, Matsuo Tsukasa, ORGANOMETALLICS, ORGANOMETALLICS, 35(19), 3397 - 3405, Oct. 10 2016 , Refereed
  • Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species, Nagata Koichi, Murosaki Takahiro, Agou Tomohiro, Sasamori Takahiro, Matsuo Tsukasa, Tokitoh Norihiro, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(41), 12877 - 12880, Oct. 04 2016 , Refereed
  • Synthesis and Structural Characterization of Lithium and Titanium Complexes Bearing a Bulky Aryloxide Ligand Based on a Rigid Fused-Ring s-Hydrindacene Skeleton, Kanazawa Shoya, Ohira Taishi, Goda Shun, Hayakawa Naoki, Tanikawa Tomoharu, Hashizume Daisuke, Ishida Yutaka, Kawaguchi Hiroyuki, Matsuo Tsukasa, INORGANIC CHEMISTRY, INORGANIC CHEMISTRY, 55(13), 6643 - 6652, Jul. 04 2016 , Refereed
  • Synthesis and Magnetic Properties of Linear Two-coordinate Monomeric Diaryliron(II) Complexes Bearing Fused-ring Bulky "Rind" Groups, Goda Shun, Nikai Masanori, Ito Mikinao, Hashizume Daisuke, Tamao Kohei, Okazawa Atsushi, Kojima Norimichi, Fueno Hiroyuki, Tanaka Kazuyoshi, Kobayashi Yoshio, Matsuo Tsukasa, CHEMISTRY LETTERS, CHEMISTRY LETTERS, 45(6), 634 - 636, Jun. 05 2016 , Refereed
  • Unsymmetrical PNP-Pincer Type Phosphaalkene Ligands Protected by a Fused-Ring Bulky Eind Group: Synthesis and Applications to Rh(I) and Ir(I) Complexes, Taguchi Hiro-omi, Sasaki Daichi, Takeuchi Katsuhiko, Tsujimoto Shota, Matsuo Tsukasa, Tanaka Hiromasa, Yoshizawa Kazunari, Ozawa Fumiyuki, ORGANOMETALLICS, ORGANOMETALLICS, 35(10), 1526 - 1533, May 23 2016 , Refereed
  • Synthesis and Structures of Sterically Congested Diarylsilanes Bearing Two Bulky Rind Groups, Hayakawa Naoki, Morimoto Tatsuto, Takagi Akihiro, Tanikawa Tomoharu, Hashizume Daisuke, Matsuo Tsukasa, CHEMISTRY LETTERS, CHEMISTRY LETTERS, 45(4), 409 - 411, Apr. 05 2016 , Refereed
  • (Z)-1,2-Di(1-pyrenyl)disilene: Synthesis, Structure, and Intramolecular Charge-Transfer Emission, Kobayashi Megumi, Hayakawa Naoki, Matsuo Tsukasa, Li Baolin, Fukunaga Takeo, Hashizume Daisuke, Fueno Hiroyuki, Tanaka Kazuyoshi, Tamao Kohei, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(3), 758 - 761, Jan. 27 2016 , Refereed
  • Coplanar Oligo(p-phenylenedisilenylene)s as Si=Si Analogues of Oligo(p-phenylenevinylene)s: Evidence for Extended pi-Conjugation through the Carbon and Silicon,pi-Frameworks, Li Liangchun, Matsuo Tsukasa, Hashizume Daisuke, Fueno Hiroyuki, Tanaka Kazuyoshi, Tamao Kohei, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(47), 15026 - 15035, Dec. 02 2015 , Refereed
  • Fused-Ring Bulky "Rind" Groups Producing New Possibilities in Elemento-Organic Chemistry, Matsuo Tsukasa, Tamao Kohei, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 88(9), 1201 - 1220, Sep. 15 2015 , Refereed
  • Extremely active alpha-olefin polymerization and copolymerization with ethylene catalyzed by a dMAO-activated zirconium(IV) dichloro complex having an [OSSO]-type ligand, Toda Tomoyuki, Nakata Norio, Matsuo Tsukasa, Ishii Akihiko, RSC ADVANCES, RSC ADVANCES, 5(108), 88826 - 88831, 2015 , Refereed
  • Controlled Isospecific Polymerization of alpha-Olefins by Hafnium Complex Incorporating with a trans-Cyclooctanediyl-Bridged [OSSO]-Type Bis(phenolate) Ligand, Nakata Norio, Toda Tomoyuki, Matsuo Tsukasa, Ishii Akihiko, MACROMOLECULES, MACROMOLECULES, 46(17), 6758 - 6764, Sep. 10 2013 , Refereed
  • Reactions of a Niobium Nitride Complex Prepared from Dinitrogen: Synthesis of Imide and Ureate Complexes and Ammonia Formation, Akagi Fumio, Suzuki Shoui, Ishida Yutaka, Hatanaka Tsubasa, Matsuo Tsukasa, Kawaguchi Hiroyuki, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013(22-23), 3930 - 3936, Aug. 06 2013 , Refereed
  • Synthesis, Structure, and 1-Hexene Polymerization Catalytic Ability of Group 5 Metal Complexes Incorporating an [OSSO]-Type Ligand, Toda Tomoyuki, Nakata Norio, Matsuo Tsukasa, Ishii Akihiko, ACS CATALYSIS, ACS CATALYSIS, 3(8), 1764 - 1767, Aug. 2013 , Refereed
  • Intramolecular [2+2+2] cycloaddition of bis(propargylphenyl)carbodiimides: synthesis of L-shaped π-extended compounds with pyrrolo[1,2-a][1,8]naphthyridine corner units., Otani T, Saito T, Sakamoto R, Osada H, Hirahara A, Furukawa N, Kutsumura N, Matsuo T, Tamao K, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), 49(55), 6206 - 6208, Jul. 2013 , Refereed
  • Sterically demanding imidazolinium salts through the activation and cyclization of formamides., Tsimerman M, Mallik D, Matsuo T, Otani T, Tamao K, Organ MG, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), 48(83), 10352 - 10354, Oct. 2012 , Refereed
  • A new binding motif of sterically demanding thiolates on a gold cluster., Nishigaki J, Tsunoyama R, Tsunoyama H, Ichikuni N, Yamazoe S, Negishi Y, Ito M, Matsuo T, Tamao K, Tsukuda T, Journal of the American Chemical Society, Journal of the American Chemical Society, 134(35), 14295 - 14297, Sep. 05 2012 , Refereed
  • A stable germanone as the first isolated heavy ketone with a terminal oxygen atom, Li Liangchun, Fukawa Tomohide, Matsuo Tsukasa, Hashizume Daisuke, Fueno Hiroyuki, Tanaka Kazuyoshi, Tamao Kohei, NATURE CHEMISTRY, NATURE CHEMISTRY, 4(5), 361 - 365, May 2012 , Refereed
  • The first observation of electroluminescence from di(2-naphthyl)disilene, an Si=Si double bond-containing π-conjugated compound., Tamao K, Kobayashi M, Matsuo T, Furukawa S, Tsuji H, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), 48(7), 1030 - 1032, Jan. 25 2012 , Refereed
  • Titanium complexes supported by an [OSSO]-type bis(phenolato) ligand based on a trans-cyclooctanediyl platform: synthesis, structures, and 1-hexene polymerization., Nakata N, Toda T, Matsuo T, Ishii A, Inorganic chemistry, Inorganic chemistry, 51(1), 274 - 281, Jan. 02 2012 , Refereed
  • Room-temperature dissociation of 1,2-dibromodisilenes to bromosilylenes., Suzuki K, Matsuo T, Hashizume D, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 133(49), 19710 - 19713, Dec. 14 2011 , Refereed
  • Synthesis and Structures of a Series of Bulky "Rind-Br" Based on a Rigid Fused-Ring s-Hydrindacene Skeleton, Matsuo Tsukasa, Suzuki Katsunori, Fukawa Tomohide, Li Baolin, Ito Mikinao, Shoji Yoshiaki, Otani Takashi, Li Liangchun, Kobayashi Megumi, Hachiya Makoto, Tahara Yoshiyuki, Hashizume Daisuke, Fukunaga Takeo, Fukazawa Aiko, Li Yongming, Tsuji Hayato, Tamao Kohei, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 84(11), 1178 - 1191, Nov. 15 2011 , Refereed
  • Boron-Boron σ-Bond Formation by Two-Electron Reduction of a H-Bridged Dimer of Monoborane., Shoji Y, Matsuo T, Hashizume D, Gutmann MJ, Fueno H, Tanaka K, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 133(29), 11058 - 11061, Jul. 27 2011 , Refereed
  • Neutral and Cationic Gold(I) Complexes with pi-Conjugated Phosphasilene Ligands, Li Baolin, Matsuo Tsukasa, Fukunaga Takeo, Hashizume Daisuke, Fueno Hiroyuki, Tanaka Kazuyoshi, Tamao Kohei, ORGANOMETALLICS, ORGANOMETALLICS, 30(13), 3453 - 3456, Jul. 11 2011 , Refereed
  • Air- and moisture-stable p-monothiobenzoquinones incorporated in an octaalkyl-s-hydrindacene skeleton., Hachiya M, Ito M, Matsuo T, Hashizume D, Fueno H, Tanaka K, Tamao K, Organic letters, Organic letters, 13(10), 2666 - 2669, May 20 2011 , Refereed
  • Synthesis and structures of dialkyl zirconium complexes with an [OSSO]-type bis(phenolate) ligand bearing a trans-1,2-cyclooctanediylbis(thio) unit, Toda Tomoyuki, Nakata Norio, Matsuo Tsukasa, Ishii Akihiko, JOURNAL OF ORGANOMETALLIC CHEMISTRY, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696(6), 1258 - 1261, Apr. 2011 , Refereed
  • A planar rhombic charge-separated tetrasilacyclobutadiene., Suzuki K, Matsuo T, Hashizume D, Fueno H, Tanaka K, Tamao K, Science (New York, N.Y.), Science (New York, N.Y.), 331(6022), 1306 - 1309, Mar. 11 2011 , Refereed
  • Synthesis and reactivity of niobium complexes having a tripodal triaryloxide ligand in bidentate, tridentate, and tetradentate coordination modes., Akagi F, Ishida Y, Matsuo T, Kawaguchi H, Dalton transactions (Cambridge, England : 2003), Dalton transactions (Cambridge, England : 2003), 40(10), 2375 - 2382, Mar. 2011 , Refereed
  • The synthesis of highly coplanar oligothiophenes induced by bulky rind groups., Otani T, Hachiya M, Hashizume D, Matsuo T, Tamao K, Chemistry, an Asian journal, Chemistry, an Asian journal, 6(2), 350 - 354, Feb. 01 2011 , Refereed
  • COORDINATION CHEMISTRY AND ORGANIC SYNTHESIS UTILIZING CYCLOALKANE-1,2-DITHIOL, Ishii Akihiko, Toda Tomoyuki, Nakata Norio, Matsuo Tsukasa, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 186(5), 1169 - 1174, 2011 , Refereed
  • Air-stable, room-temperature emissive disilenes with π-extended aromatic groups., Kobayashi M, Matsuo T, Fukunaga T, Hashizume D, Fueno H, Tanaka K, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 132(43), 15162 - 15163, Nov. 03 2010 , Refereed
  • π-Conjugated disilenes stabilized by fused-ring bulky "Rind" groups., Matsuo T, Kobayashi M, Tamao K, Dalton transactions (Cambridge, England : 2003), Dalton transactions (Cambridge, England : 2003), 39(39), 9203 - 9208, Oct. 2010 , Refereed
  • pi-conjugated phosphasilenes stabilized by fused-ring bulky "Rind" groups, Matsuo Tsukasa, Li Baolin, Tamao Kohei, COMPTES RENDUS CHIMIE, COMPTES RENDUS CHIMIE, 13(8-9), 1104 - 1110, Aug. 2010 , Refereed
  • A stable doubly hydrogen-bridged butterfly-shaped diborane(4) compound., Shoji Y, Matsuo T, Hashizume D, Fueno H, Tanaka K, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 132(24), 8258 - 8260, Jun. 23 2010 , Refereed
  • Syntheses and structures of zirconium(IV) complexes supported by 2,6-di-adamantylaryloxide ligands and formation of arene-bridged dizirconium complexes with an inverse sandwich structure., Watanabe T, Ishida Y, Matsuo T, Kawaguchi H, Dalton transactions (Cambridge, England : 2003), Dalton transactions (Cambridge, England : 2003), 39(2), 484 - 491, Jan. 2010 , Refereed
  • Isolated monomeric and dimeric mixed diorganocuprates based on the size-controllable bulky "rind" ligands., Ito M, Hashizume D, Fukunaga T, Matsuo T, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 131(50), 18024 - 18025, Dec. 23 2009 , Refereed
  • Zirconium complex of an [OSSO]-type diphenolate ligand bearing trans-1,2-cyclooctanediylbis(thio) core: synthesis, structure, and isospecific 1-hexene polymerization., Ishii A, Toda T, Nakata N, Matsuo T, Journal of the American Chemical Society, Journal of the American Chemical Society, 131(38), 13566 - 13567, Sep. 03 2009 , Refereed
  • Pi-conjugated phosphasilenes stabilized by fused-ring bulky groups., Li B, Matsuo T, Hashizume D, Fueno H, Tanaka K, Tamao K, Journal of the American Chemical Society, Journal of the American Chemical Society, 131(37), 13222 - 13223, Sep. 02 2009 , Refereed
  • DFT study on N2 activation by a hydride-bridged diniobium complex. N[triple bond]N bond cleavage accompanied by H2 evolution., Tanaka H, Shiota Y, Matsuo T, Kawaguchi H, Yoshizawa K, Inorganic chemistry, Inorganic chemistry, 48(8), 3875 - 3881, Apr. 02 2009 , Refereed
  • Reductive coupling of six carbon monoxides by a ditantalum hydride complex., Watanabe T, Ishida Y, Matsuo T, Kawaguchi H, Journal of the American Chemical Society, Journal of the American Chemical Society, 131(10), 3474 - 3475, Mar. 01 2009 , Refereed
  • Tamao oxidation: chemistry filled with a tapestry of carbon and silicon, Matsuo, Tsukasa, Kagaku to Kyoiku, Kagaku to Kyoiku, 57(9), 406 - 407, 2009 , Refereed
  • Anisole-diphenoxide ligands and their zirconium dichloride and dialkyl complexes., Matsuo T, Kawaguchi H, Inorganic chemistry, Inorganic chemistry, 46(20), 8426 - 8434, Oct. 01 2007 , Refereed
  • Dinitrogen cleavage by a diniobium tetrahydride complex: formation of a nitride and its conversion into imide species., Akagi F, Matsuo T, Kawaguchi H, Angewandte Chemie (International ed. in English), Angewandte Chemie (International ed. in English), 46(46), 8778 - 8781, 2007 , Refereed
  • Zirconium complexes of the tridentate bis(aryloxide)-N-heterocyclic-carbene ligand: Chloride and alkyl functionalized derivatives, Zhang Dao, Aihara Hidenori, Watanabe Takahito, Matsuo Tsukasa, Kawaguchi Hiroyuki, JOURNAL OF ORGANOMETALLIC CHEMISTRY, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(1-3), 234 - 242, Jan. 01 2007 , Refereed
  • Doubly charged four-membered ring systems: Cyclobutadiene dianions and heavy cyclobutadiene dianions, Sekiguchi Akira, Matsuo Tsukasa, SYNLETT, SYNLETT, (17), 2683 - 2698, Oct. 17 2006 , Refereed
  • From carbon dioxide to methane: homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes., Matsuo T, Kawaguchi H, Journal of the American Chemical Society, Journal of the American Chemical Society, 128(38), 12362 - 12363, Sep. 02 2006 , Refereed
  • A tantalum(V) carbene complex: formation of a carbene-bis(phenoxide) ligand by sequential proton and hydride abstraction., Watanabe T, Matsuo T, Kawaguchi H, Inorganic chemistry, Inorganic chemistry, 45(17), 6580 - 6582, Aug. 02 2006 , Refereed
  • A synthetic cycle for H2/CO activation and allene synthesis using recyclable zirconium complexes., Matsuo T, Kawaguchi H, Journal of the American Chemical Society, Journal of the American Chemical Society, 127(49), 17198 - 17199, Dec. 01 2005 , Refereed
  • Complexes of tantalum with triaryloxides: Ligand and solvent effects on formation of hydride derivatives, Hiroyuki Kawaguchi, Matsuo Tsukasa, J. Organomet. Chem., J. Organomet. Chem., 690(23), 5333 - 5345, Sep. 2005 , Refereed
  • Titanium and zirconium complexes of preorganized tripodal triaryloxide ligands., Akagi F, Matsuo T, Kawaguchi H, Journal of the American Chemical Society, Journal of the American Chemical Society, 127(34), 11936 - 11937, Aug. 03 2005 , Refereed
  • Synthesis of a vanadium(III) tris(arylthiolato) complex and its reactions with azide and azo compounds: formation of a sulfenamide complex via cleavage of an azo N=N bond., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Inorganic chemistry, Inorganic chemistry, 44(2), 175 - 177, Jan. 02 2005 , Refereed
  • Synthesis and structural characterization of silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Dalton transactions (Cambridge, England : 2003), Dalton transactions (Cambridge, England : 2003), (10), 1618 - 1625, May 02 2004 , Refereed
  • Formation of an iron(II) carbene-thiolato complex by insertion of carbon monoxide into an Si-C bond., Yuki M, Matsuo T, Kawaguchi H, Angewandte Chemie (International ed. in English), Angewandte Chemie (International ed. in English), 43(11), 1404 - 1407, Mar. 05 2004 , Refereed
  • Cyclobutadiene dianion, Matsuo, Tsukasa, Sekiguchi, Akira, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 77(2), 211 - 226, 2004 , Refereed
  • Tridentate aryloxide ligands: New supporting ligands in coordination chemistry of early transition metals, Matsuo, Tsukasa, Kawaguchi, Hiroyuki, Chemistry Letters, Chemistry Letters, 33(6), 640 - 645, 2004 , Refereed
  • Aryloxide-​based multidentate ligands for early transition metals and f-​element metals, Kawaguchi, Hiroyuki, Matsuo, Tsukasa, Journal of Organometallic Chemistry, Journal of Organometallic Chemistry, 689(24), 4228 - 4243, 2004 , Refereed
  • Tetrasilyl-Substituted Cyclobutadiene Dianion Dilithium: Synthesis and Structure, Sekiguchi Akira, Matsuo Tsukasa, Tanaka Masanobu, Watanabe Hidetoshi, Nakamoto Masaaki, Russ. Chem. Bull., Russ. Chem. Bull., 53(5), 1109 - 1115, 2004 , Refereed
  • Aryl-oxygen bond cleavage by a trihydride-bridging ditantalum complex., Kawaguchi H, Matsuo T, Journal of the American Chemical Society, Journal of the American Chemical Society, 125(47), 14254 - 14255, Nov. 02 2003 , Refereed
  • Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol)., Aihara H, Matsuo T, Kawaguchi H, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), (17), 2204 - 2205, Sep. 07 2003 , Refereed
  • Coordination chemistry of silanedithiolato ligands derived from cyclotrisilathiane: synthesis and structures of complexes of iron(II), cobalt(II), palladium(II), copper(I), and silver(I)., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Inorganic chemistry, Inorganic chemistry, 42(17), 5340 - 5347, Aug. 02 2003 , Refereed
  • Unusual coordination modes of arylthiolates in Mo(eta(5)-SC(6)H(3)-2,6-(SiMe(3))(2))(eta(7)-SC(6)H(3)-2,6-(SiMe(3))(2))., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Journal of the American Chemical Society, Journal of the American Chemical Society, 125(8), 2070 - 2071, Feb. 02 2003 , Refereed
  • Copper and silver complexes containing the S(SiMe2S)2(2-) ligand: efficient entries into heterometallic sulfido clusters., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Angewandte Chemie (International ed. in English), Angewandte Chemie (International ed. in English), 42(4), 465 - 468, Jan. 02 2003 , Refereed
  • Triple-​Hydrogen-​Bridged Dititanium(III) and Dizirconium(IV) Aryloxide Complexes, Matsuo, Tsukasa, Kawaguchi, Hiroyuki, Organometallics, Organometallics, 22(26), 5379 - 5381, 2003 , Refereed
  • Tetrakis(trimethylsilyl)tetrahedrane., Maier G, Neudert J, Wolf O, Pappusch D, Sekiguchi A, Tanaka M, Matsuo T, Journal of the American Chemical Society, Journal of the American Chemical Society, 124(46), 13819 - 13826, Nov. 02 2002 , Refereed
  • Synthesis and structures of niobium(V) complexes stabilized by linear-linked aryloxide trimers., Matsuo T, Kawaguchi H, Inorganic chemistry, Inorganic chemistry, 41(23), 6090 - 6098, Nov. 01 2002 , Refereed
  • Dinitrogen-bond cleavage in a niobium complex supported by a tridentate aryloxide ligand., Kawaguchi H, Matsuo T, Angewandte Chemie (International ed. in English), Angewandte Chemie (International ed. in English), 41(15), 2792 - 2794, Aug. 02 2002 , Refereed
  • Binuclear iron(II) complex from a linked-bis(amidinate) ligand: synthesis and its reaction with carbon monoxide., Kawaguchi H, Matsuo T, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), (9), 958 - 959, May 07 2002 , Refereed
  • Palladium dimethylsilanedithiolato complex: a precursor for Ti-Pd and Ti-Pd2 heterometallic complexes., Komuro T, Matsuo T, Kawaguchi H, Tatsumi K, Chemical communications (Cambridge, England), Chemical communications (Cambridge, England), (9), 988 - 989, May 07 2002 , Refereed
  • Reduction of tetrakis(trimethylsilyl)​butatriene by lithium: Monomeric and dimeric structures of the dilithium butatriene dianion, Sekiguchi, Akira, Tanaka, Masanobu, Matsuo, Tsukasa, Silicon Chemistry, Silicon Chemistry, 1(5/6), 345 - 350, 2002 , Refereed
  • Aromaticity of the Cyclobutadiene Dianion: Structural Characteristics and Magnetic Properties, Sekiguchi, Akira, Matsuo, Tsukasa, Tanaka, Masanobu, Organometallics, Organometallics, 21(6), 1072 - 1076, 2002 , Refereed
  • Synthesis and structures of Ti(III) and Ti(IV) complexes supported by a tridentate aryloxide ligand, Matsuo, Tsukasa, Kawaguchi, Hiroyuki, Sakai, Masahiro, J. Chem. Soc., Dalton. Trans., J. Chem. Soc., Dalton. Trans., (12), 2536 - 2540, 2002 , Refereed
  • From a Cyclobutadiene Dianion to a Cyclobutadiene: Synthesis and Structural Characterization of Tetrasilyl-Substituted Cyclobutadiene This work was supported by a Grant-in-Aid for Scientific Research (Nos. 10304051, 12020209, 12042213) from the Ministry o, Sekiguchi A, Tanaka M, Matsuo T, Watanabe H, Angewandte Chemie (International ed. in English), Angewandte Chemie (International ed. in English), 40(9), 1675 - 1677, May 04 2001 , Refereed
  • Isolation and characterization of the monomeric and dimeric structures of tetrakis(trimethylsilyl)​butatriene dianion dilithium, Tsukasa, Tanaka, Masanobu, Sekiguchi, Akira, Chemical Communications, Chemical Communications, (5), 503 - 504, 2001 , Refereed
  • Observation of the Predicted Negative Faraday A MCD Term in a Cyclobutadiene Dianion, Tsukasa, Tanaka, Masanobu, Sekiguchi, Akira, Journal of the American Chemical Society, Journal of the American Chemical Society, 123(22), 5356 - 5357, 2001 , Refereed
  • Cyclobutadiene Dianion Dilithium: a New Aromatic Ring System, Sekiguchi, Akira, Matsuo, Tsukasa, Watanabe, Hidetoshi, Phosphorus, Sulfur and Silicon and the Related Elements, Phosphorus, Sulfur and Silicon and the Related Elements, 168-169, 51 - 58, 2001 , Refereed
  • Synthesis and Characterization of a Cyclobutadiene Dianion Dilithium Salt: Evidence for Aromaticity, Sekiguchi, Akira, Matsuo, Tsukasa, Watanabe, Hidetoshi, Journal of the American Chemical Society, Journal of the American Chemical Society, 122(23), 5652 - 5653, 2000 , Refereed
  • A Novel Tetralithium Salt of a Tetraanion and a Dilithium Salt of a Dianion, Formed by the Reduction of the Tetrasilylethylene Moiety. Synthesis, Characterization, and Observation of an Si–H···Li+ Interaction, Matsuo, Tsukasa, Watanabe, Hidetoshi, Sekiguchi, Akira, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 73(7), 1461 - 1467, 2000 , Refereed
  • Synthesis and Molecular Structure of a Dilithium Salt of the cis-Diphenylcyclobutadiene Dianion, Matsuo, Tsukasa, Mizue, Takeru, Sekiguchi, Akira, Chemistry Letters, Chemistry Letters, (8), 896 - 897, 2000 , Refereed
  • Synthesis and Reduction of Silyl-​Substituted [5]​Radialene. Characterization and Structure of a [5]​Radialene Tetraanion with a Ten-​Center, Fourteen-​Electron π-​System, Matsuo, Tsukasa, Fure, Hidetoshi, Sekiguchi, Akira, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 73(9), 2129 - 2137, 2000 , Refereed
  • Anion chemistry of silyl-​substituted π-​electron systems based on four- and five-​membered rings, Sekiguchi, Akira, Matsuo, Tsukasa, Yuki Gosei Kagaku Kyokaishi, Yuki Gosei Kagaku Kyokaishi, 57(11), 945 - 956, 1999 , Refereed
  • Silyl-​substituted dilithium salt of fulvene dianion with 6 center​/8 electron π-​system: synthesis and characterization, Matsuo, Tsukasa, Sekiguchi, Akira, Sakurai, Hideki, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 72(5), 1115 - 1121, 1999 , Refereed
  • Silylacetylene dendrimers: synthesis and characterization, Matsuo, Tsukasa, Uchida, Kumiko, Sekiguchi, Akira, Chemical Communications, Chemical Communications, (18), 1799 - 1800, 1999 , Refereed
  • Isolation and characterization of the tetralithium salt of [5]​radialene tetraanion stabilized by silyl groups, Matsuo, Tsukasa, Fure, Hidetoshi, Sekiguchi, Akira, Chemical Communications, Chemical Communications, (19), 1981 - 1982, 1999 , Refereed
  • Reduction of the 1,4,5,8-tetrasila-1,4,5,8-tetrahydroanthracene derivative with lithium metal. Isolation and characterization of the tetralithium salt of a tetraanion, and observation of an Si–H···Li+ Interaction, Matsuo, Tsukasa, Watanabe, Hidetoshi, Ichinohe, Masaaki, Sekiguchi, Akira, Inorganic Chemistry Communications, Inorganic Chemistry Communications, 2(10), 510 - 512, 1999 , Refereed
  • Tetraanion Tetralithium with 8 Center​/12 Electron π-​System Stabilized by Silyl Groups. Synthesis and Characterization, Sekiguchi, Akira, Matsuo, Tsukasa, Akaba, Ryoichi, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 71(1), 41 - 47, 1998 , Refereed
  • The First Isolation and Full Characterization of Fulvene Dianion. Synthesis and X-​ray Structure of Dilithium Hexasilylfulvene Dianion, Matsuo, Tsukasa, Sekiguchi, Akira, Ichinohe, Masaaki, Ebata, Keisuke, Sakurai, Hideki, Organometallics, Organometallics, 17(15), 3143 - 3145, 1998 , Refereed
  • Synthesis and characterization of the dilithium salt of the octasilyl[4]​radialene dianion: evidence for a lithium walk on the eight-​center, ten-​electron π-​electron system, Sekiguchi, Akira, Matsuo, Tsukasa, Sakurai, Hideki, Angewandte Chemie, International Edition, Angewandte Chemie, International Edition, 37(12), 1662 - 1664, 1998 , Refereed
  • Synthesis and reduction of octasilyl[4]​radialene. Structure and dynamic study of [4]​radialene dianion with eight-​center ten-​electron π-​system, Matsuo, Tsukasa, Sekiguchi, Akira, Ichinohe, Masaaki, Ebata, Keisuke, Sakurai, Hideki, Bulletin of the Chemical Society of Japan, Bulletin of the Chemical Society of Japan, 71(7), 1705 - 1711, 1998 , Refereed
  • Isolation and Molecular Structure of Persilylated [5]Radialene: Intramolecular Cyclization of a Macrocyclic Pentayne with Mn(CO)3(Me-Cp), Matsuo, Tsukasa, Fure, Hidetoshi, Sekiguchi, Akira, Chemistry Letters, Chemistry Letters, (11), 1101 - 1102, 1998 , Refereed
  • A supercharged anion with a silyl-​substituted eight-​center, twelve-​electron π system: synthesis and characterization of the tetralithium salt of an octasilyl-​substituted trimethylenecyclopentene tetraanion, Sekiguchi, Akira, Matsuo, Tsukasa, Kabuto, Chizuko, Angewandte Chemie, International Edition in English, Angewandte Chemie, International Edition in English, 36(22), 2462 - 2464, 1997 , Refereed
  • Intramolecular oligomerization of disilalkylene {-​Me2Si(CH2)​nSiMe2-​} bridged cyclic triacetylenes, Ebata, Keisuke, Matsuo, Tsukasa, Inoue, Tsuyotoshi, Otsuka, Yuko, Kabuto, Chizuko, Sekiguchi, Akira, Sakurai, Hideki, Chemistry Letters, Chemistry Letters, (12), 1053 - 1055, 1996 , Refereed
  • Persilylated dimethylenecyclobutene dianion dilithium as the first 6C-​8π allyl anion system, Sekiguchi, Akira, Matsuo, Tsukasa, Ebata, Keisuke, Sakurai, Hideki, Chemistry Letters, Chemistry Letters, (12), 1133 - 1134, 1996 , Refereed

Books etc

  • Chemical Science of π-Electron Systems, Matsuo Tsukasa, 分担執筆, Part V “Heteroatom-Conjugated π-Electron Systems”, Chapter 23 “π-Conjugated Disilenes and Tetrasilacyclobutadiene”, Springer,   2015

Conference Activities & Talks

  • Heavy Cyclobutadienes, Matsuo Tsukasa, International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (GTL 2019),   2019 09 01 , 招待有り
  • Heavy Cyclobutadienes, Matsuo Tsukasa, The 7th Asian Silicon Symposium,   2019 07 28 , 招待有り
  • π-Conjugated Disilenes Stabilized by Bulky Rind Groups, Matsuo Tsukasa,   2016 04 16 , 招待有り
  • Fused-Ring Bulky Rind Groups Producing New Possibilities in Organoelement Chemistry, Matsuo Tsukasa, Institute for Chemical Research International Symposium 2016 (ICRIS’16),   2016 03 07 , 招待有り
  • Fused-Ring Bulky Rind Groups Producing New Possibilities in Organoelement Chemistry, Matsuo Tsukasa, The 10th Organoelement Chemistry Seminar,   2015 07 08 , 招待有り
  • A New Family of π-Conjugated Silicon Compounds Incorporating the Bulky Rind Groups, Matsuo Tsukasa, 2nd International Symposium on Element Innovation,   2012 10 20 , 招待有り
  • A New Family of pi-Conjugated Silicon Compounds Stabilized by the Bulky Rind Groups, Matsuo Tsukasa, The 14th Asian Chemical Congress (14 ACC),   2011 08 06 , 招待有り

Misc

  • Air-Stable Emissive Disilenes Protected by Fused-Ring Bulky “Rind” Groups, Matsuo Tsukasa, TCI MAIL, 163, 1, 6,   2014

Awards & Honors

  •   2012 03 , RIKEN, Matsuo Tsukasa
  •   2008 08 , 理事長感謝状